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Infrared Spectroscopy Study of Tetrahedral and Octahedral Substitutions in an Interstratified Illite-Smectite Clay

Published online by Cambridge University Press:  28 February 2024

E. Srasra ,
F. Bergaya  and
J. J. Fripiat
E. Srasra
Affiliation:
Unité de chimie appliquée, I.N.R.S.T., B.P.: 95-2050, Hammam-Lif, Tunisie
F. Bergaya
Affiliation:
CRMD CNRS, 1 B, Rue de la férollerie, 45075, Orléans Cedex 2, France
J. J. Fripiat
Affiliation:
Department of Chemistry and Laboratory for Surface Studies, P.O. Box 413, University of Wisconsin-Milwaukee, Milwaukee, Wisconsin 53201
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Abstract

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Infrared spectroscopy is used to distinguish between octahedral and tetrahedral substitutions in an interstratified illite-smectite clay. The Hofmann-Klemen (Li) test suggests that the AlMg□ and FeMg□ octahedral vacancies are preferentially occupied by Li after thermal treatment at 250°C. The ammonium (Chourabi-Fripiat) test reveals the beidellitic character by the formation of two OH stretching modes upon deammonation. The illitic layers are not affected since K is not exchangeable.

Keywords

Chourabi-Fripiat testHofmann-Klemen effectIlliteInfrared spectroscopyInterstratifiedSmectiteTetrahedral substitution
Type
Research Article
Information
Clays and Clay Minerals , Volume 42 , Issue 3 , June 1994 , pp. 237 - 241
Copyright
Copyright © 1994, Clay Minerals Society

References

Bailey, S. W., Alietti, A., Formoso, M. L. L., Konta, H. M., Koster, K., Mackenzie, R. C., Morgan, D. J., Humpton, F. A., Magasawa, K., Paquet, H., Raussel-Colom, J. A., and Zvyagin, B. B., (1986) Report of AIEPA Nomenclature Committee, Supplement to the AIEPA newsletter.Google Scholar
Borchardt, G. A., (1977) Montmorillonite and other Smectites minerals: in Minerals in Soil Environments: Ed. Dixon, J. B. and Weed, S. B. Soil Science Society of America, Madison, Wisconsin, 299–330.Google Scholar
Caillère, S., Hénin, S., and Rautureau, M., (1982) Minéralogie des Argiles. 1. Structure et propriétés physico-chimiques. Ed. Masson, Paris, p. 70–80.Google Scholar
Calvet, R., and Prost, R., (1971) Cation migration into empty octahedral sites and surface properties of clays: Clays & Clay Minerals 19, 175–186.CrossRefGoogle Scholar
Chourabi, B., and Fripiat, J. J., (1981) Determination of tetrahedral substitutions and interlayer surface heterogeneity from vibrational spectra of ammonium in smectites: Clays & Clay Minerals 29, 260–268.CrossRefGoogle Scholar
Farmer, V. C., (1974) The layers silicates: in The Infrared Spectra of Minerals: Mineralogical Society, London, 331–363.CrossRefGoogle Scholar
Fripiat, J. J., Chaussidon, J., and Jelli, A., (1971) Chimie Physique des phénomènes de surface; Chap. 2. Ed. Masson et Cie, Paris, 32 p.Google Scholar
Glaeser, R., and Mering, J., (1967) Effet de chauffage sur les montmorillonites saturées de cations de petit rayon: C.R. Acad. Sci. Paris. 265, 833–835.Google Scholar
Hofmann, U., and Klemen, R., (1950) Verlust der Austauschfahigkeit von Lithiumionen an Bentonit durch Erhitzung: Z. Anorg. Chem. 262, 95–99.CrossRefGoogle Scholar
Kodama, H., (1985) Infrared Spectra of Minerals: Research branch, Agriculture Canada, 140–150.Google Scholar
Srasra, E., (1987) Caractérisation Minéralogique, Propriétés Physico-Chimiques et Application de l'Argile du Gisement Haïdoudi: Thèse de 3ème cycle, Université de Tunis II, 171 pp.Google Scholar
Srasra, E., Ariguib, N. K., Ayadi, F., Bergaya, F., and Van Damme, H., (1988) Mineralogical identification of a bentonite clay deposit located near Gabes (TUNISIA): J. Soc. Chim. Tunisie II: 7, 37–45.Google Scholar
Suquet, H., and Pezerat, H., (1988) Comments on the classification of trioctahedral 2: 1 phyllosilicates: Clays & Clay Minerals 36, 184–186.CrossRefGoogle Scholar
Van Der Marel, H. W., and Beutelspacher, H., (1976) Atlas of Infrared Spectroscopy of Clay Minerals and Their Admixtures: Elsevier, Amsterdam , 31–58.Google Scholar
Weaver, C., and Pollard, L., (1973) The Chemistry of Clay Minerals: Elsevier, Amsterdam , 55–77.Google Scholar