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The Synthesis of a Platy Chabazite Analog From Delaminated Metakaolin with the Ability to Surface Template Nanosilver Particulates

Published online by Cambridge University Press:  01 January 2024

Steven M. Kuznicki*
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
Christopher C. H. Lin
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
Lan Wu
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
Haiyan Yin
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
Mohsen Danaie
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
David Mitlin
Affiliation:
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2V4
*
* E-mail address of corresponding author: steve.kuznicki@ualberta.ca
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Abstract

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Mineral chabazite has shown the unusual ability to surface template nanometal particles, especially Ag. A chabazite analog was synthesized from delaminated metakaolin. The chabazite formed retained the platy morphology of the base clay. This morphology is ideal for displaying surface-supported nanometal particles. The synthetic chabazite analog demonstrated the ability to form and support large concentrations of Ag nanoparticles, as observed in the related natural mineral. Due to greater Al content, the synthetic chabazite manifests significantly improved capacity for the formation of such Ag nanoparticles. As in the case of the mineral chabazite, surface Ag nanoparticles of high uniformity were observed in the range of 5–6 nm.

Type
Article
Copyright
Copyright © 2008, The Clay Minerals Society

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