Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-28T05:42:40.475Z Has data issue: false hasContentIssue false
  • English
  • Français

Particle Interaction and Rheology of Illite-Iron Oxide Complexes

Published online by Cambridge University Press:  02 April 2024

Masami Ohtsubo ,
Akiko Yoshimura ,
Shin-Ichiro Wada  and
Raymond N. Yong
Masami Ohtsubo
Affiliation:
Department of Agricultural Engineering, Kyushu University, Fukuoka-shi 812, Japan
Akiko Yoshimura*
Affiliation:
Department of Agricultural Engineering, Kyushu University, Fukuoka-shi 812, Japan
Shin-Ichiro Wada
Affiliation:
Department of Agricultural Chemistry, Kyushu University, Fukuoka-shi 812, Japan
Raymond N. Yong
Affiliation:
Geotechnical Research Centre, McGill University, Montreal, Quebec H3A 2K6, Canada
*
1Present address: National Research Institute of Agricultural Engineering, Kan-nondai 2-chome, Tsukuba, Ibaraki 305, Japan.
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The Bingham yield stress for suspensions of illite-iron oxide complexes is examined as a function of pH and iron oxide content. Addition of iron oxides to illite increased the yield stress over a pH range of 3 to 10. With increasing pH the yield stress decreased for the complexes with iron oxides of 2 and 5% while the complexes with iron oxides of 7, 10, and 20% exhibited the maximum yield stresses at pH values from 6 to 8. The iron oxides which are not associated with the illite enhanced the yield stress more than the iron oxides precipitated on the illite surfaces. The yield stress for the complexes was correlated with their zeta potential, and the higher yield stress is considered due to smaller interparticle repulsion.

Keywords

Bingham yield stressMorphologyIlliteIron oxideParticle interactionZeta potential
Type
Research Article
Information
Clays and Clay Minerals , Volume 39 , Issue 4 , August 1991 , pp. 347 - 354
Copyright
Copyright © 1991, The Clay Minerals Society

References

El-Swaify, S. A., 1976 Changes in the physical properties of soil clays due to precipitated aluminum and iron hydroxides, II. Colloidal interaction in the absence of drying Soil Sci. Am. J. 40 516 – 520.CrossRefGoogle Scholar
El-Swaify, S. A., Emerson, W. W. and Theng, B. K. G., 1980 Physical and mechanical properties of oxisols Soils with Variable Charge. 303 – 324.Google Scholar
Follett, E. A. C., 1965 The retention of amorphous, colloidal ‘ferric hydroxide’ by kaolinites J. Soil Sci. 16 334 – 341.CrossRefGoogle Scholar
Greenland, D. J., 1975 Charge characteristics of some kaolinite-iron hydroxide complexes Clay Miner. 10 407 – 416.Google Scholar
Greenland, D. J., Mott, C. J. B., Greenland, D. J. and Hayes, M. H. B., 1978 Surface of soil particles The Chemistry of Soil Constituents New York John Wiley 321 – 351.Google Scholar
Greenland, D. J. and Oades, J. M., 1968 Iron hydroxides and clay surfaces Trans. 9th Int. Congr. Soil Sci., Adelaide 1 657 – 668.Google Scholar
Hendershot, W. H. and Carson, M. A., 1978 Changes in the plasticity of a sample of Champlain clay after selective chemical dissolution to remove amorphous material Can. Geotech. J. 15 609 – 616.CrossRefGoogle Scholar
Hiemenz, P. C., 1977 Principles of Colloid and Surface Chemistry New York Marcel Dekker.Google Scholar
Kavanagh, B. V. and Quirk, J. P., 1978 The adsorption of polycationic Fe(III) species on Na-illite Geoderma 21 225 – 238.CrossRefGoogle Scholar
Michaels, A. S., 1954 Aggregation of suspensions by poly-electrolytes Industrial and Eng. Chem. 46 1485 – 1490.CrossRefGoogle Scholar
Mori, S., Okamoto, H., Hara, T. and Aso, K., 1980 An improved method of determining the zeta-potential of mineral particles by micro-electrophoresis Proc. of the Inter. Symp. on fine particles processing 1 632 – 651.Google Scholar
Ohtsubo, M. and Wada, S., 1988 Consistency limits of kaolinite-amorphous iron hydroxide complexes and particle interaction J. Clay Sci. Soc. Japan 28 30 – 37.Google Scholar
Rand, B. and Melton, I. E., 1977 Particle interactions in aqueous kaolinite suspensions, I. Effect of pH and electrolyte upon the mode of particle interaction in homoionic sodium kaolinite suspensions J. Colloid Interface Sci. 60 308 – 320.CrossRefGoogle Scholar
Rengasamy, P. and Oades, J. M., 1977 Interaction of monomelic and polymeric species of metal ions with clay surfaces. 2 Changes in surface properties of clays after addition of iron(III) Amt. J. Soil Sci. 15 235 – 242.Google Scholar
Saleh, A. M. and Jones, A. A., 1984 The crystallinity and surface characteristics of synthetic ferrihydrite and its relationship to kaolinite surfaces Clay Miner. 19 745 – 755.CrossRefGoogle Scholar
Schwertmann, U., Taylor, R. M., Dixon, J. B. and Weed, S. B., 1989 Iron oxides Minerals in Soil Environments Madison, WI Soil Sci. Soc. Am. 379 – 427.Google Scholar
Sumner, M. E., 1963 Effect of iron oxides on positive and negative charges in clays and soils Clay Miner. Bull. 5 218 – 226.CrossRefGoogle Scholar
Torrance, J. K., 1984 A comparison of marine clays from Ariake Bay, Japan and the South Nation River landslide site, Canada Soils and Foundations 24 75 – 81.CrossRefGoogle Scholar
Torrance, J. K., Hedges, S. W. and Bowen, L. H., 1986 Mössbauer spectroscopic study of the iron mineralogy of post-glacial marine clays Clays & Clay Minerals 34 314 – 322.CrossRefGoogle Scholar
Van Olphen, H., 1977 An Introduction to Clay Colloid Chemistry 2nd New York John Wiley & Sons 92 – 95.Google Scholar
Yong, R. N. and Ohtsubo, M., 1987 Interparticle action and rheology of kaolinite-amorphous iron hydroxide complexes Applied Clay Sci. 2 63 – 81.CrossRefGoogle Scholar
Yong, R. N., Sethi, A. J., Booy, E. and Dascal, O., 1979 Basic characterization and effect of some chemicals on a clay from Outardes 2 Eng. Geology 14 83 – 107.CrossRefGoogle Scholar