Hostname: page-component-78c5997874-lj6df Total loading time: 0 Render date: 2024-11-11T11:13:07.243Z Has data issue: false hasContentIssue false
  • English
  • Français

Investigation of the Thermal Decomposition of Talc

Published online by Cambridge University Press:  01 January 2024

Xiaowen Liu ,
Xiaoxu Liu  and
Yuehua Hu
Xiaowen Liu*
Affiliation:
School of Minerals Processing and Bioengineering, Central South University, 410083, Changsha, China
Xiaoxu Liu
Affiliation:
School of Minerals Processing and Bioengineering, Central South University, 410083, Changsha, China
Yuehua Hu
Affiliation:
School of Minerals Processing and Bioengineering, Central South University, 410083, Changsha, China
*
*E-mail address of corresponding author: onlylonely101@126.com
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Different changes in the structural and thermal properties of various types of talc have been reported in the literature which have made comparison of analytical results difficult. The objective of the present study was to obtain some fundamental insights into the effects of the thermal behavior of talc and to carry out kinetic analyses of the decomposition of talc under high temperature. X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and thermogravimetry-differential scanning calorimetry (TG-DSC) were used to study the thermal decomposition mechanism. The Coats-Redfern decomposition model was used to determine the decomposition mechanism of talc samples. The results showed that the decomposition of talc commenced at ~800°C, peaking at ~895°C, with the formation of enstatite and amorphous silica. An isothermal treatment at 1000°C caused the complete dehydroxylation of talc. The XRD and FTIR results indicated that the enstatite and amorphous silica phases were transformed into clinoenstatite and paracrystalline opal phases, respectively, after the decomposition stage at 1200°C. Good linearity in the Coats-Redfern model was observed from room temperature to 1300°C and the activation energy was calculated to be 69 kcal/mol.

Keywords

Activation EnergyCoats-RedfernThermal DecompositionTalc
Type
Article
Information
Clays and Clay Minerals , Volume 62 , Issue 2 , April 2014 , pp. 137 - 144
Copyright
Copyright © Clay Minerals Society 2014

References

Agarwal, R. Paul, A.S. Aggarwal, A.N. Gupta, D. and Jindal, S.K., 2011 A randomized controlled trial of the efficacy of cosmetic talc compared with iodopovidone for chemical pleurodesis Respirology 16 1064–1069.CrossRefGoogle ScholarPubMed
Aglietti, E.F. and Potto Lopez, J.M., 1992 Physicochemical and thermal properties of mechanochemically activated talc Materials Research Bulletin 27 1205–1216.CrossRefGoogle Scholar
Akhtar, M.J. Ahamed, M. Khan, M.A.M. Alrokayan, S.A. Ahmad, I. and Kumar, S., 2012.Cytotoxicity and apoptosis induction by nanoscale talc particles from two different geographical regions in human lung epithelial cells Environmental ToxicologyCrossRefGoogle Scholar
Avgustinik, A.I. and Vigdergauz, V.S., 1948 Properties of talc during heating Ogneupory 13 218–227.Google Scholar
Castillo, L. López, O. López, C. Zaritzky, N. García, M.A. Barbosa, S. and Villar, M., 2013 Thermoplastic starch films reinforced with talc nanoparticles Carbohydrate Polymers 95 664–674.CrossRefGoogle ScholarPubMed
Christidis, G.E. Makri, P. and Perdikatsis, V., 2004 Influence of grinding on the structure and colour properties of talc, bentonite and calcite white fillers Clay Minerals 39 163–175.CrossRefGoogle Scholar
Dellisanti, F. and Valdrè, G., 2010 On the high-temperature structural behaviour of talc (Mg3Si4O10(OH)2) to 1600°C: effect of mechanical deformation and strain Philosophical Magazine 90 2443–2457.CrossRefGoogle Scholar
Dellisanti, F. Valdrè, G. and Mondonico, M., 2009 Changes of the main physical and technological properties of talc due to mechanical strain Applied Clay Science 42 398–404.CrossRefGoogle Scholar
Dellisanti, F. Minguzzi, V. and Valdrè, G., 2011 Mechanical and thermal properties of a nanopowder talc compound produced by controlled ball milling Journal of Nanoparticle Research 13 5919–5926.CrossRefGoogle Scholar
Dritis, V.A. Guggenheim, S. Zviagina, B.B. and Kogure, T., 2012 Structures of the 2:1 layers of pyrophyllite and talc Clays and Clay Minerals 60 574–587.CrossRefGoogle Scholar
Elzea, J.M. Odom, I.E. and Miles, W.J., 1994 Distinguishing well ordered opal-CT and opal-C from high temperature cristobalite by X-ray diffraction Analytica Chimica Acta 286 107–116.CrossRefGoogle Scholar
Ewell, R.H. Bunting, E.N. and Geller, R.F., 1935 Thermal decomposition of talc Journal of Research of the National Bureau of Standards 15 551–556.CrossRefGoogle Scholar
Goel, A. Tulyaganov, D.U. Shaaban, E.R. Knee, C.S. Eriksson, S. and Ferreira, J.M.F., 2009 Structure and crystallization behaviour of some MgSiO3-based glasses Ceramics International 35 1529–1538.CrossRefGoogle Scholar
Gökçe, H. Ağaoğulları, D. Öveçoğlu, M.L. Dumana, I İ and Boyraz, T., 2011 Characterization of microstructural and thermal properties of steatite/cordierite ceramics prepared by using natural raw materials Journal of the European Ceramic Society 31 2741–2747.CrossRefGoogle Scholar
Inaki, Y. Yoshida, H. Yoshida, T. and Hattori, T., 2002 Active sites on mesoporous and amorphous silica materials and their photocatalytic activity: an investigation by FTIR, ESR, VUV-UV and photoluminescence spectroscopies Journal of Physical Chemistry B 106 9098–9106.CrossRefGoogle Scholar
Jamil, N.H. and Palaniandy, S., 2010 Acid medium sonication: A method for the preparation of low density talc nanosheets Powder Technology 200 87–90.CrossRefGoogle Scholar
Jamil, N.H. and Palaniandy, S., 2011 Comparative study of water-based and acid-based sonications on structural changes of talc Applied Clay Science 51 399–406.CrossRefGoogle Scholar
Kedesdy, H., 1943 Electron-microscope investigation of firing of talc and soapstone Berichte der Deutschen Keramischen Gesellschaft 24 201–232.Google Scholar
Lee, P. Sun, L. Lim, C.K. Aw, S.E. and Colt, H.G., 2010 Selective apoptosis of lung cancer cells with talc European Respiratory Journal 35 450–452.CrossRefGoogle ScholarPubMed
Mahadi, M.I. and Palaniandy, S., 2010 Mechanochemical effect of dolomitic talc during fine grinding process in mortar grinder International Journal of Mineral Processing 94 172–179.CrossRefGoogle Scholar
Maitra, S. and Bandyopadhyay, N., 2008 Application of non-Arrhenius method for analyzing the decomposition kinetics of SrCO3 and BaCO3 Journal of the American Ceramic Society 91 337–341.CrossRefGoogle Scholar
Mollah, M.Y.A. Promreuk, S. Schennach, R. Cocke, D.L. and Güler, R., 1999 Cristobalite formation from thermal treatment of Texas lignite fly ash Fuel 78 1277–1282.CrossRefGoogle Scholar
Okada, K. Ikawa, F. Isobe, T. Kameshima, Y. and Nakajima, A., 2009 Low temperature preparation and machinability of porous ceramics from talc and foamed glass particles Journal of the European Ceramic Society 29 1047–1052.CrossRefGoogle Scholar
Önal, M. and Sarıkaya, Y., 2007 The effect of heat treatment on the paracrystallinity of an opal-CT found in a bentonite Journal of Non-Crystalline Solids 353 4195–4198.CrossRefGoogle Scholar
Önal, M. Kahraman, S. and Sarıkaya, Y., 2007 Differentiation of a-cristobalite from opals in bentonites from Turkey Applied Clay Science 35 25–30.CrossRefGoogle Scholar
Palaniandy, S. and Azizli, K.A.M., 2009 Mechanochemical effects on talc during fine grinding process in a jet mill International Journal of Mineral Processing 92 22–33.CrossRefGoogle Scholar
Paterson, E. Swaffield, R. and Wilson, M.J., 1987 Thermal analysis A Handbook of Determinative Methods in Clay Mineralogy London Chapman & Hall 99–132.Google Scholar
Prasad, B.K. Rathod, S. Modi, O.P. and Yadav, M.S., 2010 Influence of talc concentration in oil lubricant on the wear response of a bronze journal bearing Wear 269 498–505.CrossRefGoogle Scholar
Ptáček, P. Lang, K. Šoukal, F. Opravil, T. Bartoníčková, E. and Tvrdík, L., 2014 Preparation and properties of enstatite ceramic foam from talc Journal of the European Ceramic Society 34 515–522.CrossRefGoogle Scholar
Qin, H.L. Zhang, S.M. Zhao, C.G. and Yang, M.S., 2005 Zero-order kinetics of the thermal degradation of polypropylene/clay nanocomposites Journal of Polymer Science Part B: Polymer Physics 43 3713–3719.CrossRefGoogle Scholar
Şahin, Özdemir, M. Aslanolu, M. and Beker, G., 2001 Calcination kinetics of ammonium pentaborate using the Coats-Redfern and genetic algorithm method by thermal analysis Industrial and Engineering Chemistry Research 40 1465–1470.CrossRefGoogle Scholar
Sarıkaya, Y. Önal, M. Baran, B. and Alemdaroğlu, T., 2000 The effect of thermal treatment on some of the physicochemical properties of a bentonite Clays and Clay Minerals 48 557–562.CrossRefGoogle Scholar
Schumann, D. Hartman, H. Eberl, D.D. Sears, S.K. Hesse, R. and Vali, H., 2013 The influence of oxalate-promoted growth of saponite and talc crystals on rectorite: testing the intercalation-synthesis hypothesis of 2:1 layer silicates Clays and Clay Minerals 61 342–360.CrossRefGoogle Scholar
Şener, S. and Özyılmaz, A., 2010 Adsorption of naphthalene onto sonicated talc from aqueous solutions Ultrasonics Sonochemistry 17 932–938.CrossRefGoogle ScholarPubMed
Smykatz-Kloss, W., 1974 Differential Thermal Analysis, Application and Results in Mineralogy Berlin Springer.CrossRefGoogle Scholar
Tang, W.J. Liu, Y.W. Zhang, H. and Wang, C.X., 2003 New approximate formula for Arrhenius temperature integral Thermochimica Acta 408 39–43.CrossRefGoogle Scholar
Terada, K. and Yonemochi, E., 2004 Physicochemical properties and surface free energy of ground talc Solid State Ionics 172 459–462.CrossRefGoogle Scholar
Wang, D.J. and Karato, S.-i., 2013 Electrical conductivity of talc aggregates at 0.5 GPa: influence of dehydration Physics and Chemistry of Minerals 40 11–17.CrossRefGoogle Scholar
Ward, J.R., 1975 Kinetics of talc dehydroxylation Thermochimica Acta 13 7–14.CrossRefGoogle Scholar
Wesolowski, M., 1984 Thermal decomposition of talc: a review Thermochimica Acta 78 395–421.CrossRefGoogle Scholar
Xu, X.F. Ding, Y.F. Wang, F. Wen, B. Zhang, J.H. Zhang, S.M. and Yang, M.S., 2010 Effects of silane grafting on the morphology and thermal stability of poly(ethylene terephthalate)/clay nanocomposites Polymer Composites 31 825–834.CrossRefGoogle Scholar
Yang, H.M. Du, C.F. Hu, Y.H. Jin, S.M. Yang, W.G. Tang, A.D. and Avvakumov, E.G., 2006 Preparation of porous material from talc by mechanochemical treatment and subsequent leaching Applied Clay Science 31 290–297.CrossRefGoogle Scholar
Yu, Y. Xue, G. Gu, C. Lou, J. and Li, S., 2013 Preparation of chitosan modified talc and its application in high filler content paper Journal of Applied Polymer Science 129 2692–2698.CrossRefGoogle Scholar
Zulumyan, N.H. Papakhchyan, L.R. Isahakyan, A.R. Beglaryan, H.A. and Aloyan, S.G., 2012 The influence of mechanical treatment on the silicate network of talc Russian Journal of Physical Chemistry A 86 1008–1013.CrossRefGoogle Scholar