Hostname: page-component-78c5997874-xbtfd Total loading time: 0 Render date: 2024-11-10T11:30:06.215Z Has data issue: false hasContentIssue false

Susceptibility to weathering of some Scottish rocks and their derived soils

Published online by Cambridge University Press:  03 November 2011

B. F. L. Smith
Affiliation:
The Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen AB9 2QJ, Scotland.
B. D. Mitchell
Affiliation:
The Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen AB9 2QJ, Scotland.
R. C. MacKenzie
Affiliation:
The Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen AB9 2QJ, Scotland.

Abstract

The susceptibility of rocks to weathering into soils and the subsequent weathering of the solum itself are important both with respect to sediment formation and to agriculture. Residual soils developed on some rock types representative of the major soil associations of NE Scotland have consequently been examined in detail in an attempt to assess the weatherability of both the rocks and the derived soils. Methods based on chemical composition have been supplemented by potential methods related to the production of poorly-ordered aluminosilicate material and to depolymerisation of the silicate framework in the minerals present. In general, there is, as would be expected on the basis of increasing energy supply and increasing entropy, an increase in the amount of monomeric silica towards the surface and this appears to be closely related to the amount and nature of the poorly-ordered aluminosilicate. The results suggest that only the purely chemical methods can currently enable a reasonable assessment to be made of the susceptibility of a rock or soil to further weathering.

Type
Research Article
Copyright
Copyright © Royal Society of Edinburgh 1983

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

8. References

Bracewell, J. M., Campbell, A. S. & Mitchell, B. D. 1970. An assessment of some thermal and chemical techniques used in the study of poorly ordered aluminosilicates in soil calys. CLAY MINER 8, 325–35.CrossRefGoogle Scholar
Chesworth, W. 1973. The parent rock effect in the genesis of soil. GEODERMA 10, 215–25.CrossRefGoogle Scholar
Farmer, V. C., Russell, J. D. & Berrow, M. L. 1980. Imogolite and proto-imogolite allophane in spodic horizons: evidence for a mobile aluminium silicate complex in podzol formation. J SOIL SCI 31, 673–84.CrossRefGoogle Scholar
Fieldes, M. & Swindale, L. D. 1954. Chemical weathering in soil formation. N Z J SCI TECHNOL 368, 140–54.Google Scholar
Fisher, R. A. 1954. Statistical Methods for Research Workers. Edinburgh: Oliver & Boyd.Google Scholar
Foliett, E. A. C., McHardy, W. J., Mitchell, B. D. & Smith, B. F. L. 1965. Chemical dissolution techniques in the study of soil clays. CLAY MINER 6, 2334.CrossRefGoogle Scholar
Futty, D. W. & Dry, F. T. 1977. The Soils of the Country round Wick. MEM SOIL SURV G B SCOTLAND. Aberdeen: Macaulay Institute for Soil Research.Google Scholar
Glentworth, R. 1954. The Soils of the Country round Banff, Huntly and Turriff. MEM SOIL SURV G B SCOTLAND. Edinburgh: HMSO.Google Scholar
Glossary of Soil Science Terms 1979. Wisconsin: Soil Science Society of America.Google Scholar
Götz, J. & Masson, C. R. 1970. Trimethylsilyl derivatives for the study of silicate structures. Part I: A direct method of trimethylsilylation. J CHEM SOC (A), 2683–6.CrossRefGoogle Scholar
Götz, J. & Masson, C. R. 1971. Trimethylsilyl derivatives for the study of silicate structures. Part 2: Orthosilicates, pyrosilicates and ring structures. J CHEM SOC (A) 686–8.CrossRefGoogle Scholar
Greenland, D. J. & Hayes, M. H. B. 1978. The Chemistry of Soil Constituents. New York: Wiley.Google Scholar
Heslop, R. E. F. & Bown, C. J. 1969. The Soils of Candacraig and Glenbuchat. BULL SOIL SURV SCOTLAND No. 1. Aberdeen: Macaulay Institute for Soil Research.Google Scholar
Ingamells, C. O. 1966. Absorptiometric methods in rapid silicate analysis. ANAL CHEM 38, 1228–34.CrossRefGoogle Scholar
Jackson, M. L. 1968. Weathering of primary and secondary minerals in soils. TRANS 9TH INT CONGR SOIL SCI ADELAIDE 4, 281–92.Google Scholar
Kirkman, J. H., Mitchell, B. D. & Mackenzie, R. C. 1967. Distribution in some Scottish soils of an inorganic gel system related to “Allophane”. TRANS R SOC EDINBURGH 66, 393418.Google Scholar
Lentz, C. W. 1964. Silicate minerals as source of trimethylsilyl silicates and silicate structure analysis of sodium silicate solutions. INORG CHEM 3, 574–9.CrossRefGoogle Scholar
Lentz, C. W. 1966. The silicate structure analysis of hydrated portland cement paste. SPEC REP HIGHW RES BOARD 90, 269–83.Google Scholar
Loughnan, F. C. 1969. Chemical Weathering of the Silicate Minerals. New York: Elsevier.Google Scholar
McHardy, W. J. 1971. Imogolite. In Gard, J. A. (ed.) The Electron-optical Investigation of Clays, 359–64. London: Mineralogical Society.CrossRefGoogle Scholar
Merrill, G. P. 1906. Rocks, Rock-weathering and Soils. London: MacMillan.Google Scholar
Mitchell, B. D., Bracewell, J. M., de Endredy, A. S., McHardy, W. J. & Smith, B. F. L. 1968. Mineralogical and chemical characteristics of a gley soil from NE Scotland. TRANS 9TH INT CONGR SOIL SCI ADELAIDE 3, 6777.Google Scholar
Mitchell, B. D. & Mackenzie, R. C. 1959. An apparatus for differential thermal analysis under controlled atmosphere conditions. CLAY MINER BULL 4, 3143.CrossRefGoogle Scholar
Mitchell, B. D., Smith, B. F. L. & de Endredy, A. S. 1971. The effect of buffered sodium dithionite solution and ultrasonic agitation on soil clays. ISR J CHEM 9, 4552.CrossRefGoogle Scholar
Muir, A. & Fraser, G. K. 1940. The soils and vegetation of the Bin and Clashindaroch forest. TRANS R SOC EDINBURGH 60, 233341.CrossRefGoogle Scholar
Murata, K. J. 1943. Internal structure of silicate minerals that gelatinise with acid. AM MINERAL 28, 545–62.Google Scholar
Nicholls, G. D. 1963. Environment studies in sedimentary geochemistry. SCI PROG 51, 1231.Google Scholar
Parker, A. 1970. An index of weathering for silicate rocks. GEOL MAG 107, 501–4.CrossRefGoogle Scholar
Perrott, K. W., Smith, B. F. L. & Inkson, R. E. 1976. The reaction of fluoride with soils and soil minerals. J SOIL SCI 27, 5867.CrossRefGoogle Scholar
Ragg, J. M., Bracewell, J. M., Logan, J. & Robertson, L. 1978. Some characteristics of brown forest soils of Scotland. J SOIL SCI 29, 228–42.CrossRefGoogle Scholar
Robinson, G. W. 1932. Soils: their Origin, Constitution and Classification. London: Murby.Google Scholar
Smith, B. F. L., Paterson, E. & Mitchell, B. D. 1982. Trimethylsilylation of commonly occurring primary and secondary minerals in soils. J SOIL SCI 33, 115–24.CrossRefGoogle Scholar
Tavernier, R. & Eswaran, H. 1972. Basic concepts of weathering and soil genesis in the humid tropics. PROC 2ND ASEAN SOIL CONF, JAKARTA, INDONESIA 1, 383–92.Google Scholar
Weatherburn, C. E. 1947. A First Course in Mathematical Statistics. London: Cambridge University Press.Google Scholar
Yoshinaga, N. & Aomine, S. 1962. Imogolite in some ando soils. SOIL PLANT FOOD 8, 22–9.CrossRefGoogle Scholar