Hostname: page-component-78c5997874-t5tsf Total loading time: 0 Render date: 2024-11-10T06:12:12.020Z Has data issue: false hasContentIssue false
  • English
  • Français

Interstratification in Expandable Mica Produced by Cation-Exchange Treatment

Published online by Cambridge University Press:  28 February 2024

Hiroshi Tateyama ,
Hiroaki Noma ,
Satoshi Nishimura ,
Yoshio Adachi ,
Masaru Ooi  and
Kazuo Urabe
Hiroshi Tateyama
Affiliation:
Kyushu National Industrial Research Institute, Shuku-machi, Tosu city, Saga Prefecture, 841 Japan
Hiroaki Noma
Affiliation:
Kyushu National Industrial Research Institute, Shuku-machi, Tosu city, Saga Prefecture, 841 Japan
Satoshi Nishimura
Affiliation:
Kyushu National Industrial Research Institute, Shuku-machi, Tosu city, Saga Prefecture, 841 Japan
Yoshio Adachi
Affiliation:
Kyushu National Industrial Research Institute, Shuku-machi, Tosu city, Saga Prefecture, 841 Japan
Masaru Ooi
Affiliation:
CO-OP Chemicals Co. Ltd, 1-23-3, Chiyoda-ku, Tokyo, 102, Japan
Kazuo Urabe
Affiliation:
Department of Applied Chemistry, School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464, Japan
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

A unique interstratified expandable mica was obtained by cation exchange treatments using an expandable mica synthesized from talc. The 23Na magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectrum of the expandable mica used as a starting material showed that it had 2 kinds of Na+: one was exchangeable and the other was not exchangeable. Half of the Na+ per unit cell of the expandable mica was replaced with Mg2+ by cation exchange treatments. The X-ray powder diffraction (XRD) analysis of the Mg2+-exchanged expandable mica, after heating at 73°C, indicated that Na+ in the interlayer sheets was exchanged with Mg2+ in every second layer and that it had an interstratified structure with a 12.5-Å layer thickness and a 9.6-Å layer thickness. The structure of the Mg2+-exchanged expandable mica was changed into a unique interstratified structure by the calcination at 600°C; one component had a stacking sequence of talc and a small amount of OH−, but the other had a different stacking sequence from talc and no structural OH—.

Keywords

1H MAS NMR Spectra23Na29SiCation ExchangeInterstratificationMigration
Type
Research Article
Information
Clays and Clay Minerals , Volume 46 , Issue 3 , June 1998 , pp. 245 - 255
Copyright
Copyright © 1998, The Clay Minerals Society

References

Bagshaw, S.A. and Cooney, R.P., 1995 Preparation and characterization of a highly stable pillared clay: GaAl12-pillared rectorite Chem Mater 7 1384–1389 10.1021/cm00055a017.CrossRefGoogle Scholar
Bailey, S.W.. 1984. Crystal chemistry of the true micas. In: Bailey, S.W., editor. Micas. Washington DC: Mineral Soc Am p 13–60.CrossRefGoogle Scholar
Bailey, S.W.. 1988. Mixed layer chlorite minerals. In: Bailey, S.W., editor. Hydrous phyllosilicates. Washington DC: Mineral Soc Am p 601–630.CrossRefGoogle Scholar
Daimon, N., 1978 Synthetic micas with ultra fine powder Sci Am 8 9–19.Google Scholar
Engelhardt, G. and Michel, D., 1987 High-resolution solid-state NMR of silicate and zeolite New York J. Wiley 122–134.Google Scholar
Farmer, V.C. and Russell, J.D., 1967 Infrared absorption spectrometry in clay studies Clays Clay Miner 15 121–142 10.1346/CCMN.1967.0150112.CrossRefGoogle Scholar
Farnan, I. Kohn, S.C. and Dupree, R., 1987 A study of the structural role of water in hydrous silica glass using cross-polarization magic angle spinning NMR Geochim Cosmochim Acta 49 769–777.Google Scholar
Guan, J. Min, E. Yu, Z., Phillips, M.J. and Tewrnan, M., 1988 Highly stable cross-linked rec-torite product—A novel type of cracking catalyst Chem Inst Can Ottawa Ont. Proc Int Congr Catal 104–111.Google Scholar
Guan, J. and Pinnavaia, T.J., 1994 A pillared rectorite clay with highly stable supergalleries Mater Sci Forum: 109–114 .CrossRefGoogle Scholar
Hendricks, S. and Teller, E., 1942 X-ray interference in partially ordered layer lattices J Chem Phys 10 147–167 10.1063/1.1723678.CrossRefGoogle Scholar
Leonardelli, S. Facchini, L. Fretigny, C. Tougne, P. and Legrand, A., 1992 Silicon-29 nuclear magnetic resonance study of silica J Am Chem Soc 114 6412–6418 10.1021/ja00042a018.CrossRefGoogle Scholar
Perez, F.D. and Burlitch, J.M., 1995 Sol-gel synthesis of fluoride-substituted talc Chem Mater 7 2277–2283 10.1021/cm00060a015.CrossRefGoogle Scholar
Sakurai, H. Urabe, K. and Izumi, Y., 1990 Pillared tetrasilicic mica catalysts modified by fixed interlayer cations. Classification of fixation mode by cations Bull Chem Soc Jpn 63 1389–1395 10.1246/bcsj.63.1389.CrossRefGoogle Scholar
Sato, M., 1987 Interstratified (mixed layer) structures and their theoretical X-ray powder patterns. I. Theoretical aspects Clay Sci 7 1–48.Google Scholar
Sato, M., 1988 Interstratified (mixed layer) structures and their theoretical X-ray powder patterns. II. In the case of illite/montmorillonite interstratification Clay Sci 7 3–88.Google Scholar
Schöllenberger, C.J. and Simon, R.H., 1945 Determination of exchange capacity and exchangeable bases in soils Soil Sci 58 13–25 10.1097/00010694-194501000-00004.CrossRefGoogle Scholar
Shell, H.R. and Ivey, K.H., 1969 Fluorine micas US Bur Mines Bull 647 1–2910.Google Scholar
Singh, S.S. and Kodama, H., 1988 Reactions of polynuclear hy-droxyaluminum cations with montmorillonite and the formation of a 28-A pillared complex Clays Clay Mine 36 397–402 10.1346/CCMN.1988.0360503.CrossRefGoogle Scholar
Soma, M. Tanaka, A. Seyama, H. Hayashi, S. and Hayamizu, K., 1990 Bonding states of sodium in tetrasilicic sodium flour mica Clay Sci 8 1–8.Google Scholar
Suquet, H. Calle, C.D. and Pezerat, H., 1975 Selling and structural organization of saponite Clays Clay Miner 23 1–9 10.1346/CCMN.1975.0230101.CrossRefGoogle Scholar
Tateyama, H. Nishimura, S. Tsunematsu, K. Jinnai, K. Adachi, Y. and Kimura, M., 1992 Synthesis of expandable fluorine mica from talc Clays Clay Miner 40 180–185 10.1346/CCMN.1992.0400207.CrossRefGoogle Scholar
Tateyama, H. Shimoda, S. and Sudo, T., 1976 Infrared absorption spectra of synthetic Al-free magnesium micas N Jb Miner Mh H3 128–140.Google Scholar
Tateyama, H. Tsunematsu, K. Hirosue, H. Kimura, K. Furusawa, T. and Ishida, Y., 1990 Synthesis of the expandable fluorine mica from talc and its colloidal properties Proc 9fh Int Clay Conf Strasbourg II 128–140.Google Scholar
Tateyama, H. Tsunematu, K. Noma, H. and Adachi, Y., 1996 Formation of expandable mica from talc using intercalation procedures J Am Ceram Soc 179 3321–3324 10.1111/j.1151-2916.1996.tb08113.x.CrossRefGoogle Scholar
Tennakoon, D.T.B. Jones, W. and Thomas, J.M., 1987 Characterization of clay and pillared clay catalysis Solid State Ionics 24 205–212 10.1016/0167-2738(87)90161-5.CrossRefGoogle Scholar
Tennakoon, D.T.B. Thomas, J.M. Jones, W. Carpenter, T.A. and Ramdas, S., 1986 Characterization of clays and clay-organic systems J Chem Soc Faraday Trans I 82 545–562 10.1039/f19868200545.CrossRefGoogle Scholar
Tettenhorst, R., 1962 Cation migration in montmorillonites Am Mineral 47 769–773.Google Scholar
Urabe, K. Kenmoku, I. and Izumi, Y., 1996 Staging control in microporous pillared clay J Phys Chem Solids 95 1037–1041 10.1016/0022-3697(95)00392-4.CrossRefGoogle Scholar
Urabe, K. Kenmoku, I. Kawabe, K. and Izumi, Y., 1993 Aciditytunable pillared micas catalyst derived from talc .CrossRefGoogle Scholar
Zvyagin, B.B. Mischchenko, K.S. and Soboleva, S.V., 1969 Structure of pyrophyllite and talc in relation to the polytypes of mica-type minerals Soviet Phys Crust 13 511–515.Google Scholar