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Determination of Illite-Smectite Structures using Multispecimen X-Ray Diffraction Profile Fitting

Published online by Cambridge University Press:  28 February 2024

Boris A. Sakharov ,
Holger Lindgreen ,
Alfred Salyn  and
Victor A. Drits
Boris A. Sakharov
Affiliation:
Institute of Geology, Russian Academy of Sciences, Pyzhevsky per D.7., 109017 Moscow, Russia
Holger Lindgreen
Affiliation:
Clay Mineralogical Laboratory, Geological Survey of Denmark and Greenland, Thoravej 8, DK2400 Copenhagen NV, Denmark
Alfred Salyn
Affiliation:
Institute of Geology, Russian Academy of Sciences, Pyzhevsky per D.7., 109017 Moscow, Russia
Victor A. Drits
Affiliation:
Institute of Geology, Russian Academy of Sciences, Pyzhevsky per D.7., 109017 Moscow, Russia
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Abstract

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A procedure for structural investigations by X-ray diffraction of mixed-layer structures incorporating swelling layers has been developed. For each sample, specimens saturated with different cations (Na, Mg, and Ca), are analyzed both as air-dried and as glycolated. One structural model fitting all the observed patterns then provides the structure of the sample. Samples tested include: Mite-smectite (I-S) minerals from Kazachstan (a rectorite), Dolna Ves in Slovakia, Kinnekulle in Sweden, the North Sea, and Scania in Sweden. The fitting of the patterns of the Kazachstan rectorite demonstrated that the instrumental parameters applied in the modeling were correct. For the I-S minerals from Slovakia and Kinnekulle the observed patterns were fitted with one two-component I-S model. However, the Ca-saturated and air-dried specimen of the Kinnekulle bentonites had two types of swelling interlayers. For the Slovakian I-S with Reichweite = 2, an alternative two-phase I-S plus I–V (V = vermiculite) model fitted the experimental X-ray diffraction patterns equally well. The I-S mineral from Scania is in fact a three-component I-T-S (T = tobelite) and the North Sea sample is a four-component I-S-V-V, one type of the swelling layers having swelling characteristics intermediately between smectite and vermiculite. In addition to layer types and distribution, interlayer compositions, such as the amount of interlayer glycol and water and of fixed and exchangeable cations, were determined.

Keywords

Illite-SmectiteSimulationStructureSwellingX-Ray Diffraction
Type
Research Article
Information
Clays and Clay Minerals , Volume 47 , Issue 5 , October 1999 , pp. 555 - 566
Copyright
Copyright © 1999, The Clay Minerals Society

References

Anderson, J.U., 1963 An improved pretreatment for mineralogical analysis of samples containing organic matter Clays and Clay Minerals 10 380–388 10.1346/CCMN.1961.0100134.CrossRefGoogle Scholar
Brindley, G.W., 1966 Ethylene glycol and glycerol complexes of smectites and vermiculites Clay Minerals 6 237–259 10.1180/claymin.1966.006.4.01.CrossRefGoogle Scholar
Brusewitz, A.M., 1986 Chemical and physical properties of Palaeozoic bentonites from Kinnekulle, Sweden Clays and Clay Minerals 34 442–454 10.1346/CCMN.1986.0340411.CrossRefGoogle Scholar
Buzagh, W. and Szepesi, K., 1955 A colloid-chemical method for the determination of the montmorillonite content in bentonites Acta Chimica Hungarica 5 287–298.Google Scholar
Drits, V.A. and Sakharov, B.A., 1976 X-ray Analysis of Mixed-layer Minerals Moskow Nauka.Google Scholar
Drits, V.A. and Tchoubar, C., 1990 X-ray Diffraction by Disordered Lamellar Structures Berlin Springer Verlag 10.1007/978-3-642-74802-8.CrossRefGoogle Scholar
Drits, V.A. Weber, F. Salyn, A.L. and Tsipursky, S.I., 1993 X-ray identification of one-layer illite varieties: Application to the study of illites around uranium deposits, Canada Clays and Clay Minerals 41 389–394 10.1346/CCMN.1993.0410316.CrossRefGoogle Scholar
Drits, VA V X Sakharov, B.A. and Plançon, A., 1994 A simple technique for identification of one-dimensional powder X-ray diffraction patterns for mixed-layer illite-smectites and other interstratified minerals Clays and Clay Minerals 42 382–390 10.1346/CCMN.1994.0420402.CrossRefGoogle Scholar
Drits, V.A. Sakharov, B.A. Lindgreen, H. and Salyn, A., 1997 Sequential structure transformation of illite-smectite-vermiculite during diagenesis of Upper Jurassic shales from the North Sea and Denmark Clay Minerals 32 351–371 10.1180/claymin.1997.032.3.03.CrossRefGoogle Scholar
Drits, V.A. Ŝrodoñ, J. and Eberi, D.D., 1997 XRD measurement of mean crystallite thickness of illite and illite/smectite: Reapparisal of the Kubier index and the Scherrer equation Clays and Clay Minerals 45 461–475 10.1346/CCMN.1997.0450315.CrossRefGoogle Scholar
Drits, V.A. Lindgreen, H. and Salyn, A., 1997 Determination by X-ray diffraction of content and distribution of fixed ammonium in illite-smectite. Application to North Sea illite-smectites American Mineralogist 82 79–87 10.2138/am-1997-1-210.CrossRefGoogle Scholar
Gibbs, R.J., 1967 Quantitative X-ray diffraction analysis using clay mineral standards extracted from the samples to be analysed Clay Minerals 7 79–90 10.1180/claymin.1967.007.1.07.CrossRefGoogle Scholar
Hansen, P.L. and Lindgreen, H., 1989 Mixed-layer illite/smectite diagenesis in Upper Jurassic claystones from the North Sea and onshore Denmark Clay Minerals 24 197–213 10.1180/claymin.1989.024.2.07.CrossRefGoogle Scholar
Hower, J. Eslinger, E.V. Hower, M.E. and Perry, E.A., 1976 Mechanism of burial metamorphism of argillaceous sediments Geological Society of America Bulletin 87 725–737 10.1130/0016-7606(1976)87<725:MOBMOA>2.0.CO;2.2.0.CO;2>CrossRefGoogle Scholar
Lindgreen, H. Garnaes, J. Besenbacher, F. Laegsgaard, E. and Stensgaard, I., 1992 Illite-smectite from the North Sea investigated by scanning tunneling microscopy Clay Minerals 27 331–342 10.1180/claymin.1992.027.3.06.CrossRefGoogle Scholar
MacEwan, D.M.C. Wilson, M.J., Brindley, G.W. and Brown, G., 1980 Interlayer and intercalation complexes of clay minerals Crystal Structures of Clay Minerals and Their X-ray Identification London Mineralogical Society 197–248.CrossRefGoogle Scholar
McCarty, D.K. and Thompson, G.R., 1991 Burial diagenesis in two Montana Tertiary basins Clays and Clay Minerals 39 293–305 10.1346/CCMN.1991.0390310.CrossRefGoogle Scholar
Mehra, O.P. and Jackson, M.L., 1958 Iron oxide removal from soils and clays by a dithionite-citrate buffered with sodium carbonate Clays and Clay Minerals 7 317–327 10.1346/CCMN.1958.0070122.CrossRefGoogle Scholar
Moore, D.M. and Reynolds, R.C., 1989 X-ray Diffraction and the Identification and Analysis of Clay Minerals Oxford Oxford University Press.Google Scholar
Nadeau, P.H. and Reynolds, R.C., 1981 Burial and contact metamorphism in the Mancos shale Clays and Clay Minerals 29 249–259 10.1346/CCMN.1981.0290402.CrossRefGoogle Scholar
Perry, E. and Hower, J., 1970 Burial diagenesis in Gulf Coast pelitic sediments Clays and Clay Minerals 18 165–177 10.1346/CCMN.1970.0180306.CrossRefGoogle Scholar
Reynolds, R.C., Brindley, G.W. and Brown, G., 1980 Interstratified clay minerals Crystal Structures of Clay Minerals and Their X-ray Identification London Mineralogical Society 249–304.CrossRefGoogle Scholar
Reynolds, R.C., 1986 The Lorenz-polarization factor and preferred orientation in oriented clay aggregates Clays and Clay Minerals 34 359–367 10.1346/CCMN.1986.0340402.CrossRefGoogle Scholar
Reynolds, R.C. and Bailey, S.W., 1988 Mixed-layer chlorite minerals Hydrous Phyllosilicates (Exclusive of Micas), Reviews in Mineralogy, Volume 19 Chelsea, Michigan Mineralogical Society of America 601–630 10.1515/9781501508998-020.CrossRefGoogle Scholar
Reynolds, R.C. and Hower, J., 1970 The nature of interlayering in mixed-layer illite-montmorillonite Clays and Clay Minerals 18 25–36 10.1346/CCMN.1970.0180104.CrossRefGoogle Scholar
Rule, A.C. and Bailey, S.W., 1987 Refinement of the crystal structure of a monoclinic ferroan clinochlore Clays and Clay Minerals 35 129–138 10.1346/CCMN.1987.0350205.CrossRefGoogle Scholar
Shutov, V.D. Drits, V.A. Sakharov, B.A. and Heller, L., 1969 On the mechanism of a postsedimentary transformation of montmorillonite into hydromica Proceedings of the International Clay Conference, Tokyo, 1969, Volume 1 523–532.Google Scholar
Shutov, V.D. Drits, V.A. Sakharov, B.A. and Heller, L., 1969 On the mechanism of a postsedimentary transformation of montmorillonite into hydromica: Discussion Proceedings of the International Clay Conference, Tokyo, 1969, Volume 2 126–129.Google Scholar
Środoń, J., 1980 Precise identification of illite/smectite interstratifications by X-ray powder diffraction Clays and Clay Minerals 28 401–411 10.1346/CCMN.1980.0280601.CrossRefGoogle Scholar
Srodon, J., 1981 X-ray identification of randomly interstratified illite/smectite in mixtures with discrete illite Clay Minerals 16 297–304 10.1180/claymin.1981.016.3.07.CrossRefGoogle Scholar
Środoń, J., 1984 X-ray powder diffraction identification of illitic materials Clays and Clay Minerals 32 337–349 10.1346/CCMN.1984.0320501.CrossRefGoogle Scholar
Środoń, J. Elsass, F. McHardy, W.J. and Morgan, D.J., 1986 Chemistry of illite/smectite inferred from TEM measurements of fundamental particles Clay Minerals 27 137–158 10.1180/claymin.1992.027.2.01.CrossRefGoogle Scholar
Šucha, V. Kraus, I. Mosser, C. Hroncova, Z. and Siranova, V., 1992 Mixed-layer illite/smectite from the Dovna Ves hydrothermal deposit, the western Carpathians Kremnica MTS, Bratislava Geologia Carpathica, Clays, Series 1 1 13–21.Google Scholar
Tomita, K. Takahashi, H. and Watanabe, T., 1988 Quantification curves for mica/smectite interstratifications by X-ray powder diffraction Clays and Clay Minerals 36 258–262 10.1346/CCMN.1988.0360307.CrossRefGoogle Scholar
Watanabe, T., 1981 Identification of interstratifications of illite and montmorillonite by X-ray powder diffraction Journal of the Mineralogical Society Japan 15 32–41 10.2465/gkk1952.15.Special_32.Google Scholar
Watanabe, T., 1988 Structural model of illite/smectite interstratified minerals and the diagram for their interstratification Clay Science 1 97–114.Google Scholar
Weaver, C.E. and Beck, K.C. (1971) Clay water diagenesis during burial: How mud becomes gneiss. Geological Society of America Special Paper, 134, 1—78.CrossRefGoogle Scholar