Hostname: page-component-78c5997874-fbnjt Total loading time: 0 Render date: 2024-11-13T06:04:07.823Z Has data issue: false hasContentIssue false
  • English
  • Français

Diagenesis of Miocene pelitic sedimentary rocks in the Sava Depression (Croatia)

Published online by Cambridge University Press:  09 July 2018

A. Grizelj ,
D. Tibljaš ,
M. Kovačić  and
D. Španić
A. Grizelj*
Affiliation:
Croatian Geological Survey, Sachsova 2, Zagreb, Croatia
D. Tibljaš
Affiliation:
University of Zagreb, Faculty of Science, Horvatovac 95, Zagreb, Croatia
M. Kovačić
Affiliation:
University of Zagreb, Faculty of Science, Horvatovac 95, Zagreb, Croatia
D. Španić
Affiliation:
INA d.d. Lovinčićeva bb, Zagreb, Croatia
*
*E-mail: anita.grizelj@hgi-cgs.hr
Get access Rights & Permissions [Opens in a new window]

Abstract

Miocene pelitic sedimentary rocks from six wells in the Sava Depression (sub-basin in the south-western part of the Pannonian Basin System) were investigated in order to determine the degrees of diagenetic alteration.Qualitative and semiquantitative mineral compositions of samples and the content of smectite in illite-smectite (I-S) were determined by X-ray powder diffraction (XRD).Vitrinite reflectance and thermal alteration index (TAI) were measured in order to estimate the palaeotemperatures.Carbonate minerals, clay minerals and quartz are the main constituents of the pelitic sediments.Feldspars (albite), pyrite, opal-CT and hematite are present as minor constituents in some rocks. The mineral composition of the rocks, apart from previously known differences caused by various depositional environments and clastic material provenance, is dependent on the degree of diagenetic processes. At elevated temperatures and large burial depths the minerals formed by alteration processes or precipitated at the surface; smectite, kaolinite and calcite were gradually replaced by minerals formed by diagenetic processes, i.e. by illite-smectite, illite, chlorite, Ca-excess dolomite/ankerite and albite. Based on XRD data for smectite, I-S and illite, three stages of diagenetic development have been established. The early stage was characteristic of samples at depths <1.8 km containing smectite, I-S of the random R0 type and detrital illite.The middle stage begins with the appearance of the ordered R1 type of I-S at the depths >1.8 km and temperature above 80°C. At depths >4.6 km with corresponding temperatures >190ºC, the late stage began, characterized by the presence of R>1 I-S with <10% smectite.

Keywords

diagenesisillite-smectiteMiocenePannonian Basin Systempelitic sedimentary rocksSava DepressionCroatiathermal alteration indexvitrinite reflectance
Type
Research Papers
Information
Clay Minerals , Volume 46 , Issue 1 , March 2011 , pp. 59 - 72
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Balogh, K., Jàmbor, A., Partènyi, Z., Ravasz-Baranyai, K., Solti, G. & Nusszer A.(1983) Petrography and K-Ar dating of Tertiary and Quaternary basaltic rock in Hungary. Annuarul Institutului de Geologie si Geofizica, 61, 365–373.Google Scholar
Barić, G.(2006) Oil Geology, P. 143 in: INA - Industrija nafte, Zagreb (in Croatian).Google Scholar
Barić, G., Ivković, Ž. & Perica, R.(2000) The Miocene petroleum system of the Sava depression, Croatia. Petroleum Geoscience, 6, 165–173.Google Scholar
Bjørlykke, K.(1998) Clay mineral diagenesis in sedimentary basins - a key to the prediction of rock properties.Examples from the North Sea Basin. Clay Minerals, 33, 15–34.CrossRefGoogle Scholar
Bjørlykke, K., Aagaard, P., Egeberg, P.K. & Simmons, S.P. (1995) Geochemical constraints from formation water analyses from the North Sea and Gulf Coast Basin on quartz, feldspar and illite precipitation in reservoir rocks.Pp.33–50 in: The Geochemistry of Reservoirs (J.M. Cubitt & W.A. England, editors). Geological Society Special Publication 86, London.Google Scholar
Bostick, N., Cashman, S., McCulloch, T. & Waddell, C. (1979) Gradients of vitrinite reflectance and present temperature in the Los Angeles and Ventura Basins, California.P p.65-96 in: Low-temperature Metamorphism of Kerogen and Clay Minerals (D.F. Oltz, editor). Pacific Section, Society of Economic Paleontologists and Mineralogists, Los Angeles.Google Scholar
Braun, K.(1991) Mineralogical-petrographical characteristic and genesis of the bentonite deposits of Maovice, Gornja Jelenska, Bednja and Poljanska Luka. Acta Geologica, JAZU, 21, 1–34 (in Croatian, English summary).Google Scholar
Chang, K.H. (1986) Comparison between the diagenesis of dioctahedral and trioctahedral smectite, Brazilian Offshore Basins. Clays and Clays Minerals, 34, 407–423.CrossRefGoogle Scholar
Deer, W.A., Howie, R.A & Zussman, J. (2001) Framework silicates: feldspars, Rock-forming Minerals, 4A, 530–535.The Geological Society, London.Google Scholar
Franců, J., Müller, P., Šucha, V. & Zatkalíková, V.(1990) Organic matter and clay minerals as indicators of thermal history in the Transcarpathian Depression (East Slovakian Neogene Basin) and Vienna Basin. Geologiský Zborník, Geologica Carpathica, 41, 535–546.Google Scholar
Frey, M.(1987) Very low-grade metamorphism of clastic sedimentary rocks.Pp. 9–58 in: Low Temperature Metamorphism (M.Frey, editor), Blackie and Son Ltd, Glasgow.Google Scholar
Gier, S.(1998) Burial diagenetic processes and clay mineral formation in the molasse zone of Upper Austria. Clays and Clay Minerals, 46, 658–669.CrossRefGoogle Scholar
Grizelj, A.(2008) Mineralogical and geochemical characteristics of Miocene pelitic sediments from south-western part of Pannonian Basin.PhD thesis, University of Zagreb, Croatia (in Croatian with English summary).Google Scholar
Grizelj, A., TibljaŠ, D. & Kovačić, M.(2007) Mineralogy and geochemistry of Upper Miocene pelitic sediments of Zagorje Basin (Croatia): implication for evolution of the Pannonian Basin. Geologica Carpathica, 58, 263–276. Hámor-Vidó M.& Viczián I.(1993) Vitrinite reflectance and smectite content of mixed-layer illite/ smectites in Neogene sequences of the Pannonian Basin, Hungary. Acta Geologica Hungarica, 36, 197–209.Google Scholar
Hancock, N.J. & Taylor, A.M. (1978) Clay mineral diagenesis and oil migration in the Middle Jurassic Brent Sand Formation. Journal of the Geological Society, 135, 69–72.CrossRefGoogle Scholar
Harangi, Sz.(2001) Neogene magmatism in the Alpine - Pannonian Transition Zone - a model for melt generation in a complex geodynamic setting. Acta Vulcanologica, 13, 25–39.Google Scholar
Hillier, S., Matyas, J., Matter, A. & Vasseur, G. (1995) Illite/smectite diagenesis and its variable correlation with vitrinite reflectance in the Pannonian Basin. Clays and Clay Minerals, 43, 174–183.CrossRefGoogle Scholar
Hoffman, J. & Hower, J. (1979) Clay mineral assemblages as low-grade metamorphic geothermometers: application to the thrust faulted disturbed belt of Montana, USA. Special Publication, Society of Economic Paleontologists and Mineralogists, Tulsa, 26, 55–79.Google Scholar
Horváth, F. & Royden, L.H. (1981) Mechanism for the formation of the intra-Carpathian basins: a review. Earth Science Reviews, 3-4, 307–316.Google Scholar
Kurzweil, H. & Johns, W.D. (1981) Diagenesis of Tertiary marlstones in the Vienna Basin. 70 A. Grizelj et al. Tschermaks Mineralogische und Petrographische Mitteilungen, 29, 103–125.Google Scholar
Lanson, B., Sakharov, B.A., Claret, F. & Drits, V.A. (2007) Diagenetic evolution of clay minerals in Gulf Coast shales: reappraisal of X-ray diffraction data using profile fitting.P.59 in: Abstract Book (F. Rocha, D.Terroso & A.Quintela, editors), Euroclay 2007, 22-27 July 2007 Aveiro, Portugal.Google Scholar
Lučić, D., Saftić, B., Krizmanić, K., Prelogović, E., Britvić, V., Mesić, I. & Tadej, J. (2001) The Neogene evolution and hydrocarbon potential of the Pannonian Basin in Croatia. Marine and Petroleum Geology, 18, 133–147.CrossRefGoogle Scholar
Pamić, J.(1997) Volcanic rocks of the Sava - Drava interfluve and Baranja in the South Pannonian Basin. Nafta Monograph,149–176, Zagreb, Croatia.Google Scholar
Pamić, J., McKee, E.H., Bullen, T. & Lanphere, M.A. (1995) Tertiary volcanic rocks from the southern Pannonian Basin, Croatia. International Geology Review, 37, 259–283.CrossRefGoogle Scholar
Pavelić, D.(2005) Cyclicity in the evolution of the Neogene North Croatian Basin (Pannonian Basin System).Pp.273–283 in: Cyclic Development of Sdimentary Basins (J.M. Mabesoone & V.H. Neumann, editors).Developments i n Sedimentology, 57, Elsevier, Amsterdam .Google Scholar
Pearson, D.L. (1990) Pollen/Spore Color Standard, Revised Edition.P hillips Petroleum Exploration Projects Section.Google Scholar
Perry, E. & Hower, J.(1970) Burial diagenesis in Gulf Coast pelitic sediments. Clays and Clay Minerals, 18, 165–177.CrossRefGoogle Scholar
Pollastro, R.M. (1993) Consideration and applications of the illite/smectite geothermometer in hydrocarbonbearing rocks of Miocene to Mississippian age. Clays and Clays Minerals, 41, 119–133.CrossRefGoogle Scholar
Potter, P.E., Maynard, J.B. & Depetris, P.J. (2007) Introduction and overview.Pp.127–155 in: Muds and Mudstones. Springer-Verlag, Berlin, Heidelberg, New York.Google Scholar
Rögl, F.(1996) Stratigraphic correlation of the Paratethys Oligocene and Miocene. Mitteilungen der Gesellschaft der Geologie u n d Bergbaustudenten Österreich, 41, 65–73.Google Scholar
Royden, L.H. (1988) Late Cenozoic tectonics of the Pannonian Basin System.Pp . 27–48 in: The Pannonian Basin. A study in Basin Evolution (L H. Royden & I.F. Horváth, editors): AAPG Memoir 45, Tulsa.Google Scholar
Royden, L.H., Horváth, F., Nagymarosy, A. & Stegena, L. (1983) Evolution of the Pannonian Basin System.2. Subsidence and thermal history. Tectonics, 2, 91–137.Google Scholar
Sachsenhofer, R.F., Rantitsch, G., Hasenhüttl, C., Russegger, B. & Jelen, B.(1998) Smectite to illite diagenesis in Early Miocene sediments from the hyperthermal western Pannonian Basin. Clay Minerals, 33, 523–537.Google Scholar
Saftić, B., Velić, J., Sztaó, O., Juhász, G. & Ivković, Ž. (2003) Tertiary subsurface facies, source rocks and hydrocarbon reservoirs in the SW part of the Pannonian Basin (northern Croatia and south-western Hungary). Geologia Croatica, 56, 101–122.CrossRefGoogle Scholar
Schultz, L.G. (1964) Quantitative interpretation of mineralogical composition from X-ray and chemical data for the Pierre Shale. U. S. Geological Survey Professional Paper 391-C, 1–31.Google Scholar
Schwab, K.W. (1990) Visual kerogen assessment. Pp. 10–14.in: Mededelingen Rijks Geologische Dienst, 45 (J.J. Fermont & J.W. Weegink, editors). Proceeding of International Symposium on Organic Petrology, Zeist, the Netherlands.Google Scholar
Środoń, J.(1981) X-ray identification of randomly interstratified illite/smectite in mixtures with discrete illite. Clay Minerals, 16, 297–304.CrossRefGoogle Scholar
Środoń, J.(1984) X-ray powder diffraction identification of illitic materials. Clays and Clays Minerals, 32, 337–349.CrossRefGoogle Scholar
Środoń, J.(2007) Illitization of smectite and history of sedimentary basins.Pp. 74-82 in: Invited Lectures (F.Ro cha, D.Te rroso & A.Qun tela, editors), Euroclay 2007, Aveiro, Portugal. Ś rodoń J.& Eberl D.D.(1984) Illite. Pp.495-544 in: Micas (S.W. Bailey, editor), Reviews in Mineralogy, 13, Mineralogical Society of America, Washington.Google Scholar
Środoń, J., Kotarba, M., Biro, A., Such, P., Clauer, N. & Wó jtowicz, A.(2006) Diagenetic history of the Podhale-Orava Basin and underlying Tatra sedimentary structural units (western Carpathians): evidence from XRD and K-Ar of illite-smectite. Clay Minerals, 41, 751–774.CrossRefGoogle Scholar
Šucha, V., Kraus, I., Gerthofferová, H., PeteŠ, J. & Sereková, M.(1993) Smectite to illite conversion in bentonites and shales of the East Slovak Basin. Clay Minerals, 28, 243–253.CrossRefGoogle Scholar
Szabó, C., Harangi, S. & László, C.(1992) Review of Neogene and Quaternary volcanism of the Carpathian- Pannonian region. Tectonophysics, 208, 243–256.CrossRefGoogle Scholar
Tadej, N. & Slovenec, D. (2001) Montmorillonites in Miocene bentonites from Croatia.Pp.107 in: Book of Abstracts (I.Kraus & P.Komadel, editors), Mid- European Clay Conference 01, 9–14.September 2001, Stara Lesna, Slovakia.Google Scholar
Tanács, J. & Viczián, I.(1995) Mixed-layer illite/ smectites and clay sedimentation in the Neogene of the Pannonian Basin, Hungary. Geologica Carpathica, Series Clays, 4, 3–22.Google Scholar
Varsányi, I.(1975) Clay minerals of the southern Great Hungarian Plain. Acta Mineralogica Petrographica, 22, 51–60.Google Scholar
Velde, B., Suzuki, T. & Nicot, E.(1986) Pressuretemperature- composition of illite/smectite mix-layer minerals: Niger delta mudstones and other examples. Clays and Clay Minerals, 34, 435–441.CrossRefGoogle Scholar
Viczián, I.(1975) A review of the clay mineralogy of Hungarian sedimentary rocks (with special regard of the distribution of diagenetic zones). Acta Geologica Academiae Hungarica, 19, 243–256.Google Scholar
Vrbanac, B.(2002) Facies and facies architecture of the Ivanić Grad Formation (Upper Pannonian) - Sava Depression, NW Croatia. Geologia Croatica, 55, 57–77.CrossRefGoogle Scholar
Weaver, C.E. (1989) Clays, Muds and Shales, 417–449. Elsevier, Amsterdam.Google Scholar