Hostname: page-component-cd9895bd7-q99xh Total loading time: 0 Render date: 2024-12-27T13:54:09.208Z Has data issue: false hasContentIssue false
  • English
  • Français

Mapping Kaolinite and Dickite in Sandstone Thin Sections Using Infrared Microspectroscopy

Published online by Cambridge University Press:  01 January 2024

Valentin Robin ,
Sabine Petit ,
Daniel Beaufort  and
Dimitri Prêt
Valentin Robin*
Affiliation:
Université de Poitiers, CNRS UMR 7285 IC2MP, HydrASA Bât. B35, rue Michel Brunet, F-86022 Poitiers Cedex, France
Sabine Petit
Affiliation:
Université de Poitiers, CNRS UMR 7285 IC2MP, HydrASA Bât. B35, rue Michel Brunet, F-86022 Poitiers Cedex, France
Daniel Beaufort
Affiliation:
Université de Poitiers, CNRS UMR 7285 IC2MP, HydrASA Bât. B35, rue Michel Brunet, F-86022 Poitiers Cedex, France
Dimitri Prêt
Affiliation:
Université de Poitiers, CNRS UMR 7285 IC2MP, HydrASA Bât. B35, rue Michel Brunet, F-86022 Poitiers Cedex, France
*
*E-mail address of corresponding author: valentin.robin@univ-poitiers.fr
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

A method to characterize and map both kaolinite and dickite polytypes in sandstone thin sections using infrared microspectroscopy (IRMS) was developed. Minerals identification using IRMS can be performed using the hydroxyl-stretching band of most clay minerals (3500–4000 cm−1) in spite of infrared (IR) interferences caused by the embedding resin and glass substratum. Emphasis was placed on determining the optimum analytical conditions for IR data acquisition. The best data-acquisition parameters for Fourier-transform infrared (FTIR) measurements (i.e. spectra quality as a function of beam size and the number of scans) were obtained from a series of single spectra. Then, spatial resolution was explored as a function of the IR beam size (from 50 μm × 50 μm to 15 μm × 15 μm) and the step-scan interval (i.e. the distance between two successive analysis points). The IRMS measurements were performed on thin sections of materials characterized previously using scanning electron microscopy (SEM) and chemical analysis. Using IRMS, locations on the thin sections containing nearly pure dickite or kaolinite polytypes were identified and mapped. Most spectra collected using IRMS represented kaolin mineral aggregates rather than individual crystals, however, and mixing of kaolin polytypes was common at the spatial resolution of the IR beam size used. The spatial resolution of the IRMS was comparable to optical petrography and made possible the identification of areas on the thin section for further ‘in situ’ investigation using other methods (e.g. microprobe, Laser Ablation Inductively Coupled Plasma Mass Spectrometry — LA-ICP-MS, etc.). Also, the use of blocky crystal morphology to identify dickite was questioned, as kaolinite with blocky habit was identified. Mineral mapping using IRMS seems particularly suited for investigating petrographic relationships between kaolinite and dickite in sandstone diagenesis, but could also be used for clay minerals in other rock types or soils.

Keywords

DickiteIR MicrospectroscopyKaoliniteMineral MappingSandstone
Type
Research Article
Information
Clays and Clay Minerals , Volume 61 , Issue 2 , April 2013 , pp. 141 - 151
Copyright
Copyright © Clay Minerals Society 2013

References

Balan, E. Saitta, A.M. Mauri, F. and Calas, G., 2001 First-principles modeling of the infrared spectrum of kaolinite American Mineralogist 86 1321–1330.CrossRefGoogle Scholar
Balan, E. Lazzeri, M. Saitta, A.M. Allard, T. Fuchs, Y. and Mauri, F., 2005 First-principles study of OH-stretching modes in kaolinite, dickite, and nacrite American Mineralogist 90 50–60.CrossRefGoogle Scholar
Balan, E. Delattre, S. Guillaumet, M. and Salje, E.K.H., 2010 Low-temperature infrared spectroscopic study of OH-stretching modes in kaolinite and dickite American Mineralogist 95 1257–1266.CrossRefGoogle Scholar
Beaufort, D. Cassagnabere, A. Petit, S. Lanson, B. Berger, G. Lacharpagne, J.C. and Johansen, H., 1998 Kaolinite-to-dickite reaction in sandstone reservoirs Clay Minerals 33 297–316.CrossRefGoogle Scholar
Beauvais, A. and Bertaux, J., 2002 In situ characterization and differenciation of kaolinites in lateritic weathering profiles using infrared microspectroscopy Clays and Clay Minerals 50 314–330.CrossRefGoogle Scholar
Bish, D.L., 1993 Rietveld refinement of the kaolinite structure at 1.5 K Clays and Clay Minerals 41 738–744.CrossRefGoogle Scholar
Brindley, G.W. Kao, C.-C. Harrison, J.L. Lipsicas, M. and Raythatha, R., 1986 Relation between structural disorder and other characteristics of kaolinites and dickites Clays and Clay Minerals 34 239–249.CrossRefGoogle Scholar
Cassagnabere, A., 1998 Characterization and interpretation of kaolinite-to-dickite transition in Froy and Rind hydrocarbons reservoirs (North Sea, Norway) France University of Poitiers.Google Scholar
De Andrade, V. Vidal, O. Lewin, E. O’Brien, P. and Agard, P., 2006 Quantification of electron microprobe compositional maps of rock thin sections: an optimized method and examples Journal of Metamorphic Geology 24 655–668.CrossRefGoogle Scholar
Ehrenberg, S.N. Aagaard, P. Wilson, M.J. Fraser, A.R. and Duthie, D.M.L., 1993 Depth-dependent transformation of kaolinite to dickite in sandstones of the Norwegian continental shelf Clay Minerals 28 325–352.CrossRefGoogle Scholar
Farmer, V.C., 1974 The Infrared Spectra of Minerals London The Mineralogical Society.CrossRefGoogle Scholar
Farmer, V.C., 1998 Differing effects of particle size and shape in the infrared and Raman spectra of kaolinite Clay Minerals 33 601–604.CrossRefGoogle Scholar
Farmer, V.C. and Russell, J.D., 1964 The infra-red spectra of layer silicates Spectrochimica Acta 20 1149–1173.CrossRefGoogle Scholar
Frost, R.L. and van der Gaast, S.J., 1997 Kaolinite hydroxyls; a Raman microscopy study Clay Minerals 32 471–484.CrossRefGoogle Scholar
Frost, R.L. Tran, T.H. and Kristof, J., 1997 The structure of an intercalated ordered kaolinite; a Raman microscopy study Clay Minerals 32 587–596.CrossRefGoogle Scholar
Johnston, C.T. Agnew, S.F. and Bish, D.L., 1990 Polarized single-crystal Fourier-transform infrared microscopy of Ouray dickite and Keokuk kaolinite Clays and Clay Minerals 38 573–583.CrossRefGoogle Scholar
Johnston, C.T. Kogel, J.E. Bish, D.L. Kogure, T. and Murray, H.H., 2008 Low-temperature FTIR study of kaolin-group minerals Clays and Clay Minerals 56 470–485.CrossRefGoogle Scholar
Kameda, J S K Beaufort, D. and Kogure, T., 2008 Textures and polytypes in vermiform kaolins diagenetically formed in a sandstone reservoir: a FIB-TEM investigation European Journal of Mineralogy 20 199–204.CrossRefGoogle Scholar
Kogure, T. Inoue, A. and Beaufort, D., 2005 Polytype and morphology analyses of kaolins minerals by electron back-scattered diffraction Clays and Clay Minerals 53 201–210.CrossRefGoogle Scholar
Lanson, B. Beaufort, D. Berger, G. Baradat, J. and Lacharpagne, J.-C., 1996 Illitization of diagenetic kaolinite-to-dickite conversion series; late-stage diagenesis of the Lower Permian Rotliegend Sandstone reservoir, offshore of the Netherlands Journal of Sedimentary Research 66 501–518.Google Scholar
Lanson, B. Beaufort, D. Berger, G. Bauer, A. Cassagnabere, A. and Meunier, A., 2002 Authigenic kaolin and illitic minerals during burial diagenesis of sandstones: a review Clay Minerals 37 1–22.CrossRefGoogle Scholar
Ledoux, R.L. and White, J.L., 1964 Infrared study of the OH groups in expanded kaolinite Science 143 244–246.CrossRefGoogle ScholarPubMed
Madejová, J., Balan, E., and Petit, S. (2010) Application of vibrational spectroscopy to the characterization of phyllosilicates and other industrial minerals. Advances in the Characterization of Industrial Minerals (Christidis, G.E., editor). EMU Notes in Mineralogy, 9, European Mineralogical Union and the Mineralogical Society of Great Britain and Ireland, London.Google Scholar
McAulay, G.E. Burley, S.D. Fallick, A.E. and Kusznir, N.J., 1994 Palaeohydrodynamic fluid flow regimes during diagenesis of the Brent group in the Hutton-NW Hutton reservoirs; constraints from oxygen isotope studies of authigenic kaolin and reverse flexural modelling Clay Minerals 29 609–626.CrossRefGoogle Scholar
Munoz, M. de Andrade, V. Vidal, O. Lewin, E. Pascarelli, S. and Susini, J., 2006.Redox and speciation micromapping using dispersive X-ray absorption spectroscopy; application to iron in chlorite mineral of a metamorphic rock thin section Geochemistry, Geophysics, Geosystems — G3CrossRefGoogle Scholar
Osborne, M. Haszeldine, R.S. and Fallick, A.E., 1994 Variation in kaolinite morphology with growth temperature in isotopically mixed pore-fluids, Brent Group, UK North Sea Clay Minerals 29 591–608.CrossRefGoogle Scholar
Prêt, D. Sammartino, S. Beaufort, D. Meunier, A. Fialin, M. and Michot, L.J., 2010 A new method for quantitative petrography based on image processing of chemical element maps: Part I. Mineral mapping applied to compacted bentonites American Mineralogist 95 1379–1388.CrossRefGoogle Scholar
Prêt, D. Sammartino, S. Beaufort, D. Fialin, M. Sardini, P. Cosenza, P. and Meunier, A., 2010 A new method for quantitative petrography based on image processing of chemical element maps: Part II. Semi-quantitative porosity maps superimposed on mineral maps American Mineralogist 95 1389–1398.CrossRefGoogle Scholar
Prost, R. Damême, A. Huard, E. Driard, J., Schultz, L.G. van Olphen, H. and Mumpton, F.A., 1987 Infrared study of structural OH in kaolinite, dickite, and nacrite at 300 to 5 K International Clay Conference, Denver, 1985 Indiana, USA The Clay Minerals Society, Bloomington 17–23.Google Scholar
Prost, R. Dameme, A. Huard, E. Driard, J. and Leydecker, J.P., 1989 Infrared study of structural OH in kaolinite, dickite, nacrite, and poorly crystalline kaolinite at 5 to 600 K Clays and Clay Minerals 37 464–468.CrossRefGoogle Scholar
Rintoul, L. and Fredericks, P.M., 1995 Infrared microspectroscopy of bauxitic pisoliths Applied Spectroscopy 49 1608–1616.CrossRefGoogle Scholar
Tokiwai, K. and Nakashima, S., 2010 Integral molar absorptivities of OH in muscovite at 20 to 650ºC by insitu high-temperature IR microspectroscopy American Mineralogist 95 1052–1059.CrossRefGoogle Scholar