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Sulphur reduction additive prepared from caustic-modified kaolin

Published online by Cambridge University Press:  09 July 2018

Shu-Hong Sun*
Affiliation:
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, PR China Petrochemical Research Institute, Lanzhou Petrochemical Company, PetroChina, Lanzhou 730060, PR China
Shu-Qin Zheng
Affiliation:
Petrochemical Research Institute, Lanzhou Petrochemical Company, PetroChina, Lanzhou 730060, PR China Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000, PR China
Zhi-Feng Wang
Affiliation:
Petrochemical Research Institute, Lanzhou Petrochemical Company, PetroChina, Lanzhou 730060, PR China
Yan-Hui Zhang
Affiliation:
Petrochemical Research Institute, Lanzhou Petrochemical Company, PetroChina, Lanzhou 730060, PR China
Jian-Tai Ma
Affiliation:
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, PR China

Abstract

The performance of a fluidized cracking catalyst additive prepared from caustic-modified kaolin microspheres for gasoline S reduction was investigated using N2 adsorption, infrared acid-site characterization, X-ray diffraction and small-scale fluid bed reactor tests. The additive exhibited improved coke selectivity and yield distribution, and the S content of cracked gasoline was reduced significantly. The results indicated that a reactive mesoporous structure was formed in the modified kaolin.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2005

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