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Removal of Reactive Brilliant Orange X-GN from Aqueous Solutions By Mg-Al Layered Double Hydroxides

Published online by Cambridge University Press:  01 January 2024

Pingxiao Wu ,
Qian Zhang ,
Yaping Dai ,
Nengwu Zhu ,
Ping Li ,
Jinhua Wu  and
Zhi Dang
Pingxiao Wu*
Affiliation:
College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, P.R. China The Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006, P.R. China The Key Laboratory of Environmental Protection and Eco-Remediation of Guangdong Regular Higher Education Institutions, P. R. China
Qian Zhang
Affiliation:
College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, P.R. China
Yaping Dai
Affiliation:
College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, P.R. China
Nengwu Zhu
Affiliation:
College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, P.R. China The Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006, P.R. China The Key Laboratory of Environmental Protection and Eco-Remediation of Guangdong Regular Higher Education Institutions, P. R. China
Ping Li
Affiliation:
College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, P.R. China The Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006, P.R. China
Jinhua Wu
Affiliation:
College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, P.R. China The Key Laboratory of Environmental Protection and Eco-Remediation of Guangdong Regular Higher Education Institutions, P. R. China
Zhi Dang
Affiliation:
College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, P.R. China The Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006, P.R. China The Key Laboratory of Environmental Protection and Eco-Remediation of Guangdong Regular Higher Education Institutions, P. R. China
*
* E-mail address of corresponding author: pppxwu@scut.edu.cn
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Abstract

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Among the many techniques used to remove toxic dyes from the environment, layered double hydroxides (LDH) are considered to be especially environmentally friendly, but, this quality may be altered by variations in the octahedral Mg/Al molar ratios in the LDH structure. The aim of the present study was to synthesize environmentally sound LDH for use as an economically viable sorbent for the adsorption of reactive brilliant orange X-GN. Layered double hydroxides with Mg/Al molar ratios of 2:1 and 4:1 were prepared by co-precipitation. The materials obtained were characterized by powder X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, X-ray fluorescence spectroscopy (XRF), and surface-area analysis. Batch experiments were carried out to investigate the effects of contact time, pH, adsorbent dosage, and initial dye concentration on the adsorption behavior of the reactive brilliant orange X-GN by Mg-Al LDH. The results showed that the optimum pH value for dye adsorption was 3.0, at which the adsorption capacities of the reactive brilliant orange X-GN by the 2:1 LDH and the 4:1 LDH at 298 K were 79.370 mg/g and 83.343 mg/g, respectively. Further analysis of the dye-adsorption kinetics show that they fit the pseudo second-order model well. The adsorption equilibrium data showed that the Langmuir model provided better correlation of the equilibrium data than the Freundlich model. This result indicates that LDH provide specific homogeneous sites where monolayer dye adsorption occurs. The results of XRD and FTIR analyses of LDH before and after the dye adsorption demonstrated that the adsorption mechanisms were ion exchange and coulombic attraction.

Keywords

Dye AdsorptionLayered Double HydroxidesReactive Brilliant Orange X-GN
Type
Article
Information
Clays and Clay Minerals , Volume 59 , Issue 5 , October 2011 , pp. 438 - 445
Copyright
Copyright © Clay Minerals Society 2011

References

Aksu, Z. and Dönmez, G., 2003 A comparative study on the biosorption characteristics of some yeasts for Remazol Blue reactive dye Chemosphere 50 1075–1083 10.1016/S0045-6535(02)00623-9.CrossRefGoogle ScholarPubMed
Al-Degs, Y.S. El-Barghouthi, M.I. El-Sheikh, A.H. and Walker, G.M., 2008 Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon Dyes and Pigments 77 16–23 10.1016/j.dyepig.2007.03.001.CrossRefGoogle Scholar
Anirudhan, T.S. and Radhakrishnan, P.G., 2009 Kinetics, thermodynamics and surface heterogeneity assessment of uranium (VI) adsorption onto cation exchange resin derived from a lignocellulosic residue Applied Surface Science 255 4983–4991 10.1016/j.apsusc.2008.12.047.CrossRefGoogle Scholar
Beaudot, P. De Roy, M.E. and Besse, J.P., 2004 Preparation and characterization of intercalation compounds of layered double hydroxides with Metallic Oxalato complexes Chemistry of Materials 16 935–945 10.1021/cm0311067.CrossRefGoogle Scholar
Chen, S.L. Xu, Z.P. Zhang, Q. Max Lu, G.Q. Hao, Z.P. and Liu, S.M., 2009 Studies on adsorption of phenol and 4-nitrophenol on MgAl-mixed oxide derived from MgAl-layered double hydroxide Separation and Purification Technology {b67} 194–200 10.1016/j.seppur.2009.03.016.CrossRefGoogle Scholar
Cheng, X. Huang, X.R. Wang, X.Z. Zhao, B.Q. Chen, A.Y. and Sun, D.Z., 2009 Phosphate adsorption from sewage sludge filtrate using zinc-aluminum layered double hydroxides Journal of Hazardous Materials 169 958–964 10.1016/j.jhazmat.2009.04.052.CrossRefGoogle ScholarPubMed
Chuang, Y.H. Tzou, Y.M. Wang, M.K. Liu, C.H. and Chiang, P.N., 2008 Removal of 2-Chlorophenol from aqueous solution by Mg/Al layered double hydroxide (LDH) and modified LDH Industrial & Engineering Chemistry Research 47 3813–3819 10.1021/ie071508e.CrossRefGoogle Scholar
Dadwhal, M. Kim, T.W. Sahimi, M. and Tsotsis, T.T., 2008 Study of CO2 diffusion and adsorption on calcined layered double hydroxides: The effect of particle size Industrial & Engineering Chemistry Research 47 6150–6157 10.1021/ie701701d.CrossRefGoogle Scholar
Forgacs, E. Cserháti, T. and Oros, G., 2004 Removal of synthetic dyes from wastewaters: a Review Environment International 30 953–971 10.1016/j.envint.2004.02.001.CrossRefGoogle ScholarPubMed
Goh, K.-H. Lim, T.-T. and Dong, Z., 2008 Application of layered double hydroxides for removal of oxyanions: A review Water Research 42 1343–1368 10.1016/j.watres.2007.10.043.CrossRefGoogle ScholarPubMed
Goh, K.-H. Lim, T.-T. and Dong, Z., 2009 Enhanced arsenic removal by hydrothermally treated nanocrystalline Mg/Al layered double hydroxide with nitrate intercalation Environmental Science & Technology 43 2537–2543 10.1021/es802811n.CrossRefGoogle ScholarPubMed
Justi, K.C. Fávere, V.T. Laranjeira, M.C.M. Neves, A. and Peralta, R.A., 2005 Kinetics and equilibrium adsorption of Cu(II), Cd(II), and Ni(II) ions by chitosan functionalized with 2[-bis-(pyridylmethyl)aminomethyl]-4-methyl-6-formylphenol Journal of Colloid and Interface Science 291 369–374 10.1016/j.jcis.2005.05.017.CrossRefGoogle Scholar
Nakayama, H. Hirami, S. and Tsuhako, M., 2007 Selective adsorption of mercury ions by mercaptocarboxylic acid intercalated Mg-Al layered double hydroxide Journal of Colloid and Interface Science 315 177–183 10.1016/j.jcis.2007.06.036.CrossRefGoogle ScholarPubMed
Netpradit, S. Thiravetyan, P. and Towprayoon, S., 2004 Adsorption of three azo reactive dyes by metal hydroxide sludge: effect of temperature, pH, and electrolytes Journal of Colloid and Interface Science 270 255–261 10.1016/j.jcis.2003.08.073.CrossRefGoogle ScholarPubMed
Noeline, B.F. Manohar, D.M. and Anirudhan, T.S., 2005 Kinetic and equilibrium modeling of lead (II) sorption from water and wastewater by polymerized banana stem in a batch reactor Separation and Purification Technology 45 131–140 10.1016/j.seppur.2005.03.004.CrossRefGoogle Scholar
Özacar, M. and Sengil, I.A., 2005 A kinetic study of metal complex dye sorption onto pine sawdust Process Biochemistry 40 565–572 10.1016/j.procbio.2004.01.032.CrossRefGoogle Scholar
Pearce, C.I. Lloyd, J.R. and Guthrie, J.T., 2003 The removal of colour from textile wastewater using whole bacterial cells: a review Dyes and Pigments 58 179–196 10.1016/S0143-7208(03)00064-0.CrossRefGoogle Scholar
Reinholdt, M.X. Babu, P.K. and Kirkpatrick, R.J., 2009 Preferential adsorption of lower-charge glutamate ions on layered double hydroxides: an NMR investigation The Journal of Physical Chemistry C 113 3378–3381 10.1021/jp8109786.CrossRefGoogle Scholar
Robinson, T. McMullan, G. Marchant, R. and Nigam, P., 2001 Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative Bioresource Technology 77 247–255 10.1016/S0960-8524(00)00080-8.CrossRefGoogle ScholarPubMed
Wang, S.-L. Liu, C.H. Wang, M.K. Chuang, Y.H. and Chiang, P.N., 2009 Applied Clay Science 43 79–85 10.1016/j.clay.2008.07.005.CrossRefGoogle Scholar
Weisburger, J.H., 2002 Comments on the history and importance of aromatic and heterocyclic amines in public health Mutation Research/Fundamental and Molecular Mechanisms of Mutagenesis 506–507 9–20 10.1016/S0027-5107(02)00147-1.CrossRefGoogle ScholarPubMed
Yang, L. Shahrivari, Z. Liu, P.K.T. Sahimi, M. and Tsotsis, T.T., 2005 Removal of trace levels of arsenic and selenium from aqueous solutions by calcined and uncalcined layered double hydroxides (LDH) Industrial & Engineering Chemistry Research 44 6804–6815 10.1021/ie049060u.CrossRefGoogle Scholar
Yong, Z. Mata, V. and Rodrigues, A.E., 2000 Adsorption of carbon dioxide onto hydrotalcite-like compounds (HTlcs) at high temperatures Industrial & Engineering Chemistry Research 40 204–209 10.1021/ie000238w.CrossRefGoogle Scholar
You, Y. Vance, G.F. and Zhao, H., 2001 Selenium adsorption on Mg-Al and Zn-Al layered double hydroxides Applied Clay Science 20 13–25 10.1016/S0169-1317(00)00043-0.CrossRefGoogle Scholar