Hostname: page-component-cd9895bd7-8ctnn Total loading time: 0 Render date: 2024-12-26T15:41:25.221Z Has data issue: false hasContentIssue false
  • English
  • Français

Structure and Properties of Hydrogenated Nitrile Rubber/Organo-Montmorillonite Nanocomposites

Published online by Cambridge University Press:  01 January 2024

Zheng Gu ,
Guojun Song ,
Weisheng Liu ,
Shujing Yang  and
Jianming Gao
Zheng Gu
Affiliation:
Department of Chemistry and State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China Institute of Polymer Materials, Qingdao University, Qingdao 266071, China
Guojun Song
Affiliation:
Institute of Polymer Materials, Qingdao University, Qingdao 266071, China
Weisheng Liu*
Affiliation:
Department of Chemistry and State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
Shujing Yang
Affiliation:
Institute of Polymer Materials, Qingdao University, Qingdao 266071, China
Jianming Gao
Affiliation:
Institute of Polymer Materials, Qingdao University, Qingdao 266071, China Qingdao TKS Sealing Industry Company, Qingdao 266071, China
*
* E-mail address of corresponding author: Liuws@lzu.edu.cn
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The aim of the work was to study the effect of organo-montmorillonite (OMt) on the properties of hydrogenated nitrile rubber (HNBR)/OMt nanocomposites. The nanocomposites were prepared by a melt intercalation method. The structure of the composites was studied by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The behavior of stress-strain, aging resistance, solvent resistance, and the dynamic mechanical properties of HNBR/OMt nanocomposites were investigated. The TEM and XRD results showed that the OMt layers were dispersed homogeneously in the HNBR matrix. The HNBR/OMt nanocomposites showed excellent mechanical properties which were attributed to the nanometer scale dispersion and strong interaction between the HNBR and OMt. The composites possessed excellent aging resistance and oil resistance, which improved with OMt content. Dynamic mechanical analysis showed that the glass-transition temperature, Tg, of the HNBR/OMt nanocomposites was increased and the nanocomposites had a good rolling resistance in comparison to pure HNBR. The composites displayed better dynamic mechanical properties.

Keywords

Dynamic Mechanical PropertiesHNBRHydrogenated Nitrile RubberOrgano-montmorilloniteOMtNanocompositesMechanical PropertiesOil Resistance
Type
Article
Information
Clays and Clay Minerals , Volume 58 , Issue 1 , February 2010 , pp. 72 - 78
Copyright
Copyright © Clay Minerals Society 2010

References

Galgali, G. Ramesh, C. and Lele, A., 2001 A rheological study on the kinetics of hybrid formation in polypropylene nanocomposites Macromolecules 34 852–858 10.1021/ma000565f.CrossRefGoogle Scholar
Galimberti, M. Senatore, S. tConzatti, L. Costa, G. Giuliano, G. and Guerra, G., 2008 Formation of clay intercalates with organic bilayers in hydrocarbon polymers Polymer for Advance Technologies 20 135–142 10.1002/pat.1287.CrossRefGoogle Scholar
Gao, J.M. Gu, Z. Song, G. Li, P. and Liu, W., 2008 Preparation and properties of organo-montmorillonite/fluoroelastomer nanocomposites Applied Clay Science 42 272–275 10.1016/j.clay.2008.01.007.CrossRefGoogle Scholar
Gatos, K.G. Százdi, L. Pukánsky, B. and Karger-Kocsis, J., 2005 Controlling the deintercalation in hydrogenated nitrile rubber (HNBR)/organo-montmorillonite nanocomposites by curing with peroxide Macromolecular Rapid Communication 26 915–919 10.1002/marc.200500084.CrossRefGoogle Scholar
Giannelis, E.P., 1996 Polymer layered silicate nanocomposites Advanced Materials 8 29–35 10.1002/adma.19960080104.CrossRefGoogle Scholar
Herrmann, W. Uhl, C. Heinrich, G. and Jehnichen, D., 2006 Analysis of HNBR-montmorillonite nanocomposites: morphology, orientation and macroscopic properties Polymer Bulletin 57 395–405 10.1007/s00289-006-0556-9.CrossRefGoogle Scholar
Karger-Kocsis, J. and Wu, C.M., 2004 Thermoset rubber/layered silicate nanocomposites Status and future trends. Polymer Engineering and Science 44 1083–1093.Google Scholar
Kojima, Y. Usuki, A. Kawasumi, M. Okada, A. Kurauchi, T. and Kamigaito, O., 1993 Sorption of water in nylon 6-clay hybrid Journal of Applied Polymer Science 49 1259–1264 10.1002/app.1993.070490715.CrossRefGoogle Scholar
Kong, Q.H. Ruibin, L.v. and Zhang, S., 2008 Flame retardant and the degradation mechanism of high impact polystyrene/Fe-montmorillonite nanocomposites Journal of Polymer Research 15 453–458 10.1007/s10965-008-9191-5.CrossRefGoogle Scholar
Liang, Z.M. Yin, J. and Xu, H.-J., 2003 Polyimide/montmorillonite nanocomposites based on thermally stable, rigid-rod aromatic amine modifiers Polymer 44 1391–1399 10.1016/S0032-3861(02)00911-4.CrossRefGoogle Scholar
Messersmith, P.B. and Giannelis, E.P., 1995 Synthesis and barrier properties of poly(-caprolactone)-layered silicate nanocomposites Journal of Polymer Science Part A: Polymer Chemistry 33 1047–1057 10.1002/pola.1995.080330707.CrossRefGoogle Scholar
Ray, S.S. and Okamoto, M., 2003 Polymer/layered silicate nanocomposites: a review from preparation to processing Progress Polymer Science 28 1539–1641 10.1016/j.progpolymsci.2003.08.002.Google Scholar
Sengupta, R. Chakraborty, S. Bandyopadhyay, S. Dasgupta, S. Mukhopadyhyay, R. Auddy, K. and Deuri, A.S., 2007 A short review on rubber/clay nanocomposites with emphasis on mechanical properties Polymer Engineering and Science 47 1956–1974 10.1002/pen.20921.CrossRefGoogle Scholar
Severe, G. and White, J.L., 2000 Physical properties and blend miscibility of hydrogenated acrylonitrile-butadiene rubber Journal of Applied Polymer Science 78 1521–1529 10.1002/1097-4628(20001121)78:8<1521::AID-APP90>3.0.CO;2-Z.3.0.CO;2-Z>CrossRefGoogle Scholar
Shi, X.D. and Gan, Z.H., 2008 Preparation and characterization of poly(propylene carbonate)/montmorillonite nanocomposites by solution intercalation European Polymer Journal 43 4852–4858 10.1016/j.eurpolymj.2007.09.024.CrossRefGoogle Scholar
Utracki, L.A. Sepehr, M. and Boccaleri, E., 2007 Synthetic, layered nanoparticles for polymeric nanocomposites (PNCs) Polymer for Advance Technologies 18 1–37 10.1002/pat.852.CrossRefGoogle Scholar
Wang, Y.Q. Zhang, H. Wu, Y. Yang, J. and Zhang, L., 2005 Preparation and properties of natural rubber/rectorite Nanocomposi tes European Polymer Journal 41 2776–2783 10.1016/j.eurpolymj.2005.05.019.CrossRefGoogle Scholar
Wang, X.P. Huang, A.-M. Jia, D.-M. and Li, Y.-M., 2008 From exfoliation to intercalation - changes in morphology of HNBR/organoclay nanocomposites European Polymer Journal 44 2784–2789 10.1016/j.eurpolymj.2008.06.035.CrossRefGoogle Scholar
Wu, Y.P. Wang, Y.-Q. Zhang, H.-F. Wang, Y.-Z. Yu, D.-S. Zhang, L.-Q. and Yang, J., 2005 Rubber - pristine clay nanocomposites prepared by co-coagulating rubber latex and clay aqueous suspension Composites and Science Technology 65 1195–1202 10.1016/j.compscitech.2004.11.016.CrossRefGoogle Scholar