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Arsenic Sorption onto Soils Enriched in Mn and Fe Minerals

Published online by Cambridge University Press:  01 January 2024

Eleonora Deschamps ,
Virginia S. T. Ciminelli ,
Peter G. Weidler  and
Aline Y. Ramos
Eleonora Deschamps
Affiliation:
State Environmental Agency-FEAM, Brazil
Virginia S. T. Ciminelli*
Affiliation:
Department of Metallurgical and Materials Engineering, Universidade Federal de Minas Gerais, UFMG, Brazil
Peter G. Weidler
Affiliation:
Institute for Technical Chemistry, Water- and Geotechnology (ITC-WGT), Forschungszentrum Karlsruhe-FZK, Germany
Aline Y. Ramos*
Affiliation:
Laboratório Nacional de Luz Síncrotron-LNLS/Campinas SP, Brazil
*
*E-mail address of corresponding author: ciminelli@demet.ufmg.br
†Present address: LMCP, UMR7590 CNRS, Paris, France
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Abstract

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The As sorption capacity of a natural Mn and Fe mineral-containing sample from the Iron Quadrangle province, Brazil, was investigated. A detailed mineralogical identification was obtained by combining X-ray diffraction analyses (with Rietveld refinement), X-ray fluorescence spectroscopy, optical microscopy, and scanning electron microscopy coupled with X-ray energy dispersive spectrometry-EDS. The oxidation state of the adsorbed As species was determined by X-ray absorption near edge structure spectroscopy. The results demonstrate that the presence of naturally occurring Mn oxides promotes the effective oxidation of As (III) to As(V). Also, the Mn minerals show a significant uptake of both the trivalent and pentavalent As species. This study demonstrates that the combined influences of As(III) depletion by oxidation and adsorption on a natural oxide sample consisting of Mn minerals and Fe oxides may effectively contribute to the reduction the As concentration in waters.

Keywords

AdsorptionArsenateArsenicArseniteFe OxidesMn OxidesXANES
Type
Research Article
Information
Clays and Clay Minerals , Volume 51 , Issue 2 , April 2003 , pp. 197 - 204
Copyright
Copyright © 2003, The Clay Minerals Society

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