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The point of zero charge (pzc) of kaolinite and SiO2+AI2O3 mixtures

Published online by Cambridge University Press:  09 July 2018

M. Tschapek
Affiliation:
Centro de Investigacionespara Industrias Minerales, I.N.T.I., Libertad 1235, Buenos Aires, Argentina
L. Tcheichvili
Affiliation:
Centro de Investigacionespara Industrias Minerales, I.N.T.I., Libertad 1235, Buenos Aires, Argentina
C. Wasowski
Affiliation:
Centro de Investigacionespara Industrias Minerales, I.N.T.I., Libertad 1235, Buenos Aires, Argentina

Abstract

The pzc of H+-kaolins determined by titration method is nearly pH = 3. The pzc of SiO2 + Al2O3 mixtures is not additive, and depends principally on Al2O3 content in mixture. The curve pzc—t°C (t°C = temperature of treatment of kaolins) has two maxima: 4·7 after treatment at 800-900°C, and 5 after treatment at 1300°C.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1974

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References

Ahmed, S.M. (1966) Can. J. Chem. 44, 1663.Google Scholar
Beavers, A.H. & Marshall, E. (1950) Proc. Soil Sci. Soc. Am. 15, 142.Google Scholar
Berube, Y.G. & De Bruyn, P.L. (1968) J. Colloid Interface Sci. 27, 1305.Google Scholar
Breeuwsma, A. (1973) Adsorption of ions on hematite (Fe203). Thesis, State Agricultural University, Wageningen.Google Scholar
Buchanan, A.S. & Oppenheim, R.C. (1968) Aust. J. Chem. 21, 2367.CrossRefGoogle Scholar
Cashen, G.H. (1959) Trans. Faraday Soc. 55, 477.Google Scholar
Eitel, W., Muller, H.O. & Radczewski, O.E. (1939) Ber. dt. keram. Ges. 20, 165.Google Scholar
Grim, R. (1962) Applied Clay Minerology. McGraw-Hill, New York.Google Scholar
Parks, G.A. (1965) Chem. Rev. 65, 177.CrossRefGoogle Scholar
Schofield, R.K. & Samson, H.R. (1953) Clay Min. Bull. 2, 45.Google Scholar
Smolik, T., Harman, & Fuerstenau, D. (1966) Trans. Soc. Mining Eng. A.I.M.E. 235, 367.Google Scholar
Tcheichvili, L., Bussen, W. & Weyl, W. (1939) Ber. dt. keram. Ges. 20, 249.Google Scholar
Tewari, P.H. & Mclean, A.W. (1972) J. Colloid Interface Sci. 40, 267.Google Scholar
Verwey, E.J. (1950) Colloid Chemistry 7, 47.Google Scholar
Weiss, A. (1959) Z. Anorg. Allg. Chem. 299, 92.Google Scholar