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Enhancement of the adsorption properties of two natural bentonites by ion exchange: equilibrium, kinetics and thermodynamic study

Published online by Cambridge University Press:  24 June 2020

Ali Boukhemkhem ,
Alejandro H. Pizarro  and
Carmen B. Molina Open the ORCID record for Carmen B. Molina [Opens in a new window]
Ali Boukhemkhem
Affiliation:
Laboratory Interactions Materials – Environment (LIME), University of Mohamed Seddik Ben Yahia, Jijel, 18000, Algeria
Alejandro H. Pizarro
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain
Carmen B. Molina*
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Madrid, Spain
*
*E-mail: carmenbelen.molina@uam.es
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Abstract

In this investigation, Maghnia (Ma) and Mostaganem (Ms) bentonite clays, mined from west Algeria, with no prior affinity for anionic dyes, were modified by simple ion exchange with aqueous Fe3+ solutions, followed by calcination at 500°C. The resulting materials, Fe-Ma and Fe-Ms, respectively, were employed as adsorbents for methyl orange. The starting materials and the two adsorbents were characterized by X-ray diffraction, N2 adsorption–desorption isotherms, Brunauer–Emmett–Teller specific surface area and X-ray fluorescence and by determining the point of zero charge. The effects of various variables, such as initial dye concentration, contact time, adsorbent dose, initial pH and adsorption temperature, were studied. The kinetics were well described by the pseudo-second-order model and the mechanism was determined from the intraparticle diffusion model, while corresponding isotherms fitted better to the Freundlich model. Thermodynamic parameters showed that the adsorption process was endothermic, spontaneous and physical in nature, accompanied by an increase of entropy.

Keywords

adsorptionintraparticle diffusion modelmethyl orangemodified bentonitespseudo-second-order modelthermodynamics
Type
Article
Information
Clay Minerals , Volume 55 , Issue 2 , June 2020 , pp. 132 - 141
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland, 2020

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Footnotes

Associate Editor: Javier Huertas

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