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Copper supported on acid-activated vermiculite as an efficient and recyclable catalyst for the Biginelli reaction: a green approach

Published online by Cambridge University Press:  02 December 2020

C.E. Torres-Méndez Open the ORCID record for C.E. Torres-Méndez [Opens in a new window]  and
B. López-Mayorga
C.E. Torres-Méndez*
Affiliation:
Escuela de Química, Universidad de San Carlos de Guatemala, 11 Av. Ciudad de Guatemala01012, Guatemala
B. López-Mayorga
Affiliation:
Escuela de Química, Universidad de San Carlos de Guatemala, 11 Av. Ciudad de Guatemala01012, Guatemala
*
*E-mail: torres.carlos@usac.edu.gt
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Abstract

The synthesis of copper citrate complex supported on acid-activated vermiculite was investigated with a view to preparing an efficient, mild, robust and recyclable catalyst for the Biginelli reaction. The new catalyst was characterized by X-ray fluorescence (XRF), infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), X-ray powder diffraction (XRD), and scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDS). Copper citrate supported over activated vermiculite (AAVrm-Cu2) showed good catalytic activity in the synthesis of 3,4-dihydropyrimidinones. The catalyst can be separated easily from the reaction mixture by filtration and retains its catalytic activity for up to five cycles of reaction with no apparent decrease in yield.

Keywords

vermiculitecopper complexdihydropyrimidinonesone-pot synthesisgreen chemistryheterogeneous catalysis
Type
Article
Information
Clay Minerals , Volume 55 , Issue 4 , December 2020 , pp. 271 - 280
Copyright
Copyright © The Author(s), 2020. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: M. Pospíšil

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