Hostname: page-component-cd9895bd7-q99xh Total loading time: 0 Render date: 2024-12-26T22:01:17.715Z Has data issue: false hasContentIssue false
  • English
  • Français

Influence of Manganese Oxide Minerals on the Formation of Iron Oxides

Published online by Cambridge University Press:  02 April 2024

G. S. R. Krishnamurti  and
P. M. Huang
G. S. R. Krishnamurti
Affiliation:
Department of Soil Science, University of Saskatchewan, Saskatoon Saskatchewan S7N 0W0, Canada
P. M. Huang
Affiliation:
Department of Soil Science, University of Saskatchewan, Saskatoon Saskatchewan S7N 0W0, Canada
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The influence of manganese oxide minerals (cryptomelane, hausmannite, and pyrolusite) on the formation of iron oxides was studied in the FeCl2-NH4OH system at different Mn/Fe molar ratios (0, 0.01, 0.1, and 1.0) and pHs (3.0, 4.0, 5.0, and 6.0) by X-ray powder diffraction, infrared absorption, transmission electron microscopic, and chemical analyses. In the absence of Mn minerals, lepidocrocite (γ-FeOOH) precipitated at pHs 5.0 and 6.0; however, no precipitate formed at lower pHs. All the Mn minerals studied promoted the precipitation of iron oxides and oxyhydroxides. In the presence of Mn oxides, Fe2+ was oxidized to Fe3+, which hydrolyzed and precipitated as noncrystalline and/or different crystalline iron oxides and oxyhydroxides, depending on the nature of the Mn oxides present in the system. Simultaneously, Mn2+ was detected in solution after the reaction by electron spin resonance spectroscopy. The presence of cryptomelane and hausmannite resulted in the formation of åkaganeite (β-FeOOH) and magnetite (Fe3O4), respectively. Thus, the effect of Mn oxides on the formation of Fe oxide minerals in the weathering zone merits attention.

Keywords

ÅkaganeiteCryptomelaneFeroxyhyteHausmanniteIron oxidesManganeseOxidation-reductionPyrolusiteSynthesis
Type
Research Article
Information
Clays and Clay Minerals , Volume 36 , Issue 5 , October 1988 , pp. 467 - 475
Copyright
Copyright © 1988, The Clay Minerals Society

Footnotes

1

Contribution No. R. 568, Saskatchewan Institute of Pedology, University of Saskatchewan, Saskatoon, Saskatchewan, Canada.

2

For brevity, this term is used as a group name for Fe oxides and oxyhydroxides.

References

Afremow, L. C. and Vandeberg, J. T., 1966 High resolution spectra of inorganic pigments in the mid-infrared region from 1500 cm−1 to 200 cm−1 J. Paint Techn. 38 169 – 202.Google Scholar
Bielski, B. H. J. and Gebicke, J. M., 1967 Atlas of Electron Spin Resonance Spectra New York Academic Press.Google Scholar
Bricker, O., 1965 Some stability relations in the system Mn-O2-H2O at 25°C and one atmosphere total pressure Amer. Miner. 50 1296 – 1354.Google Scholar
Chao, T. T. and Zhou, L., 1983 Extraction technique for selective dissolution of amorphous iron oxides from soils and sediments Soil Sci. Soc. Amer. J. 47 225 – 232.CrossRefGoogle Scholar
Chukhrov, F. V., Zvyagin, B. B., Ermilova, L. P., Gorshkov, A. I. and Serratosa, J. M., 1973 New data on iron oxides in the weathering zone Proc. Int. Clay Conf, Madrid, 1972 Madrid Div. Ciencias C.S.I.C. 333 – 341.Google Scholar
Chukhrov, F. V., Zvyagin, B. B., Gorshkov, A. I., Yermilova, L. P., Korovushkin, V. V., Rudniskaya, Ye S and Yakubovaskaya, N Yu, 1977 Feroxyhyte, a new modification of FeOOH Int. Geol. Rev. 19 873 – 890.CrossRefGoogle Scholar
Eltantawy, I. M. and Arnold, P. W., 1973 Reappraisal of ethylene glycol monoethyl ether (EGME) method for surface area estimation of clays J. Soil Sci. 24 232 – 238.CrossRefGoogle Scholar
Farrell, D. M., 1972 Infrared absorption in the oxidation of magnetite to maghemite and hematite Dept, of Energy, Mines, Resources Canada, Mines Br. Inv. Rep. .CrossRefGoogle Scholar
Gadsden, J. A., 1975 Infrared Spectra of Minerals and Related Compounds London Butterworths.Google Scholar
Holm, N. G., 1985 New evidence for tubular structure of β-iron(III) oxide hydroxide-fikaganeite Origin of Life 15 131 – 139.Google Scholar
Jackson, M. L., 1979 Soil Chemical Analysis—An Advanced Course 2nd ed. Madison Department of Soil Science, University of Wisconsin.Google Scholar
Jenne, E. A., 1968 Controls of Mn, Fe, Co, Ni, Cu, and Zn concentrations in soils and water: the significant role of Mn and Fe oxides Adv. Chem. Ser. 73 337 – 387.CrossRefGoogle Scholar
Karim, Z., 1977 The control of iron hydroxides crystallization by traces of inorganic components in soil solution United Kingdom University of Reading, Reading 100 – 116.Google Scholar
Karim, Z., 1984 Characteristics of ferrihydrites formed by oxidation of FeCl2 solutions containing different amounts of silica Clays & Clay Minerals 32 181 – 184.CrossRefGoogle Scholar
Krishnamurti, G. S. R. and Huang, P. M., 1987 The catalytic role of bimessite in the transformation of iron Can. J. Soil Sci. 67 533 – 543.CrossRefGoogle Scholar
Liese, H. E., 1967 An infrared absorption analysis of magnetite Amer. Miner. 52 1198 – 1206.Google Scholar
Marshall, P. R. and Rutherford, D., 1971 Physical investigations on colloidal iron-dextran complexes J. Colloid Interface Sci. 37 390 – 402.CrossRefGoogle Scholar
McKenzie, R. M., 1971 The synthesis of bimessite, cryptomelane and some other oxides and hydroxides of manganese Mineral. Mag. 38 493 – 502.CrossRefGoogle Scholar
McKenzie, R. M., 1972 The manganese oxides in soils—A review Z. Pflanzener. Bodenkd. 131 221 – 242.CrossRefGoogle Scholar
McKenzie, R. M., Dixon, J. B. and Weed, S. B., 1977 Manganese oxides and hydroxides Minerals in Soil Environments Wisconsin Soil Sci. Soc. Amer., Madison 181 – 193.Google Scholar
Murray, J. J., 1975 The interaction of metal ions at the manganese dioxide-solution interface Geochim. Cosmochim. Acta 39 505 – 519.CrossRefGoogle Scholar
Murray, J. W. and Bums, R. G., 1979 Iron oxides Reviews in Mineralogy, Vol. 6, Marine Minerals Washington D.C. Mineral. Soc. America 47 – 98.Google Scholar
Nakamoto, K., 1970 Infrared Spectra of Inorganic and Coordination Compounds New York Wiley.Google Scholar
Oscarson, D. W., Huang, P. M., Defosse, C. and Herbillon, A., 1981 Oxidative power of Mn(IV) and Fe(III) oxides with respect to As(III) in terrestrial and aquatic environments Nature (London) 291 50 – 51.CrossRefGoogle Scholar
Oscarson, D. W., Huang, P. M., Liaw, W. K. and Hammer, U. T., 1983 Kinetics of oxidation of arsenite by various manganese dioxides Soil Sci. Soc. Amer. J. 47 644 – 648.CrossRefGoogle Scholar
Postma, D., 1985 Concentration of Mn and separation from Fe in sediments.—I. Kinetics and stoichiometry of the relation between bimessite and dissolved Fe(II) at 10°C Geochim. Cosmochim. Acta 49 1023 – 1033.CrossRefGoogle Scholar
Potter, R. M. and Rossman, G. R., 1979 The tetravalent manganese oxides: Identification, hydration, and structural relationships by infrared spectroscopy Amer. Mineral. 64 1199 – 1218.Google Scholar
Schwertmann, U., 1985 The effect of pedogenic environments on iron oxide minerals Adv. Soil Sci. 1 172 – 200.Google Scholar
Schwertmann, U., Kodama, H., Fischer, W. R., Huang, P. M. and Schnitzer, M., 1986 Mutual interactions between organics and iron oxides Interactions of Soil Minerals with Natural Organics and Microbes Wisconsin Soil Sci. Soc. Amer. Madison 223 – 250.Google Scholar
Schwertmann, U., Taylor, R. M., Dixon, J. B. and Weed, S. B., 1977 Iron oxides Minerals in Soil Environments Wisconsin Soil Sci. Soc. Amer. Madison 145 – 180.Google Scholar
Schwertmann, U. and Taylor, R. M., 1979 Natural and synthetic poorly crystallized lepidocrocite Clay Miner. 14 285 – 293.CrossRefGoogle Scholar
Schwertmann, U. and Thalmann, H., 1976 The influence of Fe(II), Si, and pH on the formation of lepidocrocite and ferrihydrite during oxidation of aqueous FeCl2 solutions Clay Miner. 11 189 – 200.CrossRefGoogle Scholar
Shindo, H. and Huang, P. M., 1982 Role of Mn(IV) oxide in abiotic formation of humic substances in the environment Nature (London) 298 363 – 366.CrossRefGoogle Scholar
Shindo, H. and Huang, P. M., 1984 Significance of Mn(IV) oxide in abiotic formation of organic nitrogen complexes in natural environments Nature (London) 308 57 – 58.CrossRefGoogle Scholar
Taylor, R. M. and Schwertmann, U., 1974 Maghemite in soils and its origin. II. Maghemite synthesis at ambient temperature and pH 7 Clay Miner. 10 299 – 310.CrossRefGoogle Scholar
van der Marel, H. W. and Beutelspacher, H., 1976 An Atlas of Infrared Spectroscopy of Clay Minerals and their Admixtures New York Elsevier.Google Scholar
Watson, J H L C Jr R R and Heller, W., 1962 The internal structure of colloidal crystals of β-FeOOH and remarks on their assemblies in schillar layers J. Phy. Chem. 66 1757 – 1763.CrossRefGoogle Scholar