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X-Ray Diffraction Intensity Ratios I(111)/I(3¯11) of Natural Heulandites and Clinoptilolites

Published online by Cambridge University Press:  28 February 2024

Fahri Esenli  and
Isik Kumbasar
Fahri Esenli
Affiliation:
Istanbul Technical University, Department of Geology, Maslak, 80626, Istanbul, Turkey
Isik Kumbasar
Affiliation:
Istanbul Technical University, Department of Geology, Maslak, 80626, Istanbul, Turkey
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Abstract

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Heulandite-group zeolites are abundant in the Miocene pyroclastics from Western Anatolia, Turkey. We investigated the relation between the I(111)/I(3¯11) intensity ratios measured by X-ray diffraction (XRD) and the content of exchangeable cations for 15 samples of natural heulandite-group minerals gathered from the Gördes and Bigadiç regions of Western Anatolia. The intensity ratios range from 0.77 to 0.94 in natural heulandites and from 1.38 to 1.80 in natural clinoptilolites. The data obtained from Na-, K- and Ca-exchanged forms of a heulandite and clinoptilolite show that the intensity ratio increases with Na-, K- and Ca-exchange in heulandite and also with Na- and K-exchange in clinoptilolite, whereas it decreases with Ca-exchange in clinoptilolite. The intensity ratios were calculated using the known structural data of clinoptilolites to understand the effect of positions, amounts and kinds of exchangeable cations and water molecules. An increase in Na and Ca may increase or decrease the intensity ratio, depending on their sites and occupancies. Potassium causes a significant increase in the intensity ratio and an increase in Mg decreases the intensity ratio. There is a strong correlation between the intensity ratio I(111)/I(3¯11) and (Na + K)/(Ca + Mg) ratio and thermal stability, both of which have been used to characterize heulandite-group minerals.

Keywords

ClinoptiloliteHeulanditeNatural ZeolitesTurkeyX-Ray Diffraction
Type
Research Article
Information
Clays and Clay Minerals , Volume 46 , Issue 6 , December 1998 , pp. 679 - 686
Copyright
Copyright © 1998, The Clay Minerals Society

References

Alberti, A. and Vezzalini, G., 1983 The thermal behaviour of heu-landites: Structural study of the dehydration of Nadap heu-landite Tscherm Miner Petr Mitt 31 259–270 10.1007/BF01081372.CrossRefGoogle Scholar
Alietti, A., 1972 Polymorphism and crystal-chemistry of heu-landites and clinoptilolites Am Mineral 57 1448–1462.Google Scholar
Alietti, A. Brigatti, M.F. and Poppi, L., 1977 Natural Ca-rich clinoptilolites (heulandites of group 3): New data and review Neues Jahrb Miner Monatsh 1977 493–501.Google Scholar
Alietti, A. Gottardi, G. and Poppi, L., 1974 The heat behaviour of the cation exchanged zeolites with heulandite structure Tscherm Miner Petr Mitt 21 291–298 10.1007/BF01081037.CrossRefGoogle Scholar
Ames, L.L. Sand, J.R. and Goldich, S.S., 1958 A contribution on the Hector, California bentonite deposit Econ Geol 53 22–37 10.2113/gsecongeo.53.1.22.CrossRefGoogle Scholar
Armbmster, T.h., 1993 Dehydration mechanism of clinoptil-olite and heulandite: Single-crystal X-ray study of Na-poor, Ca-, K-, Mg-rich clinoptilolite at 100 K Am Mineral 78 260–264.Google Scholar
Armbruster, T. and Gunter, M.E., 1991 Stepwise dehydration of a heulandite-clinoptilolite from Succor Creek, Oregon, USA: A single crystal X-ray study at 100 K Am Mineral 76 1872–1883.Google Scholar
Baysal, O. Giindogdu, N. Temei, A. and Öner, F., 1986 Geological investigation of the zeolite occurences in Bigadiç. Hacet-tepe Univ Project Report: YUVAM.85-2 .Google Scholar
Bish, D.L., 1984 Effects of exchangeable cation composition on the thermal expansion/contraction of clinoptilolite Clays Clay Miner 32 444–452 10.1346/CCMN.1984.0320602.CrossRefGoogle Scholar
Boles, J.R., 1972 Composition, optical properties, cell dimensions and thermal stability of some heulandite group zeolites Am Mineral 57 1463–1493.Google Scholar
Brown, G. Catt, J.A. and Weir, A.H., 1969 Zeolites of the clinoptil-olite-heulandite type in sediments of south-east England Mineral Mag 37 480–488 10.1180/minmag.1969.037.288.08.CrossRefGoogle Scholar
Coombs, D.S., 1958 Zeolitized tuffs from the Kuttung glacial beds near Seaham, New South Wales Australian J Sci 21 18–19.Google Scholar
Downs, R.T. Bartelmehs, K.L. Gibbs, G.V. and Boisen, M.B. Jr., 1993 Interactive software for calculating and displaying x-ray or neutron diffraction patterns of crystalline materials Am Mineral 78 1104–1107.Google Scholar
Esenli, F. Kumbasar, I., Weitkamp, J. Karge, H.G. Pfeifer, H. and Hölderich, W., 1994 Thermal behaviour of heulandites and clinoptilolites of Western Anatolia Proc Int Zeolite Conf; 1994; Partenkirschen, Germany Amsterdam Elsevier Sci 645–651.Google Scholar
Esenli, F. Özpeker, I., Ercan, T. and Örçen, S., 1993 Zeolitic diagenesis of Neogene basin and the mineralogy of heulandites clinoptilolites in Gördes around Bull Geol Congress Turkey; 1993; Ankara, Turkey 1–18.Google Scholar
Flanigen, E.M. and Mumpton, F.A., 1981 Crystal structure and chemistry of natural zeolites Rev Mineral 4, Mineralogy and geology of natural zeolites Michigan Mineral Soc Am 19–51.Google Scholar
Galabova, I.M., 1979 Relationship between new structural data on clinoptilolite and its behavior in ion-exchange and heating Zeit Naturforsch 34a 248–250.CrossRefGoogle Scholar
Galli, E. Gottardi, G. Mayer, H. Preisinger, A. and Passaglia, E., 1983 The structure of a potassium-exchanged heulandite at 293, 373 and 593 K Acta Crystallogr B 39 189–197 10.1107/S010876818300227X.CrossRefGoogle Scholar
Göktekin, A., 1989 Investigation of the technological properties of Bigadiç zeolites. Istanbul Technical Univ Project Report: UYG-AR. 89 .Google Scholar
Gottardi, G. and Galli, E., 1985 Natural zeolites Berlin Springer-Verlag 10.1007/978-3-642-46518-5.CrossRefGoogle Scholar
Gunter, M.E. Armbruster, T. Kohler, T. and Knowles, C.R., 1994 Crystal structure and optical properties of Na and Pb-ex-changed heulandite-group zeolites Am Mineral 79 675–682.Google Scholar
Hay, R.L. and Mumpton, F.A., 1981 Geology of zeolites in sedimentary rocks Rev Mineral 4, Mineralogy and geology of natural zeolites Michigan Mineral Soc Am 53–64.Google Scholar
Koyama, K. and Takeuchi, Y., 1977 Clinoptilolite: The distribution of potassium atoms and its role in thermal stability Z Kris-tallogr 145 216–239.Google Scholar
Mason, B. and Sand, L.B., 1960 Clinoptilolite from Patagonia, the relationship between clinoptilolite and heulandite Am Mineral 45 341–350.Google Scholar
Merkle, A.B. and Slaughter, M., 1968 Determination and refinement of the structure of heulandite Am Mineral 53 1120–1138.Google Scholar
Minato, H. and Takano, Y., 1964 An occurrence of potassium-cli-noptilolite from Itaya, Yamagata J Clay Sci Soc Jpn 4 12–22.Google Scholar
Mumpton, F.A., 1960 Clinoptilolite redefined Am Mineral 145 351–369.Google Scholar
Mumpton, F.A. and Mumpton, F.A., 1981 Utilization of natural zeolites Rev Mineral 4, Mineralogy and geology of natural zeolites Michigan Mineral Soc Am 177–204.Google Scholar
Shepard, A.O. and Starkey, H.C., 1966 The effect of exchanged cations and the thermal behaviour of heulandite and clinoptilolite Miner Soc India. IMA Vol 155–158.Google Scholar
Sirkecioğlu, A. Esenli, F. Kumbasar, I. Eren, R.H. Erdem-Şen-atalar, A., Savaşcin, M.Y. and Eronat, A.H., 1990 Mineralogical and chemical properties of Bigadiç clinoptilolite Proc Int Earth Sci Congress on Aegean Regions; 1990; İzmir, Turkey. İzmir: IESCA Pub 291–301.Google Scholar
Smyth, J.R. Spaid, A.T. and Bish, D.L., 1990 Crystal structures of a natural and a Cs-exchanged clinoptilolite Am Mineral 75 522–528.Google Scholar
Utada, M., 1971 Zeolitic zoning of the neogene pyroclastic rocks in Japan Sci Pap Coll Gen Educ Univ Tokyo 21 189–221.Google Scholar
Wise, W.S. Nokleberg, W.J. and Kokinos, M., 1969 Clinoptilolite and ferrierite from Agoura Am Mineral 54 887–895.Google Scholar