Hostname: page-component-7dd5485656-glrdx Total loading time: 0 Render date: 2025-10-30T14:49:18.688Z Has data issue: false hasContentIssue false
  • English
  • Français

Structures, Compositions, and X-Ray Diffraction Identification of Dioctahedral Chlorites

Published online by Cambridge University Press:  02 April 2024

S. W. Bailey  and
Judith S. Lister
S. W. Bailey
Affiliation:
Department of Geology & Geophysics, University of Wisconsin, Madison, Wisconsin 53706
Judith S. Lister
Affiliation:
Department of Geology & Geophysics, University of Wisconsin, Madison, Wisconsin 53706
Get access Rights & Permissions [Opens in a new window]

Abstract

Al-rich di, trioctahedral chlorite exists as the species cookeite and sudoite. Di,dioctahedral chlorite exists as the species donbassite. Cookeite has essential Li in its structure, sudoite has essential Mg, and donbassite has only small amounts of either element. To date, sudoite has been reported to have only IIb structural units and donbassite to have only Ia structural units. Cookeite is based primarily on Ia structural units, but IIb units are present in specimens from two localities. Most Al-rich chlorite species have regular-stacking “r” or “s” 2-layer stacking sequences, but 1-layer Ia-2 and Ia-6 polytypes also are known. The structural units (Ia or IIb) and the specific stacking sequences can be explained by a combination of local charge balance and minimization of cation-cation repulsion involving the interlayer and tetrahedral cations. X-ray powder diffraction data are adequate to differentiate Al-rich chlorite from trioctahedral chlorite and to identify the type of structural unit present, but single crystal study is necessary to identify the 2-layer and 1-layer sequences with certainty.

Keywords

Chemical compositionChloriteCookeiteCrystal structureDonbassiteSudoiteX-ray powder diffraction

Information

Type
Research Article
Information
Clays and Clay Minerals , Volume 37 , Issue 3 , June 1989 , pp. 193 - 202
Copyright
Copyright © 1989, The Clay Minerals Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

Ahn, J. H. and Buseck, P. R., 1988 Alteration of andalusite to sheet silicates in a pegmatite Amer. Mineral 73 559 – 567.Google Scholar
Aleksandrova, V. A., Drits, V. A. and Sokolova, G. V., 1972 Structural features ofdioctahedral one-packet chlorite Soviet Physics Crystallogr 17 456 – 461.Google Scholar
Alysheva, E. I., Rusinova, O. V. and Chekvaidze, V. B., 1977 On sudoite from polymetal deposits of Rydnyy Altai Dokl. Akad. Nauk S.S.S.R 236 722 – 724.Google Scholar
Bailey, S. W., 1975 Cation ordering and pseudosymmetry in layer silicates Amer. Mineral 60 175 – 187.Google Scholar
Bailey, S. W. and Brown, B. E., 1962 Chlorite polytypism: I. Regular and semi-random one-layer structures Amer. Mineral 47 819 – 850.Google Scholar
Bailey, S. W. and Tyler, S. A., 1960 Clay minerals associated with the Lake Superior iron ores Econ. Geol 55 150 – 175.CrossRefGoogle Scholar
Brydon, J. E., Clark, J. S. and Osborne, V., 1961 Dioctahedral chlorite Canadian Mineral 6 595 – 609.Google Scholar
Caillère, S., Hénin, S. and Pobeguin, T., 1962 Présence dun nouveau type de chlorite dans les “bauxites” de Saint-Paul-de-Fenouillet (Pyrénées-Orientales) C.R. Acad. Sci. Paris 254 1657 – 1658.Google Scholar
de la Calle, C., Dubernat, J., Suquet, H., Pézerat, H., Gaultier, J., Mamy, J. and Bailey, S. W., 1976 Crystal structure of two-layer Mg-vermiculites and Na, Ca-vermiculites Proc. Internat. Clay Conf., Mexico City, 1975 Wilmette, Illinois Applied Publishing 201 – 210.Google Scholar
Cerný, P., 1970 Compositional variations in cookeite Canadian Mineral 10 636 547.Google Scholar
Cerný, P., Povondra, P. and Stanek, J., 1971 Twocookeites from Czechoslovakia: A boron-rich variety and a 116 poly-type Lithos 4 7 – 15.CrossRefGoogle Scholar
Drits, V. A. and Lazarenko, E. K., 1967 Structural and mineralogical characteristics of donbassites Mineralog. Sb., L’vov 21 40 – 48.Google Scholar
Eggleton, R. A. and Bailey, S. W., 1967 Structural aspects of dioctahedral chlorite Amer. Mineral 52 673 – 689.Google Scholar
Frank-Kamenetskii, V. A., 1960 A crystallochemical classification of simple and interstratified clay minerals Clay Minerals Bull 4 161 – 172.CrossRefGoogle Scholar
Fransolet, A.-M. and Bourguignon, P., 1978 Di/trioctahedral chlorite in quartz veins from the Ardenne, Belgium Canadian Mineral 16 365 – 373.Google Scholar
Frenzel, G. and Schembra, F. W., 1965 Ein dioktaedrischer Chlorit vom Kaiserbachtal (Sudfalz) N. Jahrb. Mineral., Monats. 108 – 114.Google Scholar
Gomes, C. S. F., 1967 Alteration of spodumene and lepidolite with formation of dioctahedral chlorite plus dioctahedral chlorite-dioctahedral montmorillonite interstratifications Publ. Museu Lab. Mineral. Geol. Univ. Coimbra, Memórias Notícias 64 32 – 57.Google Scholar
Guggenheim, S., Schulze, W. A., Harris, G. A. and Lin, J.-C., 1983 Noncentric layer silicates: An optical second harmonie generation, chemical, and X-ray study Clays & Clay Minerals 31 251 – 260.CrossRefGoogle Scholar
Hayashi, H. and Oinuma, K., 1964 Aluminian chlorite from Kamikita mine, Japan Clay Sci 2 22 – 30.Google Scholar
Honda, S., 1975 Dioctahedral chlorite, closely associated with kaolinite from the Kamikita mine (Kuroko deposit) Rep. Res. Inst. Underground Res. Mining College Akita Univ 43 1 – 8.Google Scholar
Kimbara, K. and Nagata, H., 1974 Clay minerals in the core samples of the mineralized zone of Niida—With special reference to the mineralogical properties of sudoite and tosudite Jap. Assoc. Mineral., Petrol. Econ. Geol 69 239 – 254.CrossRefGoogle Scholar
Kramm, U., 1980 Sudoite in low-grade metamorphic manganese-rich assemblages N. Jahrb. Mineral, Abh 138 1 – 13.Google Scholar
Lacroix, A., 1912 Sur une nouvelle espèce minérale (manandonite) des pegmatites de Madagascar Bull. Soc. Fr. Mineral 35 223 – 226.Google Scholar
Lacroix, A., 1922 Minéralogie de Madagascar. I. Géologie, Descriptive Minéralogie Paris Librairie Maritime Coloniale 481 – 482.Google Scholar
Lazarenko, E. K., 1940 Donbassite—A new group of minerals from the Donetz Basin Dokl. Akad. Nauk S.S.S.R 28 519 – 521.Google Scholar
Lin, C.-Y. and Bailey, S. W., 1985 Structural data for sudoite Clays & Clay Minerals 33 410 – 414.CrossRefGoogle Scholar
Lister, J. S., 1966 The crystal structure of two chlorites Madison, Wisconsin Univ. Wisconsin.Google Scholar
Lister, J. S. and Bailey, S. W., 1967 Chlorite polytypism: IV. Regular 2-layer structures Amer. Mineral 52 1614 – 1631.Google Scholar
Mathieson, A McL and Walker, G. F., 1954 Crystal structure of Mg-vermiculite Amer. Mineral 39 231 – 255.Google Scholar
Müller, G., 1961 Vorläufige Mitteilung über ein neues dioktaedrisches Phyllosílíkat der Chlorit-Gruppe N. Jahrb. Minerals Monatsh. 112 – 120.Google Scholar
Müller, G., 1963 Zur Kenntnis di-oktaedrischer Vierschicht-Phyllosilikate (Sudoit-Reihe der Sudoit-Chlorit-Gruppe) Proc. Internat. Clay Conf., Stockholm 1963 1 121 – 130.Google Scholar
Peacor, D.R. Rouse, R.C. and Bailey, S.W., 1988 Crystal structure of franklinfurnaceite: A tri-dioctahedral zincosilicate intermediate between chlorite and mica Amer. Mineral 73 876 – 887.Google Scholar
Ranorosoa, N., 1986 Etude minéralogique et microther-mométrique des pegmatites de champ de la Sahatany, Madagascar Toulouse, France Univ. Paul-Sabatier.Google Scholar
Rozinova, E. L. and Dubik, O Yu, 1983 Dioctahedral chlorites Mineralog. Zh 5 3 14 – 31.Google Scholar
Schultz, L. G., 1963 Clay minerals in Triassic rocks of the Colorado Plateau U.S. Geol. Survey Bull 1147–C 1 – 69.Google Scholar
Shirozu, H. and Bailey, S. W., 1965 Chlorite polytypism: III. Crystal structure of an orthohexagonal iron chlorite Amer. Mineral 50 868 – 885.Google Scholar
Shirozu, H. and Bailey, S. W., 1966 Crystal structure of a two-layer Mg-vermiculite Amer. Mineral 51 1124 – 1143.Google Scholar
Shirozu, H. and Higashi, S., 1976 Structural investigations of sudoite and regularly interstratified sericite/sudoite Mineral. J. (Japan) 8 158 – 170.CrossRefGoogle Scholar
Stanton, R. L., 1984 The direct derivation of cordierite from a clay-chlorite precursor: Evidence from the Geco mine, Manitouwadge, Ontario Econ. Geol 79 1245 – 1264.CrossRefGoogle Scholar
Strunz, H., 1957 Bor und Beryllium in Phyllosilikaten Rend. Soc. Min. Italy 13 372.Google Scholar
Sudo, T., Sato, M., Heller, L. and Weiss, A., 1966 Dioctahedral chlorite Proc. Internat. Clay Conf., Jerusalem 1966, Vol. 1 Jerusalem Israel Prog. Sci. Transi. 33 – 39.Google Scholar
Thompson, J. G., 1984 29Si and 27Al nuclear magnetic resonance spectroscopy of 2:1 clay minerals Clay Miner 19 220 – 236.CrossRefGoogle Scholar
Tsukahara, N., 1964 Dioctahedral chlorite from the Furutobe mine, Akita Prefecture, Japan Clay Sci 2 56 – 75.Google Scholar
Tsuzuki, Y. and Honda, S., 1977 Three examples of Mg-Al chlorite from Kuroko deposits J. Mineral. Soc. Japan 13 85 – 93.Google Scholar
Vlasov, V. V. and Drits, V. A., 1967 Study of endogenetic dioctahedral chlorite X-ray Analysis of Mineral Products 6 114 – 121.Google Scholar
Vrublevskaja, Z. V., Delitsin, I. S., Zvyagin, B. B. and Soboleva, S. V., 1975 Cookeite with a perfect regular structure, formed by bauxite alteration Amer. Mineral 60 1041 – 1046.Google Scholar