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Adsorption and Photo-reactivity of Bensulfuron-Methyl On Homoionic Clays

Published online by Cambridge University Press:  01 January 2024

Youbin Si ,
Shenqiang Wang ,
Dongmei Zhou  and
Huaiman Chen
Youbin Si*
Affiliation:
College of Resource and Environmental Science, Anhui Agricultural University, Hefei 230036, China
Shenqiang Wang
Affiliation:
Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China
Dongmei Zhou
Affiliation:
Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China
Huaiman Chen
Affiliation:
Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008, China
*
*E-mail address of corresponding author: youbinsi@21cn.com
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Abstract

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The adsorption and photolysis of the herbicide bensulfuron-methyl [2-(4, 6-dimethoxypyrimidm-2-carbamoylsulfamoyl)-o-toluic acid methyl ester] on homoionic Na+-, Ca2+- and Fe3+-montmorillonite and kaolinite clays were studied. The Freundlich adsorption coefficient, Kf, measured from isotherms on clays followed the order Na+ < Ca2+ < Fe3+. Montmorillonite showed a greater adsorptive capacity than kaolinite. Analysis of Fourier transform infrared spectra of bensulfuron-methyl adsorbed on clay suggested probable bonding interactions between bensulfuron-methyl and homoionic clays. The photolysis rate of herbicide adsorbed on homoionic clay surfaces was quite slow to its free state and decreased in the order Na+ > Ca2+ > Fe3+, indicating that adsorption may have prevented photolysis.

Keywords

AdsorptionBensulfuron-methylInfrared SpectroscopyKaoliniteMontmorillonitePhotolysis
Type
Research Article
Information
Clays and Clay Minerals , Volume 52 , Issue 6 , December 2004 , pp. 742 - 748
Copyright
Copyright © 2004, The Clay Minerals Society

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