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Hybrid Films Consisting of a Clay and a Diacetylenic, Two-Photon Absorptive Dye

Published online by Cambridge University Press:  01 January 2024

Yasutaka Suzuki ,
Shoichiro Hirakawa ,
Yusuke Sakamoto ,
Jun Kawamata ,
Kenji Kamada  and
Koji Ohta
Yasutaka Suzuki
Affiliation:
Department of Chemistry, Faculty of Science, Yamaguchi University, Yamaguchi 753-8512, Japan
Shoichiro Hirakawa
Affiliation:
Department of Chemistry, Faculty of Science, Yamaguchi University, Yamaguchi 753-8512, Japan
Yusuke Sakamoto
Affiliation:
Department of Chemistry, Faculty of Science, Yamaguchi University, Yamaguchi 753-8512, Japan
Jun Kawamata*
Affiliation:
Department of Chemistry, Faculty of Science, Yamaguchi University, Yamaguchi 753-8512, Japan
Kenji Kamada
Affiliation:
National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka, 563-8577, Japan
Koji Ohta
Affiliation:
National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka, 563-8577, Japan
*
* E-mail address of corresponding author: j_kawa@yamaguchi-u.ac.jp
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Abstract

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Hybrid films consisting of Sumecton SA smectite (SSA) and a diacetylenic two-photon absorptive dye; 1,4-bis(2,5-dimethoxy-4-{2-[4-(N-methyl)pyridinium]ethenyl}phenyl) butadiyne triflate (MPPBT) were fabricated. The MPPBT-clay composites were prepared by the cation exchange method in a dimethylsulfoxide (DMSO)-water mixed solvent. A low-light-scattering film, suitable for use in optical devices, was obtained by filtration of the dispersion of the MPPBT-clay composites. Estimation of the two-photon absorption cross-section (σ(2)) by means of the open-aperture Z-scan technique was performed using the present film. The σ(2) value of MPPBT in the film fabricated at the MPPBT loading levels vs. 20% cation exchange capacity was 1030 GM (1 GM= 1 × 1050 cm4 s photon−1 molecule−1) at an excitation wavelength of 800 nm. The value was 1.3 times greater than the maximum value of the σ(2) of MPPBT diss lved in DMSO with ut clay.

Keywords

Diacetylenic DyeFilmSynthetic SaponiteTwo-photon Absorption
Type
Article
Information
Clays and Clay Minerals , Volume 56 , Issue 5 , October 2008 , pp. 487 - 493
Copyright
Copyright © The Clay Minerals Society 2009

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