Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-26T08:11:49.639Z Has data issue: false hasContentIssue false

The adsorption of aliphatic alcohols by montmorillonite and kaolinite

Published online by Cambridge University Press:  09 July 2018

W. L. German
Affiliation:
Ceramics Department, North Staffordshire College of Technology, College Road, Stoke-on-Trent
D. A. Harding
Affiliation:
Ceramics Department, North Staffordshire College of Technology, College Road, Stoke-on-Trent

Abstract

Adsorption isotherms for an homologous series of primary aliphatic alcohols from aqueous solution by montmorillonite and kaolinite saturated with either sodium or calcium ions have been determined. The results show that adsorption is a function of chain length and exchangeable cation in the case of the more insoluble alcohols. Exchangeable cation does not affect the adsorption of the soluble alcohols to any significant extent. Adsorption of the longer chain alcohols occurs in voids in the mineral aggregates.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1969

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Barnaad, J.A. & Karayannis, N. (1962) Analytica chim. Acta 26, 253.CrossRefGoogle Scholar
Brindley, G.W., Bender, R. & Ray, S. (1963) Geochim. cosmochim. Acta 27, 1129.Google Scholar
Greenland, D.J. (1956a) J. Soil Sci. 7, 319.Google Scholar
Greenland, D.J. (19566) J. Soil Sci. 1, 329.Google Scholar
Greenland, D.J. (1965) Soils Fertil. Harpenden 28, 415.Google Scholar
Hansen, R.S., Ying Fu & Bartell, F.E. (1949) J.phys. Chem., Ithaca 53, 769.Google Scholar
Hoffmann, R.W. & Brindley, G.W. (1960) Geochim. cosmochim. Acta 20, 15.Google Scholar
Hoffmann, R.W. & Brindley, G.W. (1961) Am. Miner. 46, 450.Google Scholar
Kipling, J.J. (1965) Adsorption from Solutions of Non-Electrolytes. Academic Press, London.Google Scholar
Norrish, K. (1954) Disc. Faraday Soc. 18, 120.CrossRefGoogle Scholar
Seidell, A. (1941) Solubilities of Organic Compounds, Vol. 2. Van Nostrand, New York.Google Scholar
Worrall, W.E. (1968) Clays: their Nature, Origin and General Properties, p. 82. MacLaren, London.Google Scholar
Ying Fu, Hansen, R.S. & Bartell, F.E. (1948) J. phys. Chem., Ithaca 52, 374.Google Scholar