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Mineralogical and trace element composition of clay-sized fractions from Albian siliciclastic rocks (Oliete Basin, NE Spain)

Published online by Cambridge University Press:  09 July 2018

J. M. González López ,
B. Bauluz ,
A. Yuste ,
M. J. Mayayo  and
C. Fernández-Nieto
J. M. González López
Affiliation:
Departamento de Ciencias de la Tierra, Universidad de Zaragoza, Pedro Cerbuna 12, 50.009, Zaragoza, Spain
B. Bauluz*
Affiliation:
Departamento de Ciencias de la Tierra, Universidad de Zaragoza, Pedro Cerbuna 12, 50.009, Zaragoza, Spain
A. Yuste
Affiliation:
Departamento de Ciencias de la Tierra, Universidad de Zaragoza, Pedro Cerbuna 12, 50.009, Zaragoza, Spain
M. J. Mayayo
Affiliation:
Departamento de Ciencias de la Tierra, Universidad de Zaragoza, Pedro Cerbuna 12, 50.009, Zaragoza, Spain
*
E-mail: bauluz@unizar.es
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Abstract

Mineralogical and geochemical techniques have been used to determine the role of minerals in controlling the trace element composition of a set of clay-sized fractions from Albian siliciclastic rocks in NE Spain. These clay-sized fractions are composed of kaolinite and illite, minor quantities of quartz, and accessory heavy minerals. Kaolinite has a smaller crystal size than illite, accounting for its relative concentration in these fractions. The µm-sized heavy minerals are rutile, Fe-Ti- and Fe-oxides, zircon, pyrite, cassiterite, monazite and xenotime. Geochemical data indicate that most of the trace elements are relatively concentrated in clay-sized fractions, except for Zr, Hf, Y and HREE. Statistical treatment shows three different associations in the clay-sized fractions: (1) Rb, Cs and Ba with clay phyllosilicates, especially illite; (2) REE with Th, Y and P phases; and (3) Sc, Cr and V with Ti- and Nb oxides. Therefore, these data do not support the dominant REE control by clay mineralogy that other authors have reported.

Keywords

clay fractionsgeochemistryheavy mineralsillitekaolinitemineralogytrace elements
Type
Research Article
Information
Clay Minerals , Volume 40 , Issue 4 , December 2005 , pp. 565 - 580
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2005

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