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Hydroxy-Nickel Interlayering in Montmorillonite by Titration Method

Published online by Cambridge University Press:  01 July 2024

S. Yamanaka  and
G. W. Brindley
S. Yamanaka
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, Pennsylvania 16802
G. W. Brindley
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, Pennsylvania 16802
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Abstract

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Nickel nitrate solution is potentiometrically titrated (a) with montmorillonite, (b) without montmorillonite, in the nitrate solution. X-ray powder diffraction and chemical analyses are made of the products formed by the clay at various stages of titration. The pH values of the titration curve (a) are lower than those of curve (b) until the brucite-like hydroxynickel interlayer is more or less complete. The resulting product then closely resembles a chlorite. The preferential precipitation of hydroxide in the interlayer region is explained in terms of the acidic character of montmorillonite interlayers.

Резюме

Резюме

Раствор азотнокислого никеля был потенциометрически титрован /а/ с монтмориллонитом и /в/ без монтмориллонита в раствор нитрата.Полученные из глины продукты были исследованы в порошке методом дифракции рентгеновских лучей и химическими анализами.Значения pH кривой титрования /а/ меньше,чем кривой /в/,пока более или менее не завершится формирование бруситоподобного прослоя гидроокиси никеля.После этого полученный продукт близко напоминает хлорит.Преимущественное осаждение гидроокиси между слоями объясняется кислотной средой,существующей на поверхностях слоев монтмориллонита.

Keywords

ChloriteInterlayerMontmorilloniteNickelPotentiometric
Type
Research Article
Information
Clays and Clay Minerals , Volume 26 , Issue 1 , February 1978 , pp. 21 - 24
Copyright
Copyright © 1978, The Clay Minerals Society

Footnotes

*

Also associated with the Department of Geosciences.

References

Brindley, G. W. and Semples, R. E. (1977) Preparation and properties of some hydroxy-aluminum beidellites: Clay Minerals 12, 229–237.CrossRefGoogle Scholar
Brown, G. and Newman, A. C. D. (1973) The reactions of soluble aluminum with montmorillonite. J. Soil Sci. 24, 339–354.CrossRefGoogle Scholar
Caillère, S. and Hénin, S. (1949) Formation of chlorite from montmorillonite: Mineral. Mag. 28, 612–620.Google Scholar
Carstea, D. D., Harward, M. E. and Knox, E. G. (1970) Comparison of iron and aluminum hydroxy interlayers in montmorillonite and vermiculite: I. Formation: Soil Sci. Soc. Am. Proc. 34, 517–521.CrossRefGoogle Scholar
Ducros, P. and Dupont, M. (1962) Study of protons in clay by nuclear magnetic resonance (NMR): Bull. Groupe Fr. Argiles 13, 59–63.CrossRefGoogle Scholar
Gupta, G. C. and Malik, W. U. (1969) Transformation of montmorillonite to nickel-chlorite: Clays & Clay Minerals 17, 233–239.CrossRefGoogle Scholar
Herrera, R. and Peech, M. (1970) Reaction of montmorillonite with iron (III): Soil Sci. Soc. Am. Proc. 34, 740–742.CrossRefGoogle Scholar
Mortland, M. M., Fripiat, J. J., Chaussidon, J. and Uytterhoeven, J. (1963) Interaction between ammonia and the expanding lattices of montmorillonite and vermiculite. J. Phys. Chem. 67, 248–258.CrossRefGoogle Scholar
Rich, C. I. (1968) Hydroxy interlayers in expansible layer silicates: Clays & Clay Minerals 16, 15–30.CrossRefGoogle Scholar
Sawhney, B. L. (1968) Aluminum interlayers in layer silicates. Effect of OH/Al ratio of Al solution, time of reaction, and type of structure: Clays & Clay Minerals 16, 157–163.CrossRefGoogle Scholar
Slaughter, M. and Milne, I. H. (1960) The formation of chlorite-like structures from montmorillonite: Clays & Clay Minerals 5, 114–124.Google Scholar
Touillaux, R., Salvador, P., Vandermeersche, C. and Fripiat, J. J. (1968) Study of water layers adsorbed on Na- and Ca-montmorillonite by the pulse NMR technique: Israel J. Chem. 6, 337–348.CrossRefGoogle Scholar
Yamanaka, S., Kanamaru, F. and Koizumi, M. (1974) Role of interlayer cations in the formation of acrylonitrile-montmorillonite complexes: J. Phys. Chem. 78, 42–44.CrossRefGoogle Scholar