Hostname: page-component-cd9895bd7-jkksz Total loading time: 0 Render date: 2024-12-26T06:34:33.488Z Has data issue: false hasContentIssue false
  • English
  • Français

Patterned Deposition of Allophane Nanoparticles on Silicon Substrates

Published online by Cambridge University Press:  01 January 2024

Marco Fuchs ,
Zaenal Abidin ,
Christian Kübel ,
Peter G. Weidler ,
Naoto Matsue ,
Teruo Henmi ,
Rainer Köster  and
Hartmut Gliemann
Marco Fuchs
Affiliation:
Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT) Campus North, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
Zaenal Abidin
Affiliation:
Faculty of Agriculture, Ehime University Tarumi, 3-5-7, Matsuyama, Ehime Prefecture, 790-8566 Japan Department of Chemistry, Faculty of Natural Science and Mathematics, Bogor Agricultural University, Kampus Darmaga, Bogor, West of Java, Indonesia
Christian Kübel
Affiliation:
Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT) Campus North, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
Peter G. Weidler
Affiliation:
Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT) Campus North, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
Naoto Matsue
Affiliation:
Faculty of Agriculture, Ehime University Tarumi, 3-5-7, Matsuyama, Ehime Prefecture, 790-8566 Japan
Teruo Henmi
Affiliation:
Faculty of Agriculture, Ehime University Tarumi, 3-5-7, Matsuyama, Ehime Prefecture, 790-8566 Japan
Rainer Köster
Affiliation:
Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT) Campus North, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany Institute of Analytical Chemistry, Chemo- and Biosensors, University of Regensburg, Universitätsstrabe 31, 93053 Regensburg, Germany
Hartmut Gliemann*
Affiliation:
Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT) Campus North, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
*
*E-mail address of corresponding author: hartmut.gliemann@kit.edu
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

In order to obtain nanopatterned surfaces, natural allophane particles originating from Japanese soils were immobilized as single particles on Si wafer substrates.When derived from aqueous suspensions, only a few nanoparticles were deposited and detected on the surface due to the weak adsorption of allophanes on the substrate. The amount of immobilized allophane was increased significantly, however, by using an organic solvent in combination with a micelle-based technique to suspend the allophane particles. The micelles were formed from a tailored, aliphatic diblock copolymer that was dissolved in toluene and contained several allophane particles. A cleaned silica chip was used as a substrate on which a monolayer of micelles was immobilized equidistant from each other by dip coating. To remove the polymer from the substrate and to produce free, single allophane nanoparticles, ultraviolet (UV) irradiation was used. After UV treatment, single allophane particles formed ring-shaped deposition patterns with a high surface density. Transmission electron microscopy (TEM) was used to verify the presence of single allophane nanoparticles in the Japanese samples which came from natural sources. The single allophane particles as well as the allophane-containing di-block copolymer micelles, both immobilized on Si substrates and TEM sample grids, were imaged by atomic force microscopy and TEM. In this way, the diameters of the single allophane particles, as well as the distances between the immobilized micelles and the particles and their topography on the substrates, were determined.

Keywords

AFMAllophaneDiblock CopolymerMicelleNanoparticleNanostructuring
Type
Article
Information
Clays and Clay Minerals , Volume 60 , Issue 5 , October 2012 , pp. 456 - 463
Copyright
Copyright © Clay Minerals Society 2012

References

Abidin, Z. Matsue, N. and Henmi, T., 2007 Nanometerscale chemical modification of nano-ball allophane Clays and Clay Minerals 55 443–449.CrossRefGoogle Scholar
Abidin, Z. Matsue, N. and Henmi, T., 2007 Differential formation of allophane and imogolite: experimental and molecular orbital study Journal of Computer-Aided Materials Design 14 5–18.CrossRefGoogle Scholar
Creton, B. Bougeard, D. Smirnov, K.S. Guilment, J. and Poncelet, O., 2008 Structural model and computer modeling study of allophane Journal of Physical Chemistry C 112 258–364.CrossRefGoogle Scholar
Glass, R. Arnold, M. Blümmel, J. Küller, A. Möller, M. and Spatz, J.P., 2003 Micro-nanostructured interfaces fabricated by the use of inorganic block copolymer micellar monolayers as negative resist for electron-beam lithography Advanced Functional Materials 13 569–575.CrossRefGoogle Scholar
Henmi, T. and Wada, K., 1976 Morphology and composition of allophane American Mineralogist 61 379–390.Google Scholar
Higashi, T. and Ikeda, H., 1974 Dissolution of allophane by acid oxalate solution Clay Science 4 205–212.Google Scholar
Karube, J. Nakaishi, K. Sugimoto, H. and Fujihira, M., 1996 Size and shape of allophane particles in dispersed aqueous systems Clays and Clay Minerals 44 485–491.CrossRefGoogle Scholar
Kaufhold, S. Kaufhold, A. Jahn, R. Brito, S. Dohrmann, R. Hoffmann, R. Gliemann, H. Weidler, P. and Frechen, M., 2009 A new massive deposit of allophane raw material in Ecuador Clays and Clay Minerals 57 72–81.CrossRefGoogle Scholar
Lipski, A.M. Jaquiery, C. Choi, H. Eberly, D. Stevens, M. Martin, I. Wei Chen, I. and Shastri, P., 2007 Nanoscale engineering of biomaterial surfaces Advanced Materials 19 553–557.CrossRefGoogle Scholar
Lohmueller, T. Bock, E. and Spatz, P., 2008 Synthesis of quasi-hexagonal ordered arrays of metallic nanoparticles with tuneable particle size Advanced Materials 20 2297–2302.CrossRefGoogle Scholar
Manzke, A. Pfahler, C.h. Dubbers, O. Plettl, A. Ziemann, P. Crespy, D. Schreiber, E. Ziener, U. and Landfester, K., 2007 Etching masks based on miniemulsions: a novel route towards ordered arrays of surface nanostructures Advanced Functional Materials 19 1337–1341.Google Scholar
Nishikiori, H. Furukawa, M. and Fujii, T., 2011 Degradation of trichloroethylene using highly adsorptive allophane-TiO2 nanocomposite Applied Catalysis B: Environmental 102 470–474.CrossRefGoogle Scholar
Ogaki, Y. Shinozuka, Y. Hara, T. Ichikuni, N. and Shimazu, S., 2011 Hemicellulose decomposition and saccharides production from various plant biomass by sulfonated allophane catalyst Catalysis Today 146 415–418.CrossRefGoogle Scholar
Onodera, Y. Iwasaki, T. Chatterjee, A. Ebina, T. Satoh, T. Suzuki, T. and Mimura, H., 2001 Bactericidal allophanic materials prepared from allophane soil. I. Preparation and characterization of silver/phosphorus-silver loaded allophanic specimens Applied Clay Science 18 123–134.CrossRefGoogle Scholar
Sikora, A. and Tuzar, Z., 2004 Association of two-block copolymer polystyrene-block-poly(2-vinylpyridine) in toluene Macromolecular Chemistry and Physics 184 2049–2059.CrossRefGoogle Scholar
Villarrubia, J.S., 1997 Algorithms for scanned probe microscope image simulation, surface reconstruction, and tip estimation Journal of Research of the National Institute of Standards and Technology 102 425–454.CrossRefGoogle ScholarPubMed
Vu, D.-H. Wang, K.-S. Nam, B.X. Bac, B.H. and Chu, T.-C., 2011 Preparation of humidity-controlling porous ceramics from volcanic ash and waste glass Ceramics International 37 2845–2853.CrossRefGoogle Scholar
Watanabe, K. Nakazawa, H. and Matsui, Y., 2009 Allophane films formed at the liquid/liquid interface Applied Clay Science 46 330–332.CrossRefGoogle Scholar
Woignier, T. Primera, J. Duffours, L. Dieudonné, P. and Raada, A., 2008 Preservation of the allophanic soils structure by supercritical drying Microporous and Mesoporous Materials 109 370–375.CrossRefGoogle Scholar
Xie, M. and Blum, F.D., 1996 Dynamics of poly(styrene-b-2-vinylpyridine) in toluene Macromolecules 29 3862–3867.CrossRefGoogle Scholar
Xie, M. and Blum, F.D., 1996 Adsorption and dynamics of low molecular weight poly(styrene-b-2-vinylpyridine) on silica and alumina in Toluene Langmuir 12 5669–5673.CrossRefGoogle Scholar