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Smectitic clays enriched with ferric ions for the rapid removal of anionic dyes in aqueous media

Published online by Cambridge University Press:  10 February 2020

Itamar A. Rodrigues ,
Juan C. Villalba ,
Maria J. Santos ,
Fábio L. Melquiades  and
Fauze J. Anaissi Open the ORCID record for Fauze J. Anaissi [Opens in a new window]
Itamar A. Rodrigues
Affiliation:
Universidade Estadual do Centro-Oeste, Departamento de Química, Laboratório de Materiais e Compostos Inorgânicos, Rua Simeão Varela de Sá, 03, CEP 85040-080, Guarapuava, PR, Brazil
Juan C. Villalba
Affiliation:
Universidade Estadual do Centro-Oeste, Departamento de Química, Laboratório de Materiais e Compostos Inorgânicos, Rua Simeão Varela de Sá, 03, CEP 85040-080, Guarapuava, PR, Brazil
Maria J. Santos
Affiliation:
Universidade Estadual de Londrina, Rodovia Celso Garcia Cid, Pr 445 Km 380, Cx. Postal 10.011, CEP 86057-970, Londrina, PR, Brazil
Fábio L. Melquiades
Affiliation:
Universidade Estadual de Londrina, Rodovia Celso Garcia Cid, Pr 445 Km 380, Cx. Postal 10.011, CEP 86057-970, Londrina, PR, Brazil
Fauze J. Anaissi*
Affiliation:
Universidade Estadual do Centro-Oeste, Departamento de Química, Laboratório de Materiais e Compostos Inorgânicos, Rua Simeão Varela de Sá, 03, CEP 85040-080, Guarapuava, PR, Brazil
*
*E-mail: anaissi@unicentro.br
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Abstract

Sodium smectite clays were enriched with ferric ions (Argel-Fe and Volclay-Fe) to convert the surface charge of the clays from negative to positive and to use the clays in the discolouration of a synthetic effluent composed of seven anionic dyes (mixed from tartrazine, Brilliant Blue FCF and amaranth). The iron content increased from 5.99% to 11.02% for Argel-Fe and from 5.39% to 10.54% for Volclay-Fe. The efficiency of the discolouration of the anion dye mixture was evaluated by measuring the absorbance of the mixture at 562 nm, where the band with the greatest intensity was found. The contact time required for the system to reach equilibrium was ~5 min for both adsorbents. The kinetic adsorption data supported a pseudo-second-order kinetic model. The experimental data support the dual-site Langmuir–Freundlich isotherm model. The maximum adsorption capacities were 88.68 mg g–1 for Argel-Fe and 392.21 mg g–1 for Volclay-Fe. The enrichment of clays with Fe(III) added functionality to the clays and generated adsorbents with rapid adsorption abilities and high discolouration capacities.

Keywords

adsorptionanionic dyesdye mixtureFe-enrichedmodified claysurface charge
Type
Article
Information
Clay Minerals , Volume 55 , Issue 1 , March 2020 , pp. 12 - 23
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland, 2020

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Footnotes

Associate Editor: Chun-Hui Zhou

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