Hostname: page-component-cd9895bd7-p9bg8 Total loading time: 0 Render date: 2024-12-26T08:39:05.448Z Has data issue: false hasContentIssue false

Volatile products of clay mineral pyrolysis revealed by their effect on calcite

Published online by Cambridge University Press:  09 July 2018

L. Heller-Kallai
Affiliation:
Department of Geology, Institute of Earth Sciences
I. Miloslavski
Affiliation:
Casali Institute of Applied Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel
Z. Aizenshtat
Affiliation:
Casali Institute of Applied Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel

Abstract

The volatiles produced when various clay minerals were pyrolysed under a stream of He or in vacuo were condensed and analysed. They contain a wide range of cations and anions in concentrations ranging from ppm to hundreds of ppm. The reactivity of these volatiles was demonstrated by their reaction with calcite. It is suggested that the water liberated on heating acts as a scavenger of various impurities present in the clay.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1987

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Aizenshtat, Z. (1982) Thermal evaluation of bituminous rocks and pyroproducts. Israel J. Chem. 22, 266272.CrossRefGoogle Scholar
Burnham, A.K., Stubblefield, C.T. & Campbell, J.M. (1980) Effects of gas environment on mineral reactions in Colorado oil shale. Fuel 59, 871877.Google Scholar
Espitalie, J., Laport, J.L., Madec, M., Marquis, F., Leplat, P. & Paulet, J. (1977) Méthode rapide de caractérisation des roches mères, de leur potentiel pétrolier et de leur degré d'évolution. Rev. Inst. Fr. Pet. 32, 2343.Google Scholar
Ewing, J., Beruto, D. & Searcy, A.W. (1979) The nature of CaO produced by calcite powder decomposition in vacuum and in CO2 . J, Am. Ceram. Soc. 62, 580584.CrossRefGoogle Scholar
Heller-Kallai, L., Miloslavski, I. & Aizenshtat, Z. (1986) ‘Dissolution’ of calcite by steam derived from clay minerals. Naturwissenschaften 73, 615616.Google Scholar
Heller-Kallai, L., Miloslavski, I., Aizenshtat, Z. & Halicz, L. (1987) Chemical and mass spectroscopic analysis of volatiles derived from clays. Am. Miner. (in press).Google Scholar
Keller, W.D. (1986) Composition of condensates from heated clay minerals and shales. Am. Miner. 71, 14201425.Google Scholar
Maciejewski, M. & Oswald, H.R. (1985) Morphological observations on the thermal decomposition of calcium carbonate. Thermochim. Acta 85, 3942.CrossRefGoogle Scholar
Mackenzie, R.C. & Rahman, A.A. (1987) Interaction and procedural factors for one kaolinite in air and nitrogen. Thermochimica Acta, in press.Google Scholar
Macintire, W.H. & Stansel, T.B. (1953) Steam catalysis in calcinations of dolomite and limestone fines. Ind. Eng. Chem. 45, 15481555.Google Scholar
Paulik, J., Paulik, F. & Wieczorek-Ciurowa, K. (1980) Influence of foreign materials upon the thermal decomposition of dolomite, calcite and magnesite. Part III. Influence of the presence of water. Thermochim. Acta 38, 165172.CrossRefGoogle Scholar