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Facile fabrication of a stable fluorescent yellow X-10GFF/palygorskite hybrid pigment via semi-dry grinding

Published online by Cambridge University Press:  11 June 2021

Qin Wang
Affiliation:
Key Laboratory of Clay Mineral Applied Research of Gansu Province, Center of Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou730000, PR China State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou730000, PR China
Bin Mu
Affiliation:
Key Laboratory of Clay Mineral Applied Research of Gansu Province, Center of Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou730000, PR China
Shue Li
Affiliation:
Key Laboratory of Clay Mineral Applied Research of Gansu Province, Center of Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou730000, PR China Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing100049, PR China
Xiaowen Wang
Affiliation:
Key Laboratory of Clay Mineral Applied Research of Gansu Province, Center of Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou730000, PR China
Li Zong
Affiliation:
Key Laboratory of Clay Mineral Applied Research of Gansu Province, Center of Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou730000, PR China
Aiqin Wang*
Affiliation:
Key Laboratory of Clay Mineral Applied Research of Gansu Province, Center of Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou730000, PR China

Abstract

A hybrid fluorescent pigment composed of fluorescent yellow X-10GFF (FY-10G) and palygorskite (PLG) was prepared by semi-dry grinding. The effects of the physically adsorbed water content and grinding time on the environmental stability of FY-10G/PLG hybrid fluorescent pigments in terms of acid, ethanol and ultraviolet irradiation are discussed in detail. The incorporated FY-10 G molecules are mainly trapped on the external surface and the groove of PLG. Due to the host–guest interaction between PAL and FY-10G, the emission spectrum of the FY-10G/PLG hybrids shifts to a greater wavelength compared with that of FY-10G, but the physically adsorbed water content and grinding time have no effect on the position of the emission spectrum except for its intensity. A larger, physically adsorbed water content and appropriate grinding time may effectively prevent the aggregation and breakage of the bundles of PLG and facilitate FY-10 G molecules to enter into the groove of PAL. This increases the environmental stability of the as-prepared hybrid pigments.

Type
Article
Copyright
Copyright © The Author(s), 2021. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Chun Hui Zhou

This paper was submitted for the special issue “Clays and Functional Materials” and was presented at the Asian Clay Conference, Singapore, 2020.

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