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Effective Dye Removal from Waste Water Using a Novel Low-Cost NaOH-Modified Fly Ash

Published online by Cambridge University Press:  01 January 2024

Xiaoming Gao*
Affiliation:
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an, Shaanxi 716000, China
Yuan Dai
Affiliation:
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an, Shaanxi 716000, China
Yu Zhang
Affiliation:
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an, Shaanxi 716000, China
Xiang Zhai
Affiliation:
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an, Shaanxi 716000, China
Feng Fu
Affiliation:
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an University, Yan’an, Shaanxi 716000, China
*
*E-mail address of corresponding author: dawn1026@163.com
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Abstract

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Dyes are toxic and considered to be extremely hazardous to natural environments. Hence, adsorbents to remove dyes from contaminated water are needed. To develop adsorbents with a high adsorption capacity for different dyes, easy separation, and low cost, a novel dye adsorbent was prepared by activating fly ash with NaOH. The adsorbent morphology, structure, and specific surface area were characterized using scanning electron microscopy, X-ray powder diffraction, and surface area measurements using N2 adsorption-desorption. The adsorption abilities of the synthesized adsorbents were examined based on methylene blue and acid fuchsin adsorption from water. The capabilities of the adsorbents as a function of adsorbent use, dye type, dye concentration, time, and pH were investigated and compared. The results for methylene blue and acid fuchsin adsorption were modeled using pseudo-second order kinetics and the Langmuir adsorption isotherm, respectively. These modified adsorbents synthesized from fly ash may provide a promising solution to purify dye-contaminated waste water with the advantages of high efficiency and low cost.

Type
Article
Copyright
Copyright © Clay Minerals Society 2016

References

Ahmed, Z.T. Hand, D.W. Watkins, M.K. and Sutter, L.L., 2014 Combined adsorption isotherms for measuring the adsorption capacity of fly ash in concrete ACS Sustainable Chemistry & Engineering 2 614620.CrossRefGoogle Scholar
Akar, T. Celik, S. Ari, A.G. and Akar, S.T., 2013 Removal of Pb2+ ions from contaminated solutions by microbial composite: combined action of a soilborne fungus Mucor plumbeus and alunite matrix Chemical Engineering Journal 215-216 626634.CrossRefGoogle Scholar
Akkaya, R., 2013 Removal of radioactive elements from aqueous solutions by adsorption onto polyacrylamideexpanded perlite: Equilibrium, kinetic, and thermodynamic study Desalination 321 38.CrossRefGoogle Scholar
Anirudhan, T.S. Rijith, S. and Suchithra, P.S., 2010 Preparation and characterization of iron(III) complex of an amino-functionalized polyacrylamide-grafted lignocellulosics and its application as adsorbent for chromium(VI) removal from aqueous media Journal of Applied Polymer Science 115 20692083.CrossRefGoogle Scholar
Baur, G.B. Yuranov, I. and Lioubov, K.M., 2015 Activated carbon fibers modified by metal oxide as effective structured adsorbents for acetaldehyde Catalysis Today 249 252258.CrossRefGoogle Scholar
Cavka, J.H. Grande, C.A. Mondino, G. and Blom, R., 2014 High pressure adsorption of CO2 and CH4 on Zr-MOFs Industrial & Engineering Chemistry Research 53 1550015507.CrossRefGoogle Scholar
Choi, S. Drese, J.H. and Jones, C.W., 2009 Adsorbent materials for carbon dioxide capture from large anthropo-genic point sources ChemSusChem 2 796854.CrossRefGoogle ScholarPubMed
Freundlich, H.M.F., 1906 Over the adsorption in solution Journal of Physical Chemistry 57A 385470.Google Scholar
Frydrych, M. Wan, C.Y. Stengler, R. O’Kelly, K.U. and Chen, B.Q., 2011 Structure and mechanical properties of gelatin/sepiolite nanocomposite foams Journal of Materials Chemistry 21 91039111.CrossRefGoogle Scholar
Fu, F. Gao, Z.W. Gao, L.X. and Li, D.S., 2011 Effective adsorption of anionic dye, alizarin red S, from aqueous solutions on activated clay modified by iron oxide Industrial & Engineering Chemistry Research 50 97129717.CrossRefGoogle Scholar
Ge, X.Y. Tian, F. Wu, Z.L. Yan, Y.J. Cravotto, G. and Wu, Z.S., 2015 Adsorption of naphthalene from aqueous solution on coal-based activated carbon modified by microwave induction: Microwave power effects Chemical Engineering and Processing 91 6777.CrossRefGoogle Scholar
Gupta, S.S. and Bhattacharyya, K.G., 2012 Adsorption of heavy metals on kaolinite and montmorillonite: A review Physical Chemistry Chemical Physics 14 66986723.CrossRefGoogle ScholarPubMed
Gupta, S.S. and Bhattacharyya, K.G., 2014 Adsorption of metal ions by clays and inorganic solids RSC Advances 4 2853728586.CrossRefGoogle Scholar
Hameed, B.H. Tan, I.A.W. and Ahmad, A.L., 2008 Adsorption isotherm kinetic modeling and mechanism of 2,4,6-trichlorophenol on coconut husk-based activated carbon Chemical Engineering Journal 144 144235144244.CrossRefGoogle Scholar
Hassan, M.M. Schiermeister, L. and Staiger, M.P., 2015 Thermal, chemical and morphological properties of carbon fibres derived from chemically pre-treated wool fibres RSC Advances 5 5535355362.CrossRefGoogle Scholar
Huang, S.Y. Yan, B. Wang, S.P. and Ma, X.B., 2015 Recent advances in dialkyl carbonates synthesis and applications Chemical Society Reviews 44 30793116.CrossRefGoogle ScholarPubMed
Idris, N.M. Jayakumar, M.K.G. Bansal, A. and Zhang, Y., 2015 Up conversion nanoparticles as versatile light nanotransducers for photoactivation applications Chemical Society Reviews 44 14491478.CrossRefGoogle Scholar
Ji, Q.H. Tabassum, S. Yu, G.X. Chu, C.F. and Zhang, Z.J., 2015 A high efficiency biological system for treatment of coal gasification wastewater — a key in-depth technological research RSC Advances 5 4040240413.CrossRefGoogle Scholar
Kim, H. Lee, B. and Byeon, S.H., 2015 The inner filter effect of Cr(VI) on Tb-doped layered rare earth hydroxychlorides: new fluorescent adsorbents for the simple detection of Cr(VI) Chemical Communications 51 725728.CrossRefGoogle Scholar
Koukouzas, N. Vasilatos, C. Itskos, G. Mitsis, I. and Moutsatsou, A., 2010 Removal of heavy metals from wastewater using CFB-coal fly ash zeolitic materials Journal of Hazardous Material 173 581588.CrossRefGoogle ScholarPubMed
Langmuir, I., 1918 The adsorption of gases on plane surfaces of glass, mica and platinum Journal of the American Chemical Society 40 13611403.CrossRefGoogle Scholar
Lee, J.D. Lee, S.H. Jo, M.H. Park, P.K. Lee, C.H. and Kwak, J.W., 2000 Effect of coagulation conditions on membrane filtration characteristics in coagulation-microfiltration process for water treatment Environmental Science & Technology 34 37803788.CrossRefGoogle Scholar
Lee, H. Kim, D. Kim, J. Ji, M.K. Han, Y.S. Park, Y.T. Yun, H.S. and Choi, J., 2015 As(III) and As(V) removal from the aqueous phase via adsorption onto acid mine drainage sludge (AMDS) alginate beads and goethite alginate beads Journal of Hazardous Material 292 146154.CrossRefGoogle Scholar
Liao, M.S. Zhao, Y.H. Ning, P.G. Cao, H.B. Wen, H. and Zhang, Y., 2014 Optimal design of solvent blend and its application in coking wastewater treatment process Industrial & Engineering Chemistry Research 53 1507115079.CrossRefGoogle Scholar
Liu, J. Thallapally, P.K. McGrail, B.P. Brown, D.R. and Liu, J., 2012 Progress in adsorption-based CO2 capture by metal-organic frameworks Chemical Society Reviews 41 23082322.CrossRefGoogle ScholarPubMed
Liu, D.Q. Zheng, Z.Z. Wang, C.Q. Yin, Y.Q. Liu, S.Q. Yang, B. and Jiang, Z.H., 2013 CdTe quantum dots encapsulated ZnO nanorods for highly efficient photoelectrochemical degradation of phenols Journal of Physical Chemistry C 117 2652926537.CrossRefGoogle Scholar
Ma, J. Zhuang,Y, a. and Yu, F., 2015 Facile method for the synthesis of a magnetic CNTs-C@Fe-chitosan composite and its application in tetracycline removal from aqueous solutions Physical Chemistry Chemical Physics 17 1593615944.CrossRefGoogle ScholarPubMed
Petit, C. and Bandosz, T.J., 2011 Synthesis, characterization, and ammonia adsorption properties of mesoporous metal-organic framework (MIL(Fe))-graphite oxide composites: Exploring the limits of materials fabrication Advanced Functional Materials 21 21082117.CrossRefGoogle Scholar
Pizarro, J. Castillo, X. Jara, S. Ortiz, C. Navarro, P. Cid, H. Rioseco, H. Barros, D. and Belzile, N., 2015 Adsorption of Cu2+ on coal fly ash modified with functionalized mesoporous silica Fuel 156 96102.CrossRefGoogle Scholar
Sevilla, M. and Mokaya, R., 2014 Energy storage applications of activated carbons: supercapacitors and hydrogen storage Energy & Environmental Science 7 12501280.CrossRefGoogle Scholar
Shi, Z.L. Yao, S.H. and Sui, C.C., 2011 Application of fly ash supported titanium dioxide for phenol photodegradation in aqueous solution Catalysis Science & Technology 1 817822.CrossRefGoogle Scholar
Sing, K.S.W. Everett, D.H. Haul, R.A.W. Mouscou, L. Pierotti, R.A. Rouquerol, J. and Siemieniewska, T., 1985 Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity Pure and Applied Chemistry 57 603619.CrossRefGoogle Scholar
Sun, Y.B. Chen, C.L. Tan, X.L. Shao, D.D. Li, J.X. Zhao, G.X. Yang, S.B. Wang, Q. and Wang, X.K., 2012 Enhanced adsorption of Eu(III) on mesoporous Al2O3/ expanded graphite composites investigated by macroscopic and microscopic techniques Dalton Transactions 41 1338813394.CrossRefGoogle ScholarPubMed
Tang, S.C.N. Yan, DYSI and Lo, M.C., 2014 Sustainable wastewater treatment using microsized magnetic hydrogel with magnetic separation technology Industrial & Engineering Chemistry Research 53 1571815724.CrossRefGoogle Scholar
Torrellas, S. Lovera, R.G. Escalona, N. Sepúlveda, C. Sotelo, J.L. and Garc¿a, J., 2015 Chemical-activated carbons from peach stones for the adsorption of emerging contaminants in aqueous solutions Chemical Engineering Science 279 788798.CrossRefGoogle Scholar
Upadhyay, R. Soin, K.N. and Roy, S.S., 2014 Role of graphene/metal oxide composites as photocatalysts, adsorbents and disinfectants in water treatment: A review RSC Advances 4 38233851.CrossRefGoogle Scholar
Wang, M.S. Liao, L.B. Zhang, X.L. Li, Z.H. Xia, Z.G. and Cao, W.D., 2011 Adsorption of low-concentration ammonium onto vermiculite from Heibei Province, China Clays and Clay Minerals 59 459465.CrossRefGoogle Scholar
Wang, Y.Z. Wang, W.B. and Wang, A.Q., 2013 Efficient adsorption of methylene blue on an alginate-based nanocomposite hydrogel enhanced by organo-illite/smectite clay Chemical Engineering Journal 228 132139.CrossRefGoogle Scholar
Wang, X.M. Chen, L.M. Liu, Y.N. and Huang, J.H., 2014 Macroporous crosslinked polydivinylbenzene/polyacryldiethylenetriamine (PDVB/PADETA) interpenetrating polymer networks (IPNs) and their efficient adsorption to oaminobenzoic acid from aqueous solution Journal of Colloid and Interface Science 429 8387.CrossRefGoogle Scholar
Wang, J.Z. Zhao, G.H. Li, Y.F. Zhu, H. Peng, X.M. and Gao, X., 2014 One-step fabrication of functionalized magnetic adsorbents with large surface area and their adsorption for dye and heavy metal ions Dalton Transactions 43 1163711645.CrossRefGoogle ScholarPubMed
Yang, S.X. Wang, L.Y. Zhang, X.D. Yang, W.J. and Song, G.L., 2015 Enhanced adsorption of Congo red dye by functionalized carbon nanotube/mixed metal oxides nanocomposites derived from layered double hydroxide precursor Chemical Engineering Journal 275 315321.CrossRefGoogle Scholar
Yin, C.Y. Ng, M.F. Saunders, M. Goh, B.M. Senanayake, G. Sherwood, A. and Hampton, M., 2014 New insights into the adsorption of aurocyanide ion on activated carbon surface: Electron microscopy analysis and computational studies using fullerene-like models Langmuir 30 77037709.CrossRefGoogle ScholarPubMed
Zhao, D.H. Zhang,Y.L, W. Y.P, a. and Gao, H.W., 2009 Facile eco-friendly treatment of a dye wastewater mixture by in situ hybridization with growing calcium carbonate Journal of Material Chemistry 19 72397244.CrossRefGoogle Scholar
Zhang, C.L. Wu, L. Cai, D.Q. Zhang, C.Y. Wang, N. Zhang, J. and Wu, Z.Y., 2013 Adsorption of polycyclic aromatic hydrocarbons (fluoranthene and anthracenemethanol) by functional graphene oxide and removal by pH and temperature-sensitive coagulation ACS Applied Materials & Interfaces 5 47834790.CrossRefGoogle ScholarPubMed
Zhang, J.X. Zhou, Q.X. and Li, W., 2013 Adsorption of enrofloxacin from aqueous solution by bentonite Clay Minerals 48 627637.CrossRefGoogle Scholar
Zheng, X.N. Wu, D.B. Su, T. Bao, S. and Liao, CA ^QG, 2014 Magnetic nanocomposite hydrogel prepared by ZnO-initiated photopolymerization for La(III) adsorption ACS Applied Materials & Interfaces 6 1984019849.CrossRefGoogle ScholarPubMed