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Removal of Cu2+ and Ni2+ ions from aqueous solutions by adsorption onto natural palygorskite and vermiculite

Published online by Cambridge University Press:  28 February 2018

A. Bourliva ,
A. K. Sikalidis ,
L. Papadopoulou ,
M. Betsiou ,
K. Michailidis ,
C. Sikalidis  and
A. Filippidis
A. Bourliva*
Affiliation:
Department of Mineralogy-Petrology-Economic Geology, School of Geology, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
A. K. Sikalidis
Affiliation:
Istanbul Yeni Yuzyil University, Department of Nutrition and Dietetics, Istanbul, Turkey
L. Papadopoulou
Affiliation:
Department of Mineralogy-Petrology-Economic Geology, School of Geology, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
M. Betsiou
Affiliation:
Department of Chemical Engineering, School of Engineering, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
K. Michailidis
Affiliation:
Department of Mineralogy-Petrology-Economic Geology, School of Geology, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
C. Sikalidis
Affiliation:
Department of Chemical Engineering, School of Engineering, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
A. Filippidis
Affiliation:
Department of Mineralogy-Petrology-Economic Geology, School of Geology, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
*
*E-mail: annab@geo.auth.gr
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Abstract

The efficiency of two low-cost, abundant and natural clay minerals, palygorskite and vermiculite, in terms of reducing the concentation of Cu2+ and Ni2+ ions was evaluated here. Natural clay minerals were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), BET specific surface area and pore-diameter analysis. Batch-type experiments were performed and various parameters, i.e. pH, clay amount, contact time and initial metal concentration, that affect adsorption processes were investigated. The adsorption of Cu2+ and Ni2+ ions is pH-dependent, while minor clay quantities were sufficient to achieve high removal efficiencies. Adsorption equilibrium occurred in 60 min and the adsorption kinetics were better described by pseudo-second-order kinetics. Experimental results were analysed by the Langmuir, Freundlich, Dubinin–Radushkevich (D–R), Temkin and Halsey isotherm equations. The release of exchangeable cations (i.e. Ca2+, Mg2+, Na+ and K+) was examined to verify an ion-exchange mechanism.

Keywords

palygorskitevermiculiteadsorptionion exchangeisothermstrace elements
Type
Article
Information
Clay Minerals , Volume 53 , Issue 1 , March 2018 , pp. 1 - 15
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

Associate Editor: H. Stanjek

References

REFERENCES

Abollino, O., Giacomino, A., Malandrino, M. & Mentasi, E. (2008) Interaction of metal ions with montmorillonite and vermiculite. Applied Clay Science, 38, 227–236.Google Scholar
Al-Makhadmeh, L. & Batiha, M.A. (2016) Removal of iron and copper from aqueous solutions using Jordanian kaolin and zeolitic tuff. Desalination and Water Treatment, 57, 20930–20943.Google Scholar
Alexiades, C.A. & Jackson, M.L. (1966) Quantitative clay mineralogical analysis of soils and sediments. Clays and Clay Minerals, 14, 35–52.Google Scholar
Alvarez-Ayuso, E. & Garcia-Sanchez, A. (2003) Removal of heavy metals from wastewaters by natural and Na-exchanged bentonites. Clays and Clay Minerals, 51, 475.Google Scholar
Baker, H. (2009) Characterization for the interaction of nickel(II) and copper(II) from aqueous solutions with natural silicate minerals. Desalination, 244, 48–58.Google Scholar
Bayat, B. (2002) Comparative study of adsorption properties of Turkish fly ashes I. The case of nickel(II), copper(II) and zinc(II). Journal of Hazardous Materials, B10, 285–300.Google Scholar
Bhattacharya, A.K., Mandal, S.N. & Das, S.K. (2006) Adsorption of Zn (II) from aqueous solution by using different adsorbents. Journal of Chemical Engineering, 123, 43–51.Google Scholar
Bourliva, A., Michailidis, K., Sikalidis, C. & Filippidis, A. (2013a) Spectroscopic and thermal study of bentonites from Milos Island, Greece. Bulletin of the Geological Society of Greece, 47, 2020–2029.Google Scholar
Bourliva, A., Michailidis, K., Sikalidis, C., Filippidis, A. & Betsiou, M. (2013b) Lead removal from aqueous solutions by natural Greek bentonites. Clay Minerals, 48, 771–787.Google Scholar
Bourliva, A, Michailidis, K., Sikalidis, C., Filippidis, A. & Betsiou, M. (2015) Adsorption of Cd(II), Cu(II), Ni(II) and Pb(II) onto natural bentonite: study in mono- and multi-metal systems. Environmental Earth Science, 73, 5435–5444.Google Scholar
Brewer, G.J. (2003) Copper in medicine. Current Opinion in Chemical Biology, 7, 207–212.CrossRefGoogle ScholarPubMed
Brewer, G.J. (2014) The promise of copper lowering therapy with tetrathiomolybdate in the cure of cancer and in the treatment of inflammatory disease. Journal of Trace Elements in Medicine and Biology, 28, 372–378.Google Scholar
Chahi, A., Petit, S. & Decarreau, A. (2002) Infrared evidence of dioctahedral-trioctahedral site occupancy in palygorskite. Clays and Clay Minerals, 50, 306–313.Google Scholar
Cheremisinoff, P.N. (1995) Handbook of Water and Wastewater Treatment Technology. Marcel Dekker Inc., New York.Google Scholar
Christidis, G.E., Katsiki, P., Pratikakis, A. & Kacandes, G. (2010) Rheological properties of palygorskite-smectite suspensions from the Ventzia basin, W. Macedonia, Greece. Bulletin of the Geological Society of Greece, 43, 2562–2569.Google Scholar
Covelo, E.F., Vega, F.A. & Andrade, M.L. (2007) Competitive sorption and desorption of heavy metals by individual soil components. Journal of Hazardous Materials, 140, 308–315.Google Scholar
De Pablo, L., Chavez, M.L. & Abatal, M. (2011) Adsorption of heavy metals in acid to alkaline environments by montmorillonite and Ca-montmorillonite. Journal of Chemical Engineering, 171, 1276–1286.CrossRefGoogle Scholar
Ding, S., Sun, Y., Yang, C. & Xu, B. (2009) Removal of copper from aqueous solutions by bentonites and the factors affecting it. International Journal of Mining Science and Technology, 19, 489–492.Google Scholar
El-Bayaa, A., Badawy, N. & Abd Alkhalik, E. (2009) Effect of ionic strength on the adsorption of copper and chromium ions by vermiculite pure clay mineral. Journal of Hazardous Materials, 170, 1204–1209.Google Scholar
Eren, E. & Afsin, B. (2008) An investigation of Cu(II) adsorption by raw and acid-activated bentonite: A combined potentiometric, thermodynamic, XRD, IR, DTA study. Journal of Hazardous Materials, 151, 682–691.Google Scholar
Eren, E. (2008) Removal of copper ions by modified Unye clay, Turkey. Journal of Hazardous Materials, 159, 235–244.CrossRefGoogle ScholarPubMed
Frost, R.L., Locos, O.B., Ruan, J. & Kloprogge, J.T. (2001) Near-infrared and mid-infrared spectroscopic study of sepiolites and palygorskites. Vibrational Spectroscopy, 27, 1–13.CrossRefGoogle Scholar
Fu, F. & Wang, Q. (2011) Removal of heavy metal ions from wastewaters: A review. Journal of Environmental Management, 92, 407–418.Google Scholar
Giles, C.H., Smith, D. & Huitson, A. (1974) A general treatment and classification of the solute adsorption isotherm: I. Theoretical. Journal of Colloid and Interface Science, 47, 755–765.Google Scholar
Harris, E.D. (2003) Basic and clinical aspects of copper. Critical Reviews in Clinical Laboratory Sciences, 40, 547–586.Google Scholar
Ho, Y.S. & McKay, G. (1998) A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Process Safety and Environmental Protection, 76, 332–340.Google Scholar
Hojati, S. & Landi, A. (2015) Kinetics and thermodynamics of zinc removal from a metalplating wastewater by adsorption onto an Iranian sepiolite. International Journal of Environmental Science and Technology, 12, 203–210.Google Scholar
Hu, H. (2002) Human health and heavy metals exposure. In: Life Support: The Environment and Human Health (McCally, M., editor). MIT Press, Cambridge, Massachusetts, USA.Google Scholar
Ijagbemi, C.O., Baek, M. & Kim, D. (2009) Montmorillonite surface properties and sorption characteristics for heavy metal removal from aqueous solutions. Journal of Hazardous Materials, 166, 538–546.Google Scholar
Ijagbemi, C.O., Baek, M. & Kim, D. (2010) Adsorptive performance of un-calcined sodium exchanged and acid modified montmorillonite for Ni2+ removal: Equilibrium, kinetics, thermodynamics and regeneration studies. Journal of Hazardous Materials, 174, 745–755.Google Scholar
Jiang, M., Jin, X., Lu, X. & Chen, Z. (2010) Adsorption of Pb(II), Cd(II), Ni(II) and Cu(II) onto natural kaolinite clay. Desalination, 252, 33–39.Google Scholar
Kastritis, I.D., Kacandes, G.H. & Mposkos, E. (2003) The palygorskite and Mg-Fe-smectite clay deposits of the Ventzia basin, western Macedonia, Greece. In: Proceedings of the 7th SGA-Mineral Exploration and Sustainable Development Meeting (Eliopoulos, D.G., editor), Millpress, Rotterdam.Google Scholar
Kurniawan, T.A., Chan, G.Y.S., Lo, W.H. & Babel, S. (2006) Comparisons of low-cost adsorbents for treating wastewaters laden with heavy metals. Science of the Total Environment, 366, 409–426.Google Scholar
Liu, Z. & Zhou, S. (2010) Adsorption of copper and nickel on Na-bentonite. Process Safety and Environmental Protection, 88, 62–66.Google Scholar
Madejová, J. & Komadel, P. (2001) Baseline studies of the Clay Minerals Society Source Clays: infrared spectroscopy. Clays and Clay Minerals, 49, 410–432.Google Scholar
Madejová, J., Balan, E. & Petit, S. (2011) Application of vibrational spectroscopy to the characterization of phyllosilicates and other industrial minerals. In: Advances in the Characterization of Industrial Minerals (Christidis, G.E., editor), EMU Notes in Mineralogy, 9, European Mineralogical Union and the Mineralogical Society of Great Britain and Ireland, London.Google Scholar
Magave, R., Zhao, J., Bowman, L. & Ding, M. (2012) Genotoxicity and carcinogenicity of cobalt-, nickel- and copper-based nanoparticles. Experimental and Therapeutic Medicine Journal, 4, 551–561.Google Scholar
Malamis, S. & Katsou, E. (2013) A review on zinc and nickel adsorption on natural and modified zeolite, bentonite and vermiculite: Examination of process parameters, kinetics and isotherms. Journal of Hazardous Materials, 252–253, 428–461.Google Scholar
Mathialagan, T. & Viraraghavan, T. (2003) Adsorption of cadmium from aqueous solutions by vermiculite. Separation Science and Technology, 38, 57–76.CrossRefGoogle Scholar
Mendelovici, E. (1973) Infrared study of attapulgite and HCl treated attapulgite. Clays and Clay Minerals, 21, 115–119.Google Scholar
Muiambo, H.F., Focke, W.W., Atanasova, M., Van Der Westhuizen, I. & Tiedt, L.R. (2010) Thermal properties of sodium-exchanged Palabora vermiculite. Applied Clay Science, 50, 51–57.Google Scholar
Murray, H.H. (1999) Applied clay mineralogy today and tomorrow. Clay Minerals, 34, 39–49.Google Scholar
Ozdemir, G. & Yapar, S. (2009) Adsorption and desorption behavior of copper ions on Na-montmorillonite: effect of rhamnolipids and pH. Journal of Hazardous Materials, 166, 1307–1313.Google Scholar
Potgieter, J.H., Potgieter-Vermaak, S.S. & Kalibantonga, P.D. (2006) Heavy metals removal from solution by palygorskite clay. Minerals Engineering, 19, 463–470.Google Scholar
Sdiri, A.T., Higashi, T. & Jamoussi, F. (2014) Adsorption of copper and zinc onto natural clay in single and binary systems. International Journal of Environmental Science and Technology, 11, 1081–1092.CrossRefGoogle Scholar
Sen Gupta, S. & Bhattacharyya, K.G. (2008) Immobilization of Pb(II), Cd(II) and Ni(II) ions on kaolinite and montmorillonite surfaces from aqueous medium. Journal of Environmental Management, 87, 46–58.Google Scholar
Sen, T.K. & Gomez, D. (2011) Adsorption of zinc (Zn2+) from aqueous solution on natural bentonite. Desalination, 267, 286–294.Google Scholar
Sharma, A.D. (2006) Disulfiram and low nickel diet in the management of hand eczema: A clinical study. Indian Journal of Dermatology, Venereology and Leprology, 72, 113–118.Google Scholar
Sharma, A.D. (2013) Low nickel diet in dermatology. Indian Journal of Dermatology, 3, 240.Google Scholar
Shukla, A., Zhang, Y.H., Dubey, P., Margrave, J.L. & Shukla, S.S. (2002) The role of sawdust in the removal of unwanted materials from water. Journal of Hazardous Materials, 95, 137–152.Google Scholar
Srinivasan, R. (2011) Advances in application of natural clay and its composites in removal of biological, organic, and inorganic contaminants from drinking water. Advances in Materials Science and Engineering, 2011, 1–17.Google Scholar
Srivastava, V.C., Mall, I.D. & Mishra, I.M. (2008) Removal of cadmium(II) and zinc(II) metal ions from binary aqueous solution by rice husk ash. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 312, 172–184.Google Scholar
Stumm, W. (1991) Chemistry of the Solid–Water Interface. J. Wiley & Sons Inc, New York.Google Scholar
Stylianou, M.A., Inglezakis, V.J., Moustakas, K.G., Malamis, S.P. & Loizidou, M.D. (2007) Removal of Cu(II) in fixed bed and batch reactors using natural zeolite and exfoliated vermiculite as adsorbents. Desalination, 215, 133–142.Google Scholar
Suárez, M. & García-Romero, E. (2006) FTIR spectroscopic study of palygorskite: Influence of the composition of the octahedral sheet. Applied Clay Science, 31, 154–163.Google Scholar
Tahir, S. & Rauf, N. (2003) Thermodynamic studies of Ni(II) adsorption onto bentonite from aqueous solution. The Journal of Chemical Thermodynamics, 35, 2003–2009.Google Scholar
Tang, P., Chew, N.Y., Chan, H.K. & Raper, J.A. (2003) Limitation of determination of surface fractional dimension using N2 adsorption isotherms and modified Frenkel-Halsey-Hill theory. Langmuir, 19, 2632–2638.Google Scholar
Tsirambides, A. & Michailidis, K. (1999) An X-ray, EPMA, and oxygen isotope study of vermiculitized micas in the ultramafic rocks at Askos, Macedonia, Greece. Applied Clay Science, 4, 121–140.Google Scholar
Uddin, M.K. (2017) A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chemical Engineering Journal, 308, 438–462.Google Scholar
Veli, S. & Alyüz, B. (2007) Adsorption of copper and zinc from aqueous solutions by using natural clay. Journal of Hazardous Materials, 149, 226–233.Google Scholar
Xueyi, G. & Inoue, K. (2003) Elution of copper from vermiculite with environmentally benign reagents. Hydrometallurgy, 70, 9–21.Google Scholar
Yavuz, O., Altunkaynak, Y. & Güzel, F. (2003) Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite. Water Research, 37, 948–952.CrossRefGoogle ScholarPubMed