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Synthesis and optical properties of composites based on ZnS nanoparticles embedded in layered magadiite

Published online by Cambridge University Press:  09 July 2018

Yufeng Chen  and
Gensheng Yu
Yufeng Chen*
Affiliation:
Department of Chemistry, Nanchang University, Jiangxi, 330031, P.R. China
Gensheng Yu
Affiliation:
Department of Chemistry, Nanchang University, Jiangxi, 330031, P.R. China
*
*E-mail: yfchen@ncu.edu.cn
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Abstract

Composites based on ZnS nanparticles embedded in layered magadiite were synthesized via a three step process : protonation of Na-magadiite, ion exchange in order to introduce Zn(NH3)42+ in the interlayer space, and addition of Na2S to form ZnS particles in the interlayer space of magadiite. The composites obtained were characterized by X-ray power diffraction (XRD), Scanning Electron Microscopy coupled with Energy Dispersive Spectroscopy (SEM-EDS), Transmission Electron Microscopy (TEM), Raman spectroscopy, Photoluminscence spectra (PL), and UV-visible transmission spectra (UV-vis). Results indicated that ZnS nanoparticles embedded in magadiite presented different optical properties and photoluminescence enhancement properties compared with those of uncovered ZnS particles (without host magadiite).

Keywords

magadiiteZnSphotoluminescencenanoparticlescomposite
Type
Research Article
Information
Clay Minerals , Volume 48 , Issue 5 , December 2013 , pp. 739 - 748
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2013

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