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27Al Nuclear Magnetic Resonance and Ferron Kinetic Studies of Partially Neutralized AlCl3 Solutions

Published online by Cambridge University Press:  02 April 2024

Dorothy Z. Denney  and
Pa Ho Hsu
Dorothy Z. Denney
Affiliation:
Department of Chemistry, The State University of New Jersey, New Brunswick, New Jersey 08903
Pa Ho Hsu
Affiliation:
Department of Soils and Crops Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903
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Abstract

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Keywords

AluminumFerronGibbsiteHydroxy-Al complexNuclear magnetic resonance
Type
Notes
Information
Clays and Clay Minerals , Volume 34 , Issue 5 , October 1986 , pp. 604 - 607
Copyright
Copyright © 1986, The Clay Minerals Society

Footnotes

New Jersey Agriculture Experiment Station publication no. D-15221-1-85.

References

Akitt, J. W. and Farthing, A., 1978 New27Al NMR studies of the hydrolysis of the aluminum(III) ions J. Magn. Reson. 32 345–352.Google Scholar
Akitt, J. W. and Farthing, A., 1981 Aluminum-27 nuclear magnetic resonance studies of the hydrolysis of aluminum(III). Part 2. Gel-permeation chromatography J. Chem. Soc. Dalton Trans. 1606–1608.CrossRefGoogle Scholar
Akitt, J. W., Greenwood, N. N., Khandelwal, B. and Lester, G., 1972 27Al nuclear magnetic resonance studies of the hydrolysis and polymerization of the hexa-aquo-aluminum(III) cation J. Chem. Soc. Dalton Trans. 604–610.CrossRefGoogle Scholar
Aveston, J., 1965 Hydrolysis of the aluminum ion: ultracentrifugation and acidity measurements J. Chem. Soc. 4438–4443.CrossRefGoogle Scholar
Bertsch, P. M., 1984 Mechanism of polymer formation in hydroxy-Al solutions Agron. Abstr. 1984 Annual ASA meetings 175.Google Scholar
Bertsch, P. M., Thomas, G. W. and Bamhisel, R. I., 1986 Characterization of hydroxy-Al solutions by 27Al nuclear magnetic resonance spectroscopy Soil Sci. Soc. Amer. J. (in press).CrossRefGoogle Scholar
Bottero, J. Y., Cases, J. M., Fiessinger, F. and Poirior, J. E., 1982 Studies of hydrolyzed aluminum chloride solution. 1. Nature of aluminum species and composition of aqueous solution J. Phys. Chem. 84 2933–2939.CrossRefGoogle Scholar
Brosset, C., Biederman, G. and Sillen, L. G., 1954 Studies on the hydrolysis of metal ions XI. The aluminum ion, Al3+ Acta Chem. Scand. 8 1917–1926.CrossRefGoogle Scholar
Hsu, P. H., Dixon, J. B. and Weed, S. B., 1977 Aluminum hydroxides and oxyhydroxides Minerals in Soil Environments Madison, Wisconsin Soil. Sci. Soc. Amer. 99–143.Google Scholar
Johansson, G., 1960 On the crystal structures of some basic aluminum salts Acta Chem. Scand. 14 771–773.CrossRefGoogle Scholar
Johansson, G., 1963 On the crystal structure of the basic aluminum sulfate 13Al2O3-6SO3xH2O Ark. Kemi. 20 321–342.Google Scholar
Rausch, W. V. and Bale, H. D., 1964 Small angle X-ray scattering from hydrolyzed aluminum nitrate solutions J. Chem. Phys. 40 3391–3394.CrossRefGoogle Scholar
Sillen, L. G., 1959 Quantitative studies of hydrolytic equilibria Quart. Rev. 13 146–168.CrossRefGoogle Scholar
Teagarden, D. L., Koslowski, J. F., White, J. L. and Hem, S. L., 1981 Aluminum chlorohydrate I: structural studies J. Pharm. Sci. 70 758–761.CrossRefGoogle Scholar
Tsai, P. P. and Hsu, P. H., 1984 Studies of aged OH-Al solutions using kinetics of Al-ferron reactions and sulfate precipitation Soil Sci. Soc. Amer. J. 48 59–65.CrossRefGoogle Scholar
Tsai, P. P. and Hsu, P. H., 1985 Aging of partially neutralized aluminum solutions of NaOH/Al molar ratio = 2.2 Soil Sci. Soc. Amer. J. 49 1060–1065.CrossRefGoogle Scholar
Turner, R. C., 1976 Effect of aging on properties of polynuclear hydroxyaluminum cations Can. J. Chem. 54 1528–1534.CrossRefGoogle Scholar
Turner, R. C., 1976 A second species of polynuclear hydroxy-aluminum cation, its formation and some of its properties Can. J. Chem. 54 1910–1915.CrossRefGoogle Scholar