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Reactions of expanding-lattice clay minerals with glycerol and ethylene glycol

Published online by Cambridge University Press:  14 March 2018

G. F. Walker
G. F. Walker*
Affiliation:
C.S.I.R.O., Chemical Research Laboratories, Melbourne, Australia
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Abstract

Under certain circumstances, both glycerol and ethylene glycol form interlayer complexes with vermiculites resembling those formed with the smectites. The rate and degree of complex formation are related to the surface charge on the silicate layers, to the type of interlayer cation present and to crystal size. With glycerol, but not with ethylene glycol, the hydration state of the mineral immediately prior to complex formation is of some importance.

Type
Research Article
Information
Clay Minerals Bulletin , Volume 3 , Issue 20 , December 1958 , pp. 302 - 313
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1958

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