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The trapping of B from water by exfoliated and functionalized vermiculite

Published online by Cambridge University Press:  01 January 2024

Mohamed Kehal ,
Laurence Reinert ,
David Maurin ,
Jean-Louis Bantignies ,
Fumihiko Ohashi ,
Ammar Mennour  and
Laurent Duclaux
Mohamed Kehal
Affiliation:
Laboratoire de Chimie Moléculaire et Environnement, Polytech’Savoie - Université de Savoie, 73376, Le Bourget du Lac Cedex, France Laboratoire Pollution et Traitement des Eaux, Département de Chimie, Université Mentouri, 25000, Constantine, Algeria
Laurence Reinert
Affiliation:
Laboratoire de Chimie Moléculaire et Environnement, Polytech’Savoie - Université de Savoie, 73376, Le Bourget du Lac Cedex, France
David Maurin
Affiliation:
Laboratoire des colloïdes verres et nanomatériaux (UMR CNRS 5587), Université Montpellier II, 34095, Montpellier Cedex 5, France
Jean-Louis Bantignies
Affiliation:
Laboratoire des colloïdes verres et nanomatériaux (UMR CNRS 5587), Université Montpellier II, 34095, Montpellier Cedex 5, France
Fumihiko Ohashi
Affiliation:
Materials Research Institute for Sustainable Development, National Institute of Advanced Industrial Science and Technology, Shimo-Shidami, Moriyama, Nagoya 463-8560, Japan
Ammar Mennour
Affiliation:
Laboratoire Pollution et Traitement des Eaux, Département de Chimie, Université Mentouri, 25000, Constantine, Algeria
Laurent Duclaux*
Affiliation:
Laboratoire de Chimie Moléculaire et Environnement, Polytech’Savoie - Université de Savoie, 73376, Le Bourget du Lac Cedex, France
*
* E-mail address of corresponding author: laurent.duclaux@univ-savoie.fr
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Abstract

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Micron-grade natural vermiculite was modified by several physical and chemical treatments in order to increase the adsorption capacity of this material for B. A thermal exfoliation (T = 600°C) of pristine material, a chemical exfoliation through reaction with hydrogen peroxide (H2O2 35%), or grafting of a specific B complexant (i.e. N-methyl-D-glucamine: NMDG) led to an increase in the uptake of B at low initial concentrations of the aqueous solutions ([B] ≈ 5 mg L−1). The more efficient material is the NMDG-grafted clay, for which the adsorption uptake is four times greater than that of raw vermiculite, and reaches 0.04 mmol g−1. For all modified materials, the effect of the pH on B adsorption and the adsorption kinetics were studied and compared to raw vermiculite. Adsorption isotherms were also plotted and fitted well with the Freundlich equation.

Keywords

AdsorptionGraftingN-methyl-D-glucamine
Type
Article
Information
Clays and Clay Minerals , Volume 56 , Issue 4 , August 2008 , pp. 453 - 460
Copyright
Copyright © 2008, The Clay Minerals Society

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