Hostname: page-component-78c5997874-fbnjt Total loading time: 0 Render date: 2024-11-10T07:46:40.861Z Has data issue: false hasContentIssue false

Vermicular Kaolinite Epitactic on Primary Phyllosilicates in the Weathering Profiles of Anorthosite

Published online by Cambridge University Press:  28 February 2024

Gi Young Jeong*
Affiliation:
Department of Earth and Environmental Sciences, Andong National University, Andong 760-749, Korea
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The microtextural changes in the kaolinization of primary phyllosilicates including biotite, sericite, clinochlore and muscovite were investigated by scanning electron microscopy (SEM) and microchemical analysis of thin sections of weathered anorthosite. Kaolinization began at grain edges and propagated toward the interior. Grains were highly fanned out from the edges and exfoliated into several flakes along the basal cleavages, producing lenticular voids. Finally, long vermicular kaolinite pseudomorphs were formed after primary phyllosilicates. Statistical analysis showed a ninefold increase in volume during the kaolinization of biotite, suggesting that most AI in the kaolinite was imported from ambient weathering solution. Weathering primary phyllosilicates supplied templates suitable for the thick epitactic overgrowth of kaolinite to form long vermicular pseudomorphs. AI was sufficiently available due to the intense weathering of soluble anorthosite. Although present in small amounts, primary phyllosilicates gave high volumetric and mineralogical contributions to the weathering profiles by facilitating kaolinite precipitation.

Type
Research Article
Copyright
Copyright © 1998, The Clay Minerals Society

References

Ahn, J.H. and Peacor, D.R., 1987 Kaolinitization of biotite: TEM data and implications for an alteration mechanism Am Minerai 72 353356.Google Scholar
Bailey, S.W., Brindley, G.W. and Goodman, G., 1980 Structure of layer silicates Crystal structures of clay minerals and their X-ray identification London Mineral Soc. 1124.Google Scholar
Banfield, J.F. and Eggleton, R.A., 1988 Transmission electron microscope study of biotite weathering Clays Clay Miner 36 4760 10.1346/CCMN.1988.0360107.CrossRefGoogle Scholar
Banfield, J.F. and Eggleton, R.A., 1990 Analytical transmission electron microscope studies of plagioclase, muscovite, and K-feldspar weathering Clays Clay Miner 38 7789 10.1346/CCMN.1990.0380111.CrossRefGoogle Scholar
Banfield, J.F. Veblen, D.R. and Jones, B.F., 1990 Transmission electron microscopy of subsolidus oxidation and weathering of olivine Contrib Mineral Petrol 106 110123 10.1007/BF00306412.CrossRefGoogle Scholar
Brindley, G.W., Brindley, G.W. and Brown, G., 1980 Order-disorder in clay mineral structures Crystal structures of clay minerals and their X-ray identification London Mineral Soc 125195.CrossRefGoogle Scholar
Cho, H.D. and Mermut, A.R., 1992 Evidence of halloysite formation from weathering of ferruginous chlorite Clays Clay Miner 40 608619 10.1346/CCMN.1992.0400516.Google Scholar
Churchman, G.J. Whitton, J.S. Claridge, G.G.C. and Theng, B.K.G., 1984 Intercalation method using formamide for differentiating halloysite from kaolinite Clays Clay Miner 32 241248 10.1346/CCMN.1984.0320401.CrossRefGoogle Scholar
Coffman, C.B. and Fanning, D.S., 1975 Maryland soils developed in residuum from chlorite metabasalt having high amounts of vermiculite in sand and silt fractions Soil Sci Soc Am J 39 723732 10.2136/sssaj1975.03615995003900040038x.CrossRefGoogle Scholar
Eswaran, H. and Bin, W.C., 1978 A study of a deep weathering profile on granite in Peninsular Malaysia: III. Alteration of feldspars Soil Sci Soc Am J 42 154158 10.2136/sssaj1978.03615995004200010034x.CrossRefGoogle Scholar
Fordham, A.W., 1990 Formation of trioctahedral illite from biotite in a soil profile over granite gneiss Clays Clay Miner 38 187195 10.1346/CCMN.1990.0380210.CrossRefGoogle Scholar
Gilkes, R.J. and Suddhiprakam, A., 1979 Biotite in deeply weathered granite. I. Morphologic, mineralogical, and chemical properties Clays Clay Miner 27 349360 10.1346/CCMN.1979.0270505.CrossRefGoogle Scholar
Gilkes, R.J. and Suddhiprakam, A., 1979 Biotite in deeply weathered granite. II. The oriented growth of secondary minerals Clays Clay Miner 27 361367 10.1346/CCMN.1979.0270506.CrossRefGoogle Scholar
Harris, W.G. Zelazny, J.C. Baker, J.C. and Martens, D.C., 1985 Biotite kaolinitization in Virginia Piedmont soils: I. Extent, profile trends, and grain morphological effects Soil Sci Soc Am J 49 12901297 10.2136/sssaj1985.03615995004900050044x.CrossRefGoogle Scholar
Harris, W.G. Zelazny, J.C. and Bloss, F.D., 1985 Biotite kaolinitization in Virginia Piedmont soils: II. Zonation in single grains Soil Sci Soc Am J 49 12971302 10.2136/sssaj1985.03615995004900050045x.CrossRefGoogle Scholar
Jeong, G.Y., 1992 Mineralogy and genesis of kaolin in the Sancheong district, Korea Seoul, Korea Seoul National Univ..Google Scholar
Jeong, G.Y. Kim, S.J. and Nagasawa, K., 1992 Kaolinites in the Sancheong kaolin, Korea: Their textures, chemistry, and origin Clay minerals, their natural resources and uses Japan Nagoya 129135.Google Scholar
Jeong, G.Y. and Kim, S.J., 1993 Boxwork fabric of halloysite-rich kaolin formed by weathering of anorthosite in Sancheong area, Korea Clays Clay Miner 41 5665 10.1346/CCMN.1993.0410106.CrossRefGoogle Scholar
Jepson, W.B. and Rouse, J.B., 1975 The composition of kaolinite—An electron microscope microprobe study Clays Clay Miner 23 310317 10.1346/CCMN.1975.0230407.CrossRefGoogle Scholar
Jiang, W.T. and Peacor, D.R., 1991 Transmission electron microscopic study of the kaolinitization of muscovite Clays Clay Miner 39 113 10.1346/CCMN.1991.0390101.CrossRefGoogle Scholar
Keller, W.D., 1977 Scan electron micrographs of kaolins collected from diverse environments of origin. IV. Georgia kaolin and kaolinizing source rocks Clays Clay Miner 25 311345 10.1346/CCMN.1977.0250501.CrossRefGoogle Scholar
Konta, J. 1972. Secondary illite and primary muscovite in kaolins from Karlovy Vary area, Czechoslovakia. In: Serratosa, J.M., editor. Proc Int Clay Conf; 1972; Madrid, Spain. Madrid: Div Ciencias, CSIC. p 143157.Google Scholar
Korea Meteorological Service., 1985 Climatic summary of Korea Korea Meteorological Service Seoul, Korea 220.Google Scholar
Kwon, S.T. and Jeong, J.G., 1990 Preliminary Sr-Nd isotope study of the Hadong-Sanchung anorthositic rocks in Korea: Implication for their origin and for the Precambrian tectonics J Geol Soc Korea 26 341349.Google Scholar
Lee, S.Y. Jackson, M.L. and Brown, J.L., 1975 Micaceous inclusions in kaolinite observed by ultramicrotomy and high resolution electron microscopy Clays Clay Miner 23 125129 10.1346/CCMN.1975.0230208.CrossRefGoogle Scholar
Murray, H.H. and Bailey, S.W., 1988 Kaolin minerals: Their genesis and occurrences Hydrous phyllosilicates Washington Mineral Soc Am. 6789 10.1515/9781501508998-009.CrossRefGoogle Scholar
Nahon, D.B., 1991 Introduction to the petrology of soils and chemical weathering New York J. Wiley.Google Scholar
Pevear, D.R. and Nagy, K.L., 1993 Kaolinite growth on mica in sandstones, bentonites, and experiments .Google Scholar
Rebertus, R.A. Weed, S.B. and Buol, S.W., 1986 Transformation of biotite to kaolinite during saprolite—Soil weathering Soil Sci Soc Am J 50 810819 10.2136/sssaj1986.03615995005000030049x.CrossRefGoogle Scholar
Reynolds, R.C. Jr., 1985 NEWMOD©—A computer program for the calculation of one-dimensional diffraction patterns of mixed-layered clays R. C. Reynolds, Jr. Hanover, New Hampshire.Google Scholar
Robertson, I.D.M. and Eggleton, R.A., 1991 Weathering of granitic muscovite to kaolinite and halloysite and of plagioclasederived kaolinite to halloysite Clays Clay Miner 39 113126 10.1346/CCMN.1991.0390201.CrossRefGoogle Scholar
Samotoin, N.D. and Chekin, S.S., 1993 Helical growth of kaolinite crystal in layer silicates 143.Google Scholar
Singh, B. and Gilkes, R.J., 1991 Weathering of a chromian muscovite to kaolinite Clays Clay Miner 39 571579 10.1346/CCMN.1991.0390602.CrossRefGoogle Scholar
Stoch, L. and Sikora, W., 1976 Transformations of micas in the process of kaolinitization of granites and gneisses Clays Clay Miner 24 156162 10.1346/CCMN.1976.0240402.CrossRefGoogle Scholar
Velbel, M.A., 1989 Weathering of hornblende to ferruginous products by a dissolution-precipitation mechanism: Petrography and stoichiometry Clays Clay Miner 37 515524 10.1346/CCMN.1989.0370603.CrossRefGoogle Scholar
Weaver, C.E. and Pollard, L.D., 1973 The chemistry of clay minerals Amsterdam, Netherlands Elsevier.Google Scholar