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Isomerization of limonene over natural zeolite-clinoptilolite

Published online by Cambridge University Press:  22 April 2019

Monika Retajczyk ,
Agnieszka Wróblewska Open the ORCID record for Agnieszka Wróblewska [Opens in a new window] ,
Alicja Szymańska  and
Beata Michalkiewicz
Monika Retajczyk
Affiliation:
West Pomeranian University of Technology, Faculty of Chemical Technology and Engineering, Institute of Organic Chemical Technology, Pułaskiego 10, PL 70-322 Szczecin, Poland
Agnieszka Wróblewska*
Affiliation:
West Pomeranian University of Technology, Faculty of Chemical Technology and Engineering, Institute of Organic Chemical Technology, Pułaskiego 10, PL 70-322 Szczecin, Poland
Alicja Szymańska
Affiliation:
West Pomeranian University of Technology, Faculty of Chemical Technology and Engineering, Institute of Inorganic Chemical Technology and Environment Engineering, Pułaskiego 10, PL 70-322 Szczecin, Poland
Beata Michalkiewicz
Affiliation:
West Pomeranian University of Technology, Faculty of Chemical Technology and Engineering, Institute of Inorganic Chemical Technology and Environment Engineering, Pułaskiego 10, PL 70-322 Szczecin, Poland
*
*E-mail: agnieszka.wroblewska@zut.edu.pl
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Abstract

The isomerization of limonene over natural the zeolite, clinoptilolite, was studied. The main products of limonene isomerization were terpinolene, α-terpinene, γ-terpinene and p-cymene. These products have numerous applications in the cosmetic, food and pharmaceutical industries. The main parameters affecting limonene isomerization were reaction time, temperature and catalyst content. These parameters varied within the following ranges: reaction time 15–1440 min; temperature 155–175°C; and catalyst content 5–15 wt.%. Terpinolene was obtained after reaction for 60 min at 175°C using 10 wt.% catalyst. p-Cymene was produced using similar conditions as for terpinolene except for a longer reaction time of 1440 min. The use of optimum experimental conditions allowed the greatest amounts of the desired products to be obtained in the shortest time.

Keywords

limonene isomerizationclinoptiloliteterpinolenep-cymene
Type
Article
Information
Clay Minerals , Volume 54 , Issue 2 , June 2019 , pp. 121 - 129
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019 

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Footnotes

Guest Associate Editor: A. Dakovic.

This paper was presented at the 10th International Conference on the Occurrence, Properties, and Utilization of Natural Zeolites (June 2018, Krakow).

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