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Ultramafic-Rock-Hosted Vein Sepiolite Occurrences in the Ankara Ophiolitic Mélange, Central Anatolia, Turkey

Published online by Cambridge University Press:  01 January 2024

Hüseyin Yalçin*
Affiliation:
Cumhuriyet University, Department of Geological Engineering, TR-58140 Sivas, Turkey
Ömer Bozkaya
Affiliation:
Cumhuriyet University, Department of Geological Engineering, TR-58140 Sivas, Turkey
*
*E-mail address of corresponding author: yalcin@cumhuriyet.edu.tr
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Abstract

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A 2 m thick brecciated zone containing magnesian minerals is present at the contact of tectonites and cumulates. Tectonites below this zone comprise serpentinized orthopyroxenite and serpentinite. An alteration zone with vein-type bedding comprises four different levels; from bottom to top they are: (1) green-brown serpentinite with dolomite (0.9 m), (2) light greenish-white dolomite with serpentine (0.5 m), (3) white dolomite with sepiolite (0.4 m), and (4) greenish-white dolomite with smectite-chlorite (0.2 m). The first level has a mineral association of serpentine + dolomite ± calcite ± aragonite, the second level consists of dolomite + serpentine ± calcite or dolomite + magnesite + serpentine, the third level comprises dolomite + sepiolite, and the fourth level is made up of dolomite + chlorite + smectite + serpentine. Dolomite, the main mineral of the alteration zone, occurs as coarse crystals (microsparitic-sparitic) in fractures and as small crystals (microsparitic-micritic) in the matrix, which includes serpentine and gabbro relics. Sepiolite developed at the edges and surfaces of dolomite and as fibrous forms in voids. Cumulate rocks above this zone comprise uralitic gabbros. The occurrences of magnesian minerals developed in three stages: the first stage was the serpentinization of olivine; the second stage was the dissolution of serpentine by groundwater and/or meteoric water containing carbon dioxide; and the last stage was the synthesis of neoformed minerals.

Type
Research Article
Copyright
Copyright © 2004, The Clay Minerals Society

References

Abu-Jaber, N.S. and Kimberley, M.M., (1992) Origin of ultramafic-hosted vein magnesite deposits Ore Geology Reviews 7 155191 10.1016/0169-1368(92)90004-5.CrossRefGoogle Scholar
Bailey, E.B. and McCallien, W.J., (1950) The Ankara Melange and the Anatolian Thrust Nature 166 938 10.1038/166938a0 940.CrossRefGoogle Scholar
Bailey, S.W., (1988) X-ray diffraction identification of the polytypes of mica, serpentine, and chlorite Clays and Clay Minerals 36 193213 10.1346/CCMN.1988.0360301.CrossRefGoogle Scholar
Birsoy, R., (2002) Formation of sepiolite-palygorskite and related minerals from solution Clays and Clay Minerals 50 736745 10.1346/000986002762090263.CrossRefGoogle Scholar
Bonatti, E. Emiliani, C. Ferrara, G. Honnorez, J. and Rydell, H., (1974) Ultramafic carbonate breccias from the equatorial Mid-Atlantic Ridge Marine Geology 16 83102 10.1016/0025-3227(74)90057-7.CrossRefGoogle Scholar
Brindley, G.W., Brindley, G.W. and Brown, G., (1980) Quantitative X-ray mineral analysis of clays Crystal Structures of Clay Minerals and their X-ray Identification London Mineralogical Society 411438.CrossRefGoogle Scholar
Coleman, R.G., (1977) Ophiolites: Ancient Oceanic Lithosphere Berlin Springer-Verlag 10.1007/978-3-642-66673-5 229 pp.CrossRefGoogle Scholar
Coleman, R.G. Jove, C., Baker, A.J.M. Proctor, J. and Revees, R.D., (1992) Geological origin of serpentinites The Vegetation of Ultramafic (Serpentine) Soils Andover, United Kingdom Intercept Ltd. 117.Google Scholar
Capan, U. Lauer, J.P. and Whitechurch, H., (1983) The Ankara Melange (Central Anatolia): An important element for the reconstruction of Tethyan closure Bulletin of Earth Sciences Application and Research Centre of Hacettepe University of Ankara 10 3543 (in Turkish, with English abstract).Google Scholar
Çelik, M., (1989) Ankara doǵu kesiminin mineralojik — petrografik ve jeokimyasal özelliklerinin incelenmesi Turkey Hacettepe University Institute of Sciences PhD.Google Scholar
Ece, I., (1998) Diagenetic transformation of magnesite pebbles and cobbles to sepiolite (Meerschaum) in the Miocene Eskişehir lacustrine basin, Turkey Clays and Clay Minerals 46 436445 10.1346/CCMN.1998.0460408.CrossRefGoogle Scholar
Ece, I. and Çoban, F., (1994) Geology, occurrence, and genesis of Eskişehir sepiolite, Turkey Clays and Clay Minerals 42 8192 10.1346/CCMN.1994.0420111.CrossRefGoogle Scholar
Evans, B.W. Guggenheim, S. and Bailey, S.W., (1988) Talc, pyrophyllite, and related minerals Hydrous Phyllosilicates (Exlusive of Micas) Washington, D.C. Mineralogical Society of America 225294 10.1515/9781501508998-013.CrossRefGoogle Scholar
Flanagan, F.J. (1976) Descriptions and analyses of eight new USGS rock standards. Twenty-eight papers present analytical data on new and previously described whole rock standards (Flanagan, F.J., editor). United States Geological Survey, Professional Paper, 840, 171172.Google Scholar
Frost, R.L. and Ding, Z., (2003) Controlled rate thermal analysis and differential scanning calorimetry of sepiolites and palygorskites Thermochimica Acta 397 119128 10.1016/S0040-6031(02)00228-9.CrossRefGoogle Scholar
Galán, E. and Carretero, M.I., (1999) A new approach to compositional limits for sepiolite and palygorskite Clays and Clay Minerals 47 399409 10.1346/CCMN.1999.0470402.CrossRefGoogle Scholar
Govindaraju, K., (1989) 1989 compilation of working values and sample description for 272 geostandards Geostandards Newsletter 13 1113 10.1111/j.1751-908X.1989.tb00476.x.CrossRefGoogle Scholar
Jones, B.F. Galán, E. and Bailey, S.W., (1988) Palygorskite-Sepiolite Hydrous Phyllosilicates (Exlusive of Micas) Washington, D.C Mineralogical Society of America 631674 10.1515/9781501508998-021.CrossRefGoogle Scholar
Lambert, S.J. and Epstein, S., (1992) Stable-isotope studies of rocks and secondary minerals in a vapor-dominated hydrothermal system at The Geysers, Sonoma County, California Journal of Volcanology and Geothermal Research 53 199226 10.1016/0377-0273(92)90082-O.CrossRefGoogle Scholar
Mittwede, S.K. and O’Hanley, D.S., (1996) Serpentinite-related mineralization Serpentinites: Records of Tectonic and Petrological History Oxford, New York Oxford University Press 144148.Google Scholar
Moore, D.M. and Reynolds, R.C. Jr., (1997) X-ray Diffraction and the Identification and Analysis of Clay Minerals Oxford, UK Oxford University Press 378 pp.Google Scholar
O’Hanley, D.S., (1996) Serpentinites: Records of Tectonic and Petrological History Oxford, New York Oxford University Press 277 pp.Google Scholar
Peabody, C.E. and Einaudi, M.T., (1992) Origin of petroleum and mercury in the Culver-Baer cinnabar deposit, Mayacmas district, California Economic Geology 87 10781103 10.2113/gsecongeo.87.4.1078.CrossRefGoogle Scholar
Peters, E.K., (1993) D-18O enriched waters of the Coast Range mountains, northern California: connate and ore-forming fluids Geochimica et Cosmochimica Acta 57 10931104 10.1016/0016-7037(93)90043-V.CrossRefGoogle Scholar
Sakai, R. Kusakabe, M. Noto, M. and Ishii, T., (1991) Origin of waters responsible for serpentinization of the Izu-Ogawawara-Mariana forearc seamounts in view of hydrogene and oxygen isotope ratios Earth and Planetary Science Letters 100 291303 10.1016/0012-821X(90)90192-Z.CrossRefGoogle Scholar
Schandl, E.S. and Wicks, F.J., (1993) Carbonates and associated alteration of ultramafic and rhyolitic rocks at the Hemingwat property, Kidd Creek volcanic complex, Timmins, Ontario Economic Geology 88 16151635 10.2113/gsecongeo.88.6.1615.CrossRefGoogle Scholar
Şengör, A.M.C. and Yılmaz, Y., (1981) Tethyan evolution of Turkey: a plate tectonic approach Tectonophysics 75 181241 10.1016/0040-1951(81)90275-4.CrossRefGoogle Scholar
Şengör, A.M.C., (1979) The North Anatolian fault: its age, offset, and tectonic significance Journal of the Geological Society, London 136 268282 10.1144/gsjgs.136.3.0269.CrossRefGoogle Scholar
Singer, A. and Galán, E., (1984) Palygorskite-Sepiolite: Occurrences, Genesis and Uses Amsterdam Elsevier 352 pp.Google Scholar
Taylor, S.R. and McLennan, S.M., (1985) The Continental Crust: Its Composition and Evolution Oxford, UK Blackwell 312 pp.Google Scholar
Weaver, C.E. and Pollard, L.D., (1973) The Chemistry of Clay Minerals Amsterdam Elsevier 213 pp.Google Scholar
Wicks, F.J. O’Hanley, D.S. and Bailey, S.W., (1988) Serpentine minerals: structures and petrology Hydrous Phyllosilicates (Exlusive of Micas) Washington, D.C Mineralogical Society of America 91167 10.1515/9781501508998-010.CrossRefGoogle Scholar
Wicks, F.J. and Plant, G., (1979) Electron microprobe and X-ray microbeam studies of serpentine textures The Canadian Mineralogist 17 785830.Google Scholar
Wicks, F.J. and Whittaker, E.J.W., (1977) Serpentine textures and serpentinization The Canadian Mineralogist 15 459488.Google Scholar
Yalçın, H. Bozkaya, , Şener, M. Öner, F. and Koşun, E., (1995) Mineralogy and geochemistry of lacustrine palygorskites from Kangal-Çetinkaya sub-basin (Sivas basin), Central Eastern Anatolia, Turkey Proceedings of VIIth Turkish National Clay Symposium Ankara MTA 105116 (in Turkish, with English abstract).Google Scholar
Yalçın, H. and Bozkaya, , (1995) Sepiolite-palygorskite from the Hekimhan region (Turkey) Clays and Clay Minerals 43 705717 10.1346/CCMN.1995.0430607.CrossRefGoogle Scholar
Yeniyol, M., (1986) Vein-like sepiolite occurrence as a replacement of magnesite in Konya, Turkey Clays and Clay Minerals 34 353356 10.1346/CCMN.1986.0340317.CrossRefGoogle Scholar
Yeniyol, M., (1992) Yenidoǵan (Sivrihisar) sepiolit yataǵının jeolojisi, mineralojisi ve oluşumu Maden Tetkik ve Arama Dergisi 114 7184 (in Turkish).Google Scholar
Yeniyol, M., (1993) Sivrihisar’da (Eskişehir) sedimanter-diyajenetik oluşÞumlu yeni bir lületaşı türü Maden Tetkik ve Arama Dergisi 115 8190 (in Turkish).Google Scholar
Yılmaz, Y. Tüysüz, O. Yigitbas, E. Genc, C. Şengör, A.M.C. and Robinson, A.G., (1997) Geology and tectonic evolution of the Pontides Regional and Petroleum Geology of the Black Sea and Surrounding Region Oklahoma Tulsa 183226.Google Scholar