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Iron catalyst supported on modified kaolin for catalytic wet peroxide oxidation

Published online by Cambridge University Press:  29 March 2019

Ali Boukhemkhem ,
Kamel Rida ,
Alejandro H. Pizarro ,
Carmen B. Molina Open the ORCID record for Carmen B. Molina [Opens in a new window]  and
Juan J. Rodriguez
Ali Boukhemkhem
Affiliation:
Laboratory Interactions Materials–Environment (LIME), University Mohamed Seddik Ben Yahia, Jijel, 18000, Algeria
Kamel Rida
Affiliation:
Laboratory Interactions Materials–Environment (LIME), University Mohamed Seddik Ben Yahia, Jijel, 18000, Algeria
Alejandro H. Pizarro
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Spain
Carmen B. Molina*
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Spain
Juan J. Rodriguez
Affiliation:
Chemical Engineering Department, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco, 28049, Spain
*
*E-mail: carmenbelen.molina@uam.es
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Abstract

An iron catalyst supported on the modified Tamazert kaolin has been prepared and tested in catalytic wet peroxide oxidation using phenol and 4-chlorophenol (4-CP) as target compounds (100 mg/L initial concentration). Kaolin is not usually employed as a catalytic support due to its low developed porous structure, but its textural properties may be improved upon calcination and acid and basic treatment. The catalyst was characterized by N2 adsorption–desorption and chemical analysis by total-reflection X-ray fluorescence spectroscopy. The catalytic tests were carried out in a batch reactor with a stoichiometric amount of H2O2. The catalytic efficiency was studied within the temperature range of 25–55°C at an initial pH of 3.3 and 1 g/L catalyst. Complete phenol and 4-CP removal was achieved with no significant differences in phenol and 4-CP conversions within the temperature range tested. Meanwhile, total organic carbon (TOC) reduction was greatly favoured by increasing the temperature, which may be partially attributed to a probable contribution of a homogeneous reaction associated with iron leaching. However, this effect might be of limited significance because the highest concentrations of iron in the liquid phase were below 4.5 and 8.5 mg/L in the experiments with phenol and 4-CP, respectively. At 55°C, TOC was reduced by ~70% after 4 h reaction time, with the remaining by-products corresponding almost completely to low-molecular-weight carboxylic acids of very low ecotoxicity.

Keywords

Tamazert kaolinchemical activationiron catalystCWPOphenol4-chlorophenol
Type
Article
Information
Clay Minerals , Volume 54 , Issue 1 , March 2019 , pp. 67 - 73
Copyright
© Mineralogical Society of Great Britain and Ireland 2019 

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Footnotes

Associate Editor: M. Pospisil

References

Auta, M. & Hameed, B.H. (2012) Modified mesoporous clay adsorbent for adsorption isotherm and kinetics of methylene blue. Chemical Engineering Journal, 198–199, 219–227.Google Scholar
Ayodele, O.B., Lim, J.K. & Hameed, B.H. (2012) Degradation of phenol in photo-Fenton process by phosphoric acid modified kaolin supported ferric-oxalate catalyst: optimization and kinetic modeling. Chemical Engineering Journal, 197, 181–192.Google Scholar
Bautista, P., Mohedano, A.F., Casas, J.A., Zazo, J.A. & Rodriguez, J.J. (2011) Highly stable Fe/γ-Al2O3 catalyst for catalytic wet peroxide oxidation. Journal of Chemical Technology & Biotechnology, 86, 497–504.Google Scholar
Boukhemkhem, A. & Rida, K. (2017) Improvement adsorption capacity of methylene blue onto modified Tamazert kaolin. Adsorption Science and Technology, 35(9–10), 753–773.Google Scholar
Carriazo, J., Guelou, E., Barrault, J., Tatibouët, J.M., Molina, R. & Moreno, S. (2005) Catalytic wet peroxide oxidation of phenol by pillared clays containing Al–Ce–Fe. Water Research, 39, 3891–3899.Google Scholar
Catrinescu, C., Arsene, D. & Teodosiu, C. (2011) Catalytic wet hydrogen peroxide oxidation of para-chlorophenol over Al/Fe pillared clays (AlFePILCs) prepared from different host clays. Applied Catalysis B: Environmental, 101, 451–460.Google Scholar
Catrinescu, C., Arsene, D., Apopei, P. & Teodosiu, C. (2012) Degradation of 4-chlorophenol from wastewater through heterogeneous Fenton and photo-Fenton process catalyzed by Al–Fe PILC. Applied Clay Science, 58, 96–101.Google Scholar
Deka, B. & Bhattacharya, B.G. (2015) Using coal fly ash as a support for Mn(II), Co(II) and Ni(II) and utilizing the materials as novel oxidation catalysts for 4-chlorophenol mineralization. Journal of Environmental Management, 150, 479–488.Google Scholar
Dominguez, C.M., Quintanilla, A., Casas, J.A. & Rodriguez, J.J. (2014) Kinetics of wet peroxide oxidation of phenol with a gold/activated carbon catalyst. Chemical Engineering Journal, 253, 486–492.Google Scholar
Duan, F., Yang, Y., Li, Y., Cao, H., Wang, Y & Zhang, Y. (2014) Heterogeneous Fenton-like degradation of 4-chlorophenol using iron/ordered mesoporous carbon catalyst. Journal of Environmental Sciences, 26, 1171–1179.Google Scholar
Eisenberg, G. (1943) Colorimetric determination of hydrogen peroxide. Industrial and Engineering Chemistry Analytical Edition, 15(5), 327–328.Google Scholar
EPA (1982) 40 CFR 423, Appendix A. Clean Water Act.Google Scholar
European Parliament (2008) European Directive 2008/105/EC. European Parliament and of the Council of 16 December 2008. Annex II. List of Priority Substances in the Field of Water Policy.Google Scholar
Gao, Z., Li, X., Wu, H., Zhao, S., Deligeer, W. & Asuha, S. (2015) Magnetic modification of acid-activated kaolin: synthesis, characterization, and adsorptive properties. Microporous and Mesoporous Materials, 202, 1–7.Google Scholar
Gao, W., Zhao, S., Wu, H., Deligeer, W. & Asuha, S. (2016) Direct acid activation of kaolinite and its effects on the adsorption of methylene blue. Applied Clay Science, 126, 98–106.Google Scholar
Garcıa-Molina, V., Lopez-Arias, M., Florczyk, M., Chamarro, E. & Esplugas, S. (2005) Wet peroxide oxidation of chlorophenols. Water Research, 39, 795–802.Google Scholar
Hailing, L., Pingxiao, W., Zhi, D., Nengwu, Z. & Ping, L. (2011) Synthesis, characterization, and visible-light photo-Fenton catalytic activity of hydroxy Fe/Al-intercalated montmorillonite. Clays and Clay Minerals, 59(5), 466–477.Google Scholar
Horikawa, T., Do, D.D. & Nicholson, D. (2011) Capillary condensation of adsorbates in porous materials. Advances in Colloid and Interface Science, 169, 40–58.Google Scholar
Jozefaciuk, G. & Bowanko, B. (2002) Effect of acid and alkali treatments on surface areas and adsorption energies of selected minerals. Clays and Clay Minerals, 50(6), 771–783.Google Scholar
Inchaurrondo, N.S., Massa, P., Fenoglio, R., Font, J. & Haure, P. (2012) Efficient catalytic wet peroxide oxidation of phenol at moderate temperature using a high-load supported copper catalyst. Chemical Engineering Journal, 198–199, 426–434.Google Scholar
Khanikar, I. & Bhattacharyya, K.G. (2013) Cu(II)-kaolinite and Cu(II)-montmorillonite as catalysts for wet oxidative degradation of 2-chlorophenol, 4-chlorophenol and 2,4-dichlorophenol. Chemical Engineering Journal, 233, 88–97.Google Scholar
Kosa, S.A., El Maksod, I.H.A., Alkhateeb, L. & Hegazy, E.Z. (2012) Preparation and surface characterization of CuO and Fe2O3 catalyst. Applied Surface Science, 258, 7617–7624.Google Scholar
Kurian, M., Nair, D.S. & Rahnamol, A. M. (2014) Influence of the synthesis conditions on the catalytic efficiency of NiFe2O4 and ZnFe2O4 nanoparticles towards the wet peroxide oxidation of 4-chlorophenol. Reaction Kinetics Mechanisms and Catalysis, 111, 591–604.Google Scholar
Leal, T.W., Lourenço, L.A., Brandao, H.L., da Silva, A., Souza, S.M.A.G.U. & Souza, A.A.U. (2018) Low-cost iron-doped catalyst for phenol degradation by heterogeneous Fenton. Journal of Hazardous Materials, 395, 96–103.Google Scholar
Molina, C.B., Zazo, J.A., Casas, J.A. & Rodrıguez, J.J. (2010a) CWPO of 4-CP and industrial wastewater with Al–Fe pillared clays. Water Science and Technology, 61(8), 2161–2168.Google Scholar
Molina, C.B., Pizarro, A.H. Monsalvo, V.M., Polo, A.M., Mohedano, A.F., & Rodrıguez, J.J. (2010b) Integrated CWPO and biological treatment for the removal of 4-chlorophenol from water. Separation Science and Technology, 45, 1595–1602.Google Scholar
Molina, C.B., Casas, J.A., Pizarro, A.H. & Rodriguez, J.J. (2011) Pillared clays as green chemistry catalysts: application to wastewater treatments. Pp. 435–474 in: Clay: Types, Properties and Uses (Humphrey, J.P. & Boyd, D.D., editors). Nova Science Publishers, Inc., New York, NY, USA.Google Scholar
Munoz, M., de Pedro, Z.M., Casas, J.A. & Rodriguez, J.J. (2013) A ferromagnetic γ-alumina-supported iron catalyst for CWPO. Application to chlorophenols. Applied Catalysis B: Environmental, 136–137, 218–224.Google Scholar
Munoz, M., Dominguez, P., de Pedro, Z.M., Casas, J.A. & Rodriguez, J.J. (2017) Naturally-occurring iron minerals as inexpensive catalysts for CWPO. Applied Catalysis B: Environmental, 203, 166–173.Google Scholar
Oxana, T.P., Artemiy, B.A., Olga, L.O., Prosvirin, I P., Isupova, L.A. & Parmon, V.N. (2016) Perovskite-like catalysts LaBO3 (B = Cu, Fe, Mn, Co, Ni) for wet peroxide oxidation of phenol. Applied Catalysis B: Environmental, 180, 86–93.Google Scholar
Pan, W., Fang, B.X. & Xin, L.Y. (2012) Catalytic oxidation of phenol in wastewater. A new application of the amorphous Fe78Si9B13 alloy. Chinese Science Bulletin, 57, 33–40.Google Scholar
Peraira, M.C., Tavares, C.M., Fabris, J.D., Lago, R.M., Murad, E. & Criscuolo, P.S. (2007) Characterization of a tropical soil and a waste from kaolin mining and their suitability as heterogeneous catalysts for Fenton and Fenton-like reactions. Clay Minerals, 42, 299–306.Google Scholar
Sanabria, N.R., Centeno, M.A., Molina, R. & Moreno, S. (2009) Pillared clays with Al–Fe and Al–Ce–Fe in concentrated medium: synthesis and catalytic activity. Applied Catalysis A: General, 356, 243–249.Google Scholar
Saywell, L.G. & Cunningham, B.B. (1937) Determination of iron: colorimetric o-phenanthroline method. Industrial and Engineering Chemistry Analytical Edition, 9(2), 67–69.Google Scholar
Tatibouët, J.-M., Guélou, E. & Fournier, J. (2005) Catalytic oxidation of phenol by hydrogen peroxide over a pillared clay containing iron. Active species and pH effect. Topics in Catalysis, 33, 225–232.Google Scholar
Tomul, F. (2012) Adsorption and catalytic properties of Fe/Cr-pillared bentonites. Chemical Engineering Journal, 185–186, 380–390.Google Scholar
Tomul, F. (2016) The effect of ultrasonic treatment on iron–chromium pillared bentonite synthesis and catalytic wet peroxide oxidation of phenol. Applied Clay Science, 120, 121–134.Google Scholar
Valkaj, K.M., Katovic, A. & Zrncevic, S. (2007) Investigation of the catalytic wet peroxide oxidation of phenol over different types of Cu/ZSM-5 catalyst. Journal of Hazardous Materials, 144, 663–667.Google Scholar
Valverde, J.L., Romero, A., Romero, R., García, P.B., Sánchez, M.L. & Asencio, I. (2005) Preparation and characterization of Fe-PILCs. Influence of the synthesis parameters. Clays and Clay Minerals, 53(6), 613–621.Google Scholar
Volzone, C. & Ortiga, J. (2006) Removal of gases by thermal-acid leached kaolinitic clays: influence of mineralogical composition. Applied Clay Science, 32, 87–93.Google Scholar
Wei, G.T., Li, Y.S., Zhang, L.Y., Li, Z.M., Deng, Y., Shao, L.H. & Mo, J.H. (2017) Effect of mechanical activation on catalytic properties of Fe2O3-pillared bentonite for Fenton-like reaction. Clay Minerals, 52, 439–451Google Scholar
Yavuz, Ö. & Saka, C. (2013) Surface modification with cold plasma application on kaolin and its effects on the adsorption of methylene blue. Applied Clay Science, 85, 96–102.Google Scholar
Zazo, J.A., Casas, J.A., Mohedano, A.F., Gilarranz, M.A. & Rodriguez, J.J. (2005) Chemical pathway and kinetics of phenol oxidation by Fenton's reagent. Environmental Science and Technology, 39(23), 9295–9302.Google Scholar
Zazo, J.A., Casas, J.A., Mohedano, A.F. & Rodriguez, J.J. (2006) Catalytic wet peroxide oxidation of phenol with a Fe/active carbon catalyst. Applied Catalysis B: Environmental, 65(3–4), 261–268.Google Scholar
Zazo, J.A., Casas, J.A., Molina, C.B., Quintanilla, A. & Rodriguez, J.J. (2007) Evolution of ecotoxicity upon Fenton's oxidation of phenol in water. Environmental Science & Technology, 39(23), 9295–9302.Google Scholar
Zazo, J.A., Pliego, G., Blasco, S., Casas, J.A. & Rodriguez, J.J. (2011) Intensification of the Fenton process by increasing the temperature. Industrial and Engineering Chemistry Research, 50, 866–870.Google Scholar
Zhang, S., Zhao, X., Niu, H., Shi, Y & Jiang, G. (2009) Superparamagnetic Fe3O4 nanoparticles as catalysts for the catalytic oxidation of phenolic and aniline compounds. Journal of Hazardous Materials, 167(1–3), 560–566.Google Scholar
Zhou, S., Gu, C., Qian, Z., Xu, J., Xia, C. (2011) The activity and selectivity of catalytic peroxide oxidation of chlorophenols over Cu–Al hydrotalcite/clay composite. Journal of Colloid and Interface Science, 357, 447–452.Google Scholar
Zhou, S., Zhang, C., Hu, X., Wang, Y., Xu, R., Xia, C., Zhang, H. & Song, Z. (2014) Catalytic wet peroxide oxidation of 4-chlorophenol over Al-Fe-, Al-Cu- and Al-Fe-Cu-pillared clays. Sensitivity, kinetics and mechanism. Applied Clay Science, 95, 275–283.Google Scholar