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Stichtite: a review

Published online by Cambridge University Press:  09 July 2018

F. L. Theiss ,
G. A. Ayoko  and
R. L. Frost
F. L. Theiss
Affiliation:
School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, Brisbane Queensland 4001, Australia
G. A. Ayoko
Affiliation:
School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, Brisbane Queensland 4001, Australia
R. L. Frost*
Affiliation:
School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, Brisbane Queensland 4001, Australia
*
*E-mail: r.frost@qut.edu.au
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Abstract

Stichtite is a naturally occurring layered double hydroxide (LDH) with the ideal chemical formula Mg6Cr2CO3(OH)16.4H2O. It has received less attention in the literature than other LDHs and is often described as a rare mineral; however, abundant deposits of the mineral do exist. In this article we aim to review a number of significant publications concerning the mineral stichtite, including papers covering the discovery, geological origin, synthesis and characterizsation of stichtite. Characterization techniques reviewed include powder X-ray diffraction (XRD), infrared spectroscopy (IR), near infrared spectroscopy (NIR), Raman spectroscopy (Raman), thermogravimetry (TG) and electron microprobe analysis.

Keywords

stichtitelayered double hydroxideanionic clayshydrotalcitesynthesisX-ray powder diffractionthermal analysisIR spectroscopynear-IR spectroscopyRaman spectroscopyelectron microprobe analysis
Type
Review
Information
Clay Minerals , Volume 48 , Issue 1 , March 2013 , pp. 143 - 148
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2013

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References

Ashwal, L.D. & Cairncross, B. (1997) Mineralogy and origin of stichtite in chromite-bearing serpentinites. Contributions to Mineralogy and Petrology, 127, 75–86.Google Scholar
Bookin, A.S., Cherkashin, V.I. & Drits, V.A. (1993) Reinterpretation of the X-ray diffraction patterns of stichtite and reevesite. Clays and Clay Minerals, 41, 631–634.Google Scholar
Bouzaid, J. & Frost, R.L. (2007) Thermal decomposition of stichtite. Journal of Thermal Analysis and Calorimetry, 89, 133–135.CrossRefGoogle Scholar
Frondel, C. (1940) Constitution and polymorphism of the pyroaurite and sjogrenite groups. Mineralogical Society of America, Annual Meeting, Program and Abstracts, 6–7.Google Scholar
Frost, R.L. & Erickson, K.L. (2004) Vibrational spectroscopy of stichtite. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 60, 3001–3005.CrossRefGoogle ScholarPubMed
Frost, R.L. & Erickson, K.L. (2005) Near-infrared spectroscopy of stitchtite, iowaite, desautelsite and arsenate exchanged takovite and hydrotalcite. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 61, 51–56.CrossRefGoogle ScholarPubMed
Frost, R.L., Bouzaid, J.M. & Martens, W.N. (2007) Thermal decomposition of the composite hydrotalcites of iowaite and woodallite. Journal of Thermal Analysis and Calorimetry, 89, 511–519.Google Scholar
Frost, R.L., Palmer, S.J. & Spratt, H.J. (2009) Thermal decomposition of hydrotalcites with variable cationic ratios. Journal of Thermal Analysis and Calorimetry, 95, 123–129.Google Scholar
Labajos, F.M. & Rives, V. (1996) Thermal evolution of chromium(III) ions in hydrotalcite-like compounds. Inorganic Chemistry, 35, 5313–5318.CrossRefGoogle Scholar
Mills, S.J., Whitfield, P.S., Wilson, S.A., Woodhouse, J.N., Dipple, G.M., Raudsepp, M. & Francis, C.A. (2011) The crystal structure of stichtite, re-examination of barbertonite, and the nature of polytypism in MgCr hydrotalcites. American Mineralogist, 96, 179–187.CrossRefGoogle Scholar
Mondal, S.K. & Baidya, T.K. (1996) Stichtite [Mg6Cr2(OH)16 CO3.4H2O] in Nausahi ultramafites, Orissa, India; its transformation at elevated temperatures. Mineralogical Magazine, 60, 836–840.Google Scholar
Nickel, E.H. & Grice, J.D. (1998) The IMA Commission on New Minerals and Mineral Names: Procedures and guidelines on mineral nomenclature, 1998. Mineralogy and Petrology, 64, 237–263.CrossRefGoogle Scholar
Petterd, W.F. (1910) Catalogue of the Minerals of Tasmania. Tasmania Department of Mines.Google Scholar
Read, H.H. (1933) On stichtite from Cunningsburgh, Shetland Islands. Mineralogical Magazine, 23, 309–316.Google Scholar
Rives, V. (2001) Layered Double Hydroxides: Present and Future. Nova Science Publ. Inc., New York.Google Scholar
Rives, V. (2002) Characterisation of layered double hydroxides and their decomposition products. Materials Chemistry and Physics, 75, 19–25.Google Scholar
Tatarinov, A.V., Sapozhnikov, A.N., Prokudin, S. & Frolova, L.P. (1985) Stichtite in serpentinites of Terektinsky Ridge (Mountain Altay). Zapiski RMO (Proceedings of the Russian Mineralogical Society), 114, 575–581.Google Scholar
Twelvetrees, W.H. (1914) Stichtite: a New Tasmanian Mineral. Tasmania Department of Mines.Google Scholar