Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2024-12-26T08:38:21.017Z Has data issue: false hasContentIssue false
  • English
  • Français

A Polarized Infrared and X-Ray Study of Lysine-Vermiculite

Published online by Cambridge University Press:  01 July 2024

M. Raupach ,
P. G. Slade ,
L. Janik  and
E. W. Radoslovich
M. Raupach
Affiliation:
C.S.I.R.O. Division of Soils, Glen Osmond, S. Australia 5064
P. G. Slade
Affiliation:
C.S.I.R.O. Division of Soils, Glen Osmond, S. Australia 5064
L. Janik
Affiliation:
C.S.I.R.O. Division of Soils, Glen Osmond, S. Australia 5064
E. W. Radoslovich*
Affiliation:
C.S.I.R.O. Division of Soils, Glen Osmond, S. Australia 5064
*
*Division of Soils, C.S.I.R.O., Adelaide, Australia
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Lysine and vermiculite form a stable, ordered, interlamellar complex which has a well defined superlattice structure with respect to the ab-plane of vermiculite. The lysine molecules lie at a low angle to the silicate surfaces and establish a double layer network between such surfaces. I.R. and chemical data for the complex are given. The possible role of hydrogen bonds in linking the system together is considered.

Type
Research Article
Information
Clays and Clay Minerals , Volume 23 , Issue 3 , June 1975 , pp. 181 - 186
Copyright
Copyright © 1975, The Clay Minerals Society

References

Adamowicz, R. and Fishman, E., (1972) Some observations of the vibrational spectrum of single crystalline b-alanine Spectrochim, Acta 28A 889–895.CrossRefGoogle Scholar
Farmer, V. C., (1971) The characterization of adsorption bonds in clays by i.r. spectroscopy Soil Sci. 112 62–68.CrossRefGoogle Scholar
Flournoy, P. A. and Schaffers, W. J., (1966) Attenuated total reflection spectra from surfaces of anisotropic, absorbing films Spectrochim. Acta. 22 5–13.CrossRefGoogle Scholar
Fraser, R. D. B. and Suzuki, E., (1969) Resolution of overlapping bands: functions for simulating band shapes Anal. Chem. 41 37–39.CrossRefGoogle Scholar
Fripiat, J. J. Pennequin, M. Poncelet, G. and Cloos, P., (1969) The influence of the Van Der Waals force on the i.r. spectra of short aliphatic alkylammonium cations held on montmorillonite Clay Minerals 8 119–134.CrossRefGoogle Scholar
Garrett, W., (1962) Complexes of vermiculite with amino acids 1st Australian Conf. on Clay Minerals and Related Topics, Melbourne. Abstracts of papers .Google Scholar
Garrett, W. G. and Walker, G. F., (1962) Swelling of some vermiculite-organic complexes in water Clays and Clay Minerals 9 557–567.CrossRefGoogle Scholar
Jang, S. D. and Condrate, R. A., (1972) The i.r. spectra of lysine adsorbed on several cation-substituted montmorillonites Clays and Clay Minerals 20 79–82.Google Scholar
Koetzle, T. F. Lehman, M. S. Verbist, J. J. and Hamilton, W. C., (1972) Precision neutron diffraction structure determination of protein and nucleic acid components—VII. The crystal and molecular structure of the amino acid l-lysine monohydrochloride dihydrate Acta Cryst. B28 3207–3213.CrossRefGoogle Scholar
Mathieson, A McL and Walker, G. F., (1954) Crystal structure of magnesium vermiculite Am. Miner. 39 231–255.Google Scholar
Mifsud, A. Fornes, V. and Rausell-Colom, J. A., (1970) Cationic complexes of vermiculite with l-ornithine Reunion Hispano-Belga de Minérales de la Arcilla 121–127.Google Scholar
Norrish, K. and Hutton, J. T., (1969) An accurate X-ray spectrographic method for the analysis of a wide range of geological samples Geochim. Cosmochim. Acta 33 431–453.CrossRefGoogle Scholar
Norrish, K., (1972) Factors in the weathering of mica to vermiculite Preprints, Int. Clay Conf. 2 83–101.Google Scholar
Pearson, J. F. and Slifkin, M. A., (1972) The i.r. spectra of amino acids and dipeptides Spectrochim. Acta 28A 2403–2417.CrossRefGoogle Scholar
Rausell-Colom, J. A. and Salvador, P. S., (1971) Gelification de vermiculite dans des solutions d’acide γ-amino-butyrique Clay Minerals 9 193–208.CrossRefGoogle Scholar
Serratosa, J. M. Johns, W. D. and Shimoyama, A., (1970) I.r. study of alkylammonium vermiculite complexes Clays and Clay Minerals 18 107–113.CrossRefGoogle Scholar
Suzuki, S. and Shimanouchi, T., (1963) Normal vibrations of glycine and deuterated glycine molecules Spectrochim. Acta 19 1195–1208.CrossRefGoogle Scholar
Takenaka, T. Nogami, K. Gotoh, H. and Gotoh, R., (1971) Studies on built-up films by means of polarized infrared ATR spectrum—I. Built-up films of stearic acid J. Colloid Interface Sci. 35 395–402.CrossRefGoogle Scholar
Tsuboi, M. Takenishi, T. and Nakamura, A., (1963) Some characteristic frequencies of amino acids Spectrochim. Acta 19 271–284.CrossRefGoogle Scholar
Walker, G. F., (1960) Macroscopic swelling of vermiculite crystals in water Nature, Land. 187 312–313.CrossRefGoogle Scholar
Walker, G. F. and Garrett, W. G., (1961) Complexes of vermiculite with amino-acids Nature, Lond. 191 1389.CrossRefGoogle Scholar
Walker, G. F., (1967) Interactions of n-alkylammonium ions with mica-type layer lattices Clay Minerals 7 129–143.CrossRefGoogle Scholar
Zoltai, T., (1963) Double spots and their elimination in precession photography Am. Miner. 48 759–771.Google Scholar