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Effect of Interaction Between Clay Particles And Fe3+ Ions on Colloidal Properties of Kaolinite Suspensions

Published online by Cambridge University Press:  28 February 2024

Kunsong Ma  and
Alain C. Pierre
Kunsong Ma
Affiliation:
University of Alberta, Edmonton, Canada
Alain C. Pierre
Affiliation:
University of Alberta, Edmonton, Canada
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Abstract

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Fine kaolinite suspensions were mixed with unaged or aged FeCl3 in this experiment. The interaction between clay particles and Fe3+ hydrolysis products was studied by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The proportion of Fe adsorbed was measured and the electrical charge on the clay particles was determined by electrophoresis. The effect of this interaction on flocculation of clay suspensions was investigated in a series of sedimentation tests. The Fe3+ ions acted as counterions when their concentration was low and when unaged FeCl3 solution was used. Otherwise, their hydrolysis complexes acted as a bonding agent between kaolinite particles. The dispersion-flocculation behavior of kaolinite suspensions was found to be in agreement with the theory of Derjaguin, Landau, Verwey and Overbeek (DLVO), as the sedimentation behavior could be predicted from the data of zeta potentials (ζ).

Keywords

ColloidElectron MicroscopyFlocculationIronKaoliniteSedimentationZeta Potential
Type
Research Article
Information
Clays and Clay Minerals , Volume 45 , Issue 5 , October 1997 , pp. 733 - 744
Copyright
Copyright © 1997, The Clay Minerals Society

References

Blackmore, A.V., 1973 Aggregation of clay by the products of iron(III) hydrolysis Aust J Soil Res 11 75–82 10.1071/SR9730075.CrossRefGoogle Scholar
Brindley, G.W. and Kingery, W.D., 1958 Clays and clay raw materials Ceramic fabrication processes New York MIT and J. Wiley 7–22.Google Scholar
El-Swaify, S.A. and Emerson, W.W., 1975 Changes in the physical properties of soil clays due to precipitated aluminum and iron hydroxides Soil Sci 39 1056–1063 10.2136/sssaj1975.03615995003900060016x.CrossRefGoogle Scholar
Georgia Kaolin Company, Inc., 1990 Information about properties of hydrite UF kaolinite particles .Google Scholar
Greenland, D.J., 1975 Charge characteristics of some kaolinite-iron hydroxide complexes Clay Miner 10 407–416.Google Scholar
Henry, M. Jolivet, J.P. and Livage, J., 1990 Aqueous chemistry of metal cation: Hydrolysis, condensation, and complexation Structure and Bonding 25 1–64.Google Scholar
Hiemenz, P.C., 1977 Principles of colloidal and surface chemistry New York Marcel Dekker.Google Scholar
Livage, J. Henry, M. and Sanchez, C., 1988 Sol-gel chemistry of transition metal oxides Prog Solid State Chem 18 259–342 10.1016/0079-6786(88)90005-2.CrossRefGoogle Scholar
Ma, K., 1995 Microstructure of clay sediments or gels [Ph.D. thesis], Edmonton Canada Univ of Alberta.Google Scholar
Ma, K. and Pierre, A.C., 1992 Sedimentation behavior of a fine kaolinite in the presence of fresh Fe electrolyte Clays Clay Miner 40 586–592 10.1346/CCMN.1992.0400513.Google Scholar
Michaels, A.S. and Boiger, J.C., 1962 Settling rates and sediment volumes of flocculated kaolin suspensions IEC Fundam 1 24–33 10.1021/i160001a004.CrossRefGoogle Scholar
Plitt, L.R., 1993 Mineral processing Department of Mining, Metallurgical, and Petroleum Engineering Edmonton, Canada Univ of Alberta.Google Scholar
Rand, B. and Melton, I.E., 1977 Particle interactions in aqueous kaolinite suspensions: I. Effect of pH and electrolyte upon the mode of particle interaction in homoionic sodium kaolinite suspensions J Colloid Interface Sci 60 308–320 10.1016/0021-9797(77)90290-9.CrossRefGoogle Scholar
Rengasamy, P. and Oades, J.M., 1977 Interaction of monomelic and polymeric species of metal ions with clay surfaces. I: Adsorption of iron(III) species; II: Changes in surface properties of clays after addition of iron(III) Aust J Soil Res 15 221–242 10.1071/SR9770221.CrossRefGoogle Scholar
Smart, P. and Tovey, N.Y., 1982 Electron microscopy of soils and sediments: Techniques Oxford Clarendon Pr 10.1097/00010694-198208000-00010.CrossRefGoogle Scholar
Schofield, R.K. and Samson, H.R., 1954 Flocculation of kaolinite due to the attraction on oppositely charged crystal faces Discuss Faraday Soc 18 135–145 10.1039/df9541800135.CrossRefGoogle Scholar
Schwertmann, U. Taylor, R.M., Dixon, J.B. and Weed, S.B., 1989 Iron oxides Minerals in soil environments Madison, WI Soil Sci Soc Am 379–427.Google Scholar
van Olphen, H., 1977 An introduction to clay colloid chemistry 2nd New York John Welwey.Google Scholar
Verwey, E.J.W. and Overbeek, J.T.G., 1948 Theory of the stability of lyophobic colloids New York Elsevier.Google Scholar
Young, R.N. and Ohtsubo, M., 1987 Interparticle action and rheology of kaolinite-amorphous iron hydroxide (ferrihydrite) complexes Appl Clay Sci 2 63–81 10.1016/0169-1317(87)90014-7.CrossRefGoogle Scholar
Zou, J. and Pierre, A.C., 1992 SEM observations of card-house structures in montmorillonite gels J Mater Sci Lett 10 664–665 10.1007/BF00728899.CrossRefGoogle Scholar