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Geochemical and mineralogical approaches to assessing provenance and deposition of shales: a case study

Published online by Cambridge University Press:  09 July 2018

F. Cavalcante*
Affiliation:
Institute of Methodologies for Environmental Analyses, Laboratory of Geochemistry and Environmental Mineralogy, CNR 85050 TitoScalo(PZ)
S. Fiore
Affiliation:
Institute of Methodologies for Environmental Analyses, Laboratory of Geochemistry and Environmental Mineralogy, CNR 85050 TitoScalo(PZ)
G. Piccarreta
Affiliation:
Department of Geomineralogy, University of Bari, Via Orabona 4, 70125, Bari
F. Tateo
Affiliation:
Institute of Geosciences and Earth Resources, CNR c/o Department of Geological Sciences, Via Giotto, 1, 35137, PadovaItaly
*
*E-mail: fiore@imaa.cnr.it

Abstract

Mineralogical and geochemical studies of Cretaceous segments of Argille Varicolori and Flysch Rosso successions from the southern Apennines allow their provenance and history to be evaluated.

The occurrence of detrital kaolinite and fine-grained Fe-oxyhydroxides, the strong depletion of Na2O, K2O and CaO, and the enrichment in the transition elements document severe alteration in the source areas. Nevertheless, mineralogical and geochemical features able to discriminate the shale families are still preserved. The presence/absence of rock fragments derived from a ‘crystalline’ source, the significant chemical differences as well as the characteristics of clay minerals, discriminate the studied shales. The absence of indications suggestive of mixing of the detrital components favour the hypothesis that the two shales were deposited in distinct basins which probably received contributions from continent-ocean convergent areas (Argille Varicolori) and from more stable areas (Flysch Rosso).

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2003

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References

Acquafredda, P., Fornelli, A., Piccarreta, G. & Summa, V. (1997) Provenance and tectonic implications of heavy minerals in Pliocene-Pleistocene siliciclastic sediment s of the southern Apennine s, Italy. Sedimentary Geology, 113, 149159.CrossRefGoogle Scholar
Amodio Morelli, L., Bonari, G., Colonna, V., Dietrich, D., Giunta, G., Ippolito, F., Liguori, V., Lorenzoni, S., Paglionico, A., Perrone, V., Piccarreta, G., Russo, M., Scandone, P., Zanettin Lorenzoni, E. & Zappetta, A. (1976) L’arco calabro peloritano nell’orogene appennini co-magre bide. Memorie della Società Geologica Italiana, 17, 1160.Google Scholar
Bathia, M.R. (1985) Rare earth element geochemistry of Australian Palaeozoic graywackes and mudrocks: provenance and tectonic control. Sedimentary Geology, 45, 97113.Google Scholar
Bathia, M.R. & Crook, K.A.W. (1986) Trace element characteristics of graywackes and tectonic setting discrimination of sedimentary basins. Contributions to Mineralogy and Petrology, 92, 181193.Google Scholar
Bonardi, G., D’Argenio, B. & Perrone, V. (1988) Carta geologica dell’Appennino meridionale alla scala 1:250.000. Memorie della Società Geologica Italiana, 41, 1341.Google Scholar
Bonini, M. & Sani, F. (2000) Thrusting, strike-slip faulting and syntectonic deposition in the Potenza Guardia Perticara Area (Basilic ata, Southern Apennines, I taly). Memorie de l la Soc ietà Geologica Italiana, 55, 123132.Google Scholar
Boullin, J.P., Durand-Delga, M. & Oliver, P. (1986) Betic- Rifain and Thyrrenian arcs: distinctive features, genesis and development stages. Pp. 281304 in: The Origin of Arcs(Wezel, F.C., editor). Elsevier, Amsterdam.Google Scholar
Carbone, S., Monaco, S., Lazzari, S., Lentini, F. & Monaco, C. (1991) Presentazione della carta geologica del bacino del fiume Agri (Basilicata). Memorie della Società Geologica Italiana, 47, 129143.Google Scholar
Casero, P., Roure, F., Endignoux, L., Moretti, I., Muller, C., Sage, L. & Vialli, R. (1988) Neogene geodynamic evolution of the southern Apennines. Memorie della Società Geologica Italiana, 41, 109120.Google Scholar
Chamley, H. (1989. Clay Sedimentology. Springer- Verlag, Berlin.CrossRefGoogle Scholar
Channel, J.E.T., D’Argenio, B. & Horvarth, H.F. (1979) Adria, the African promontory, in Mesozoic Mediterranean paleogeography: a review. Earth Science Reviews, 15, 213292.Google Scholar
Cifelli, F. (1999) Elementi per la ricostruzione stratigrafica delle successioni bacinali cretacico-paleogeniche affioranti nell’Appennino lucano. PhD thesis, Univ. di Bari, Italy.Google Scholar
Condie, K.C. (1993) Chemical composition and evolution of the upper continental crust: contrasting results from surface samples and shales. Chemical Geology, 104, 137.Google Scholar
D’Argenio, B., Pescatore, T. & Scandone, P. (1975) Structural pattern of the Campania-Lucania Apennines. Quaderni de ‘ La Ricerca Scientifica’, 90, 313327.Google Scholar
Dellisanti, F., Minguzzi, V., Tateo, F., Chiari, M., Cifelli, F., Coccioni, R. & Morandi, N. (2001) Preliminary mineralogical and geochemical data of the Selli level near Albano di Lucania (PZ, Italy). 3º Forum Italiano di Scienze della Terra, Chieti, 656657.(abstract).Google Scholar
Dietrich, D. (1988) Sense of overthrust shear in the Alpine nappes of Calabria (Southern Italy). Journal of Structural Geology, 10, 373381.CrossRefGoogle Scholar
Dunoyer de Segonzac, G. (1970) The transformation of clay minerals during diagenesis and low-grade metamorphism: a review. Sedimentol ogy, 15, 281346.CrossRefGoogle Scholar
Evensen, N.M., Hamilton, P.J. & O’Nions, R.K. (1978) Rare-earth abundances in chondritic meteorites. Geochimica et Cosmochimica Acta, 42, 11991212.Google Scholar
Fedo, C.M., Eriksson, K.A. & Krongstad, E.J. (1996) Geochemistry of shales from the Archean (∼3.0 Ga) Buhwa Greenstone Belt, Zimbabwe: Implications for provenance and source-area weathering. Geochimica et Cosmochimica Acta, 60, 17511763.Google Scholar
Finetti, I., Lentini, F., Carbone, S., Monaco, S. & Del Ben, A. (1996) Il sistema appenninico meridionale – Arco calabro – Sicilia nel Mediterraneo centrale: Studio Geologico geofisico. Bollettino della Società Geologica Italiana, 115, 529559.Google Scholar
Fiore, S., Piccarreta, G., Santaloia, F., Santarcangelo, R. & Tateo, F. (2000a) The Flysch Rosso shales from the Southern Apennines, Italy. 1. Mineralogy and geochemistry. Periodico di Mineralogia, 69, 6378.Google Scholar
Fiore, S., Piccarreta, G., Tateo, F. & Santaloia, F. (2000b) The Flysch Rosso shales from the Southern Apennines, Italy. 2. The origin of the colour. Periodico di Mineralogia, 69, 7987.Google Scholar
Gallicchio, S., Marcucci, M., Pieri, P., Premoli Silva, I., Sabato, L. & Salvini, G. (1996) Stratigraphical data from a Cretaceous claystones sequence of the “Argille varicolori” in the Southern Apennines (Basilicata, Italy). Palaeopelagos, 6, 261272.Google Scholar
Harnois, L. (1988) The CIW index: A new chemical index of weathering. Sedimentary Geology, 55, 319322.CrossRefGoogle Scholar
Hassan, S., Ishiga, H., Roser, B.P., Dozen, K. & Naka, T. (1999) Geochemistry of Permian-Triassic shales in the Salt Range, Pakistan: implications for provenance and tectonism at the Gondwana margin. Chemical Geology, 158, 293314.Google Scholar
Hower, J., Eslinger, E.V., Hower, M.E. & Perry, E.A. (1976) Mechanism of burial metamorphism of argillaceous sediments: 1. Mineralogical and chemical evidence. Geological Society of America Bulletin, 87, 725737.Google Scholar
Krumm, S. (1997. WinFit: a computer program. www.geol.uni - erlangen.de/html/software/ winsoft.htmlGoogle Scholar
Marsella, E., Balli, A.W., D’Argenio, B., Cippitelli, G. & Pappone, G. (1995) The paleogeographic position of the Lagonegro Domain, Southern Apennines. Tectonophysics, 252, 307330.Google Scholar
McLennan, S.M. & Taylor, S.R. (1991) Sedimentary rocks and crustal evolution: Tectonic setting and secular trends. Journal of Geology, 99, 121.Google Scholar
McLennan, S.M., Taylor, S.R., McCullock, M.T. & Maynard, J.B. (1990) Geochemical and Nd-Sr isotopic composition of deep-sea turbidites: crustal evolution and plate tectonic associations. Geochimica et Cosmochimica Acta, 54, 20152050.Google Scholar
McLennan, S.M., Hemming, S., McDaniel, D.K. & Hanson, G.N. (1993) Geochemical approaches to sedimentation, provenance and tectonics. Pp. 2140 in: Processes Controlling the Composition of Clastic Sediments(Johnsson, M.J. & Basu, A., editors). Geological Society of America, Special paper, 284.CrossRefGoogle Scholar
Monaco, C. & Tortorici, L. (1995) Tectonic role of ophiolite-bearing terranes in the development of the Southern Apennines orogenic belt. Terra Nova, 7, 153160.CrossRefGoogle Scholar
Mongelli, G., Cullers, R.L. & Muelheiesen, S. (1996) Geochemistry of Late Cretaceous-Oligocenic shales from the Varicolori Formation, southern Apennines, Italy: implication for mineralogical, grain-size control and proven ance. Europea n Journa l of Mineralogy, 8, 733754.Google Scholar
Moore, D.M. & Jr.Reynolds, R.C., (1997) X-ray Diffraction and the Identification and Analysis of Clay Minerals, 2nd edition. Oxford University Press, Oxford, UK, and New York.Google Scholar
Mostardini, F. & Merlini, S. (1986) Appennino centromeridionale: Sezioni geologiche e proposta di modello strutturale. Memorie della Societ à Geologica Italiana, 35, 177202.Google Scholar
Nesbitt, H.W. & Young, G.M. (1982) Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature, 299, 715717.Google Scholar
Ogniben, L. (1969) Schema introduttivo alla geologia del confine calabro-lucano. Memorie della Società Geologica Italiana, 8, 453763.Google Scholar
Patacca, E., Sartori, R. & Scandone, P. (1990) Thyrrenian basin and apenninic arcs: Kinematic relation since late Tortonian times. Memorie della Società Geologica Italiana, 45, 425451.Google Scholar
Pescatore, T., Renda, P. & Tramutoli, M. (1988) Rapporti tra le Unità Lagonegresi e le Unità Sicilidi nella media valle del Basento, Lucania (Appennino Meridionale). Memorie della Società Geologica Italiana, 41, 353356.Google Scholar
Pescatore, T., Renda, P., Schiattarella, M. & Tramutoli, M. (1999) Stratigraphic and structural relations between Meso-Cenozoic Lagonegro basin and coeval carbonate platform in southern Apennine s, Italy. Tectonophysics, 315, 269286.Google Scholar
Philip, J., Babinot, J.F., Tronchetti, G., Fourcade, E., Guiraud, R., Bellion, Y., Herbin, J.P., Combes, P.J., Cornee, J., Dercourt, J. & Ricou, L.E. (1993) Late Cenomanian (94 –92 Ma). Pp. 153178 in: Atlas Tethys Paleoenvironmental Maps (Dercourt, J., Ricou, L.E. & Vrielynck, B., editors). Gauthiers-Villars, Paris.Google Scholar
Pollastro, R.M. (1993) Consideration and applications of the illite-smectite geothermometer in hydrocarbonbearing rocks of Miocene to Mississippian age. Clays and Clay Minerals, 41, 119133.Google Scholar
Jr.Reynolds, R.C., (1985) NEWMOD: a computer program for the calculation of the basal diffraction intensities of mixed-layered clay minerals.Reynolds, R.C., 8 Brook Rd. Hanover, NH, USA.Google Scholar
Roser, B.P. & Korsch, R.J. (1986) Determination of tectonic setting of sandstone-mudstone suites using SiO2 content and K2O/Na2O ratio. Journal of Geology, 94, 635650.Google Scholar
Roser, B.P. & Korsch, R.J. (1988) Provenance signatures of sandstone-mudstone suites determined using discriminant function analysis of major-element data. Chemical Geology, 67, 119139.Google Scholar
Scandone, P. (1972) Studi di geologia lucana: Carta dei terreni della serie calcareo-silico-marnosa e note illustrative. Bollettino della Società Naturalisti in Napoli, 81, 225300.Google Scholar
Środoń, J. & Clauer, N. (2001) Diagenetic history of Lower Palaeozoic sediments in Pomerania (northern Poland), traced across the Teisseyre-Tornquist tectonic zone using mixed-layer illite-smectite. Clay Minerals, 36, 1527.CrossRefGoogle Scholar
Taylor, S.R. & McLennan, S.M. (1985) The Continental Crust: Its Composition and Evolution. Blackwell Scientific Publications, Oxford, UK.Google Scholar
Wronkiewicz, D.J. & Condie, K.C. (1987) Geochemistry of Archean shales from the Witwatersran d Supergroup, South Africa: source-area weathering and provenance. Geochimica et Cosmochimica Acta, 51, 24012416.Google Scholar