Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-10T14:49:16.080Z Has data issue: false hasContentIssue false
  • English
  • Français

Geology and properties of the Kawasaki and Dobuyama bentonite deposits of Zao region in northeastern Japan

Published online by Cambridge University Press:  09 July 2018

T. Takagi ,
S. M. Koh ,
M. S. Song ,
M. Itoh  and
K. Mogi
T. Takagi*
Affiliation:
Research Center for Deep Geological Environments, Geological Survey of Japan, National Institute of Advanced Industrial Science and Technology (AIST), Central-7, 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8567 Japan
S. M. Koh
Affiliation:
Geology and Geoinformation Division, Korea Institute of Geoscience andMineral Resources (KIGAM), 30 Gajung-dong, Yusung-gu, Daejeon 305-350, Korea
M. S. Song
Affiliation:
Geology and Geoinformation Division, Korea Institute of Geoscience andMineral Resources (KIGAM), 30 Gajung-dong, Yusung-gu, Daejeon 305-350, Korea
M. Itoh
Affiliation:
Kunimine Industries Co., Ltd., 1-10-5, Iwamoto-cho, Chiyoda-ku, Tokyo, 101-0032 Japan
K. Mogi
Affiliation:
Kunimine Industries Co., Ltd., 1-10-5, Iwamoto-cho, Chiyoda-ku, Tokyo, 101-0032 Japan
*
*E-mail: takagi-t@aist.go.jp
Get access Rights & Permissions [Opens in a new window]

Abstract

The Kawasaki and Dobuyama bentonite deposits in northeastern Japan show contrasting properties even though they are only 5 km apart in a sequence of Neogene sedimentary and pyroclastic rocks. The Kawasaki deposit consists of stratiform bentonite layers up to >50 m thick, and its wall rocks are unaltered shallow marine sedimentary rocks. In contrast, the Dobuyama deposit consists of a funnel-shaped ore body 200 m across, and its wall rocks are hydrothermally altered terrestrial rhyolitic pyroclastic rocks. The Kawasaki and Dobuyama bentonites mainly consist of Na-Ca smectite and Ca smectite, respectively, with subordinate opal-CT, quartz and zeolite. The geological occurrences of the deposits and wall-rock properties suggest that the Kawasaki and Dobuyama deposits were probably formed by diagenesis and low-temperature hydrothermal alteration, respectively. The difference in exchangeable cation ratios of the smectite between the two deposits is attributable to the difference in their sedimentary environments and/or burial depth.

Keywords

clay mineralsbentoniteNeogenediagenesishydrothermal alterationexchangeable cationsupergene processJapan
Type
Research Article
Information
Clay Minerals , Volume 40 , Issue 3 , September 2005 , pp. 333 - 350
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bjørlykke, K. (1997) Lithological control on fluid flow in sedimentary basins. Pp. 15–34 in: Fluid Flow and Transport in Rocks, Mechanisms and Effect. (B. Jamtveit and B.W.D. Yardley, editors). Chapman & Hall, London.Google Scholar
Christidis, G.E. (1998) Physical and chemical properties of some bentonite deposits of Kimolos Island, Greece. Applied Clay Science. 13, 79–98.Google Scholar
Christidis, G.E., Scott, P.W. & Marcopoulos, T. (1995) Origin of the bentonite deposits of eastern Milos, Agean, Greece: Geological, mineralogical and geochemical evidence. Clays and Clay Minerals. 43, 63–77.Google Scholar
Cole, T.G. & Shaw, H.F. (1983) The nature and origin of authigenic smectites in some recent marine sediments. Clay Minerals. 18, 239–252.Google Scholar
Davis, S.N. & DeWiest, R.J.M. (1966) Water quality. Pp. 96-128 in: Hydrogeology. John Wiley & Sons, New York.Google Scholar
Grim, R.E. & Guven, N. (1978) Bentonite, Geology, Mineralogy, Properties and Uses. Developments in Sedimentology, 24, Elsevier, Amsterdam, 256 pp.Google Scholar
Hosterman, J.W. & Patterson, S.H. (1992) Bentonite and fuller's earth resources of the United States. US Geological Survey Professional Paper. 1522, 45 pp.CrossRefGoogle Scholar
Ishii, T., Itoh, M., Nakashima, H., Sugawara, H., Ohe, T. & Hirata, Y. (1998) The long-term degradation rate in natural bentonite formations according to the field data. Clay Science. 38, 10–22 (in Japanese with English abstract).Google Scholar
Itoh, M., Ishii, T., Nakashima, H. & Hirata, Y. (1999) The study of genesis and formation condition of bentonite. Clay Science. 38, 181–187 (in Japanese with English abstract).Google Scholar
Jeans, C.V., Merriman, R.J. & Mitchell, J.G. (1977) Origin of middle Jurassic and lower Cretaceous fuller's earth in England. Clay Minerals. 12, 11–44.Google Scholar
Nevins, M.J. & Weintritt, D.J. (1967) Determination of cation exchange capacity by methylene blue adsorption. Bulletin of the American Ceramic Society. 46, 587–592.Google Scholar
Ohe, T., Itoh, M., Ishii, T., Nakashima, H., Hirata, Y. & Yoshida, H. (1998) The long-term alteration rate of Na-smectite in natural bentonite formation. Journal of Contaminant Hydrology. 35, 285–294.Google Scholar
Ohe, T., Ishii, T., Itoh, M., Nakashima, H. & Hirata, Y. (1999) The long-term alteration rate of Na-smectite to Ca-form in the bentonite deposit evaluated by a cation diffusion-conversion model. Clay Science. 38, 220–232 (in Japanese with English abstract).Google Scholar
Ossaka, J., Hirabayashi, J., Okada, K. & Kato, M. (1981) The occurrence and its chemical composition changes in the Dobuyama montmorillonite deposit, Miyagi Prefecture. Journal of the Mineralogical Society of Japan. 15, 170–186 (in Japanese with English abstract).Google Scholar
Otsuki, K., Saito, T. and Yoshida, T. (1986) Island arc transection route No. 24. In: Geological data files on Neogene of Northeast Japan Ar. (S. Kitamura, editor), 3(3), 19 pp. (in Japanese).Google Scholar
Sato, H. (1994) The relationship between late Cenozoic tectonic events and stress field and basin development in northeast Japan. Journal of Geophysical Research. 99, Bll, 22261-22274.Google Scholar
Sato, H. & Amano, K. (1991) Relationship between tectonics, volcanism, sedimentation and basin development, Late Cenozoic, central part of Northern Honshu, Japan. Sedimentary Geology. 74, 323–343.Google Scholar
Slaughter, M. & Earley, J.W. (1965) Mineralogy and geological significance of the Mowry bentonites, Wyoming. Geological Society of America, Special Paper. 83, 95 pp.Google Scholar
Song, M.S., Koh, S.M. & Takagi, T. (2004) Occurrences and physicochemical properties of Japanese bentonite deposits. Journal of the Mineralogical Society of Korea. 17, 245–265 (in Korean with English abstract).Google Scholar
Uno, Y. & Takeshi, H. (1979) Exchange cations and structural formulae of montmorillonites in the Nakajo acid clay deposit, Niigata Prefecture. Journal of the Mineralogical Society of Japan. 14, 90–103 (in Japanese with English abstract).CrossRefGoogle Scholar
Vogt, K. & Koster, H.M. (1978) Zur mineralogie, kristallchemie und geochemie einiger montmorillonite aus bentoniten. Clay Minerals. 13, 25–43.Google Scholar
Watanabe, T. & Sato, T. (1988) Expansion characteristics of montmorillonite and saponite under various relative humidity conditions. Clay Science. 7, 129–138.Google Scholar
Williams, L.A., Parks, G.A. & Crerar, D.A. (1985) Silica diagenesis, I. Solubility controls. Journal of Sedimentary Petrology. 55, 301–311.Google Scholar
Yalçin, K. & Gümüşer, G. (2000) Mineralogical and geochemical characteristics of late Cretaceous bentonite deposits of the Kelkit valley region, northern Turkey. Clay Minerals. 35, 807–824.CrossRefGoogle Scholar
Yamaji, A. & Sato, H. (1989) Miocene subsidence of the Northeast Honshu Arc and its mechanism. Memoirs of the Geological Society of Japan. 32, 339–349 (in Japanese with English abstract).Google Scholar
Yildiz, A. & Kuscu, M. (2004) Origin of the Basoren (Kutahya W Turkey) bentonite deposits. Clay Minerals. 39, 219–231.Google Scholar