Hostname: page-component-78c5997874-mlc7c Total loading time: 0 Render date: 2024-11-10T06:44:50.963Z Has data issue: false hasContentIssue false

On identifying the appropriate boundary conditions at a moving contact line: an experimental investigation

Published online by Cambridge University Press:  26 April 2006

E. B. Dussan V.
Affiliation:
Schlumberger-Doll Research, Old Quarry Road, Ridgefield, CT 06877--4108, USA
Enrique Ramé
Affiliation:
General Electric Company, Corporate Research and Development, Schenectady, NY 12301, USA
Stephen Garoff
Affiliation:
Department of Physics, Carnegie-Mellon University, Pittsburgh, PA 15213, USA

Abstract

Over the past decade and a half, analyses of the dynamics of fluids containing moving contact lines have specified hydrodynamic models of the fluids in a rather small region surrounding the contact lines (referred to as the inner region) which necessarily differ from the usual model. If this were not done, a singularity would have arisen, making it impossible to satisfy the contact-angle boundary condition, a condition that can be important for determining the shape of the fluid interface of the entire body of fluid (the outer region). Unfortunately, the nature of the fluids within the inner region under dynamic conditions has not received appreciable experimental attention. Consequently, the validity of these novel models has yet to be tested.

The objective of this experimental investigation is to determine the validity of the expression appearing in the literature for the slope of the fluid interface in the region of overlap between the inner and outer regions, for small capillary number. This in part involves the experimental determination of a constant traditionally evaluated by matching the solutions in the inner and outer regions. Establishing the correctness of this expression would justify its use as a boundary condition for the shape of the fluid interface in the outer region, thus eliminating the need to analyse the dynamics of the fluid in the inner region.

Our experiments consisted of immersing a glass tube, tilted at an angle to the horizontal, at a constant speed, into a bath of silicone oil. The slope of the air–silicone oil interface was measured at distances from the contact line ranging between O.O13a. and O.17a, where a denotes the capillary length, the lengthscale of the outer region (1511 μm). Experiments were performed at speeds corresponding to capillary numbers ranging between 2.8 × 10-4 and 8.3 × 10-3. Good agreement is achieved between theory and experiment, with a systematic deviation appearing only at the highest speed. The latter may be a consequence of the inadequacy of the theory at that value of the capillary number.

Type
Research Article
Copyright
© 1991 Cambridge University Press

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Boender, W. & Chesters, A. K. 1986 The hydrodynamics of moving contact lines: an analytic approximation for the advancing liquid-gas case, private communications.
Cox, R. G. 1986 The dynamics of the spreading of a liquid on a solid surface. J. Fluid Mech. 168, 169.Google Scholar
Durbin, P. A. 1988 Considerations on the moving contact-line singularity, with application to frictional drag on a slender drop. J. Fluid Mech. 197, 157.Google Scholar
DussanV., E. B. 1976 The moving contact line: the slip boundary condition. J. Fluid Mech. 77, 665.Google Scholar
Goldstein, S. 1938 Modern Developments in Fluid Dynamics, pp. 67680. Oxford University Press.
Halst, H. van Dee 1979 Light Scattering by Small Particles. University Microfilms International, Ann Arbor.
Hocking, L. M. 1976 A moving fluid interface on a rough surface. J. Fluid Mech. 76, 801.Google Scholar
Hocking, L. M. & Rivers, A. D. 1982 The spreading of a drop by capillary action. J. Fluid Mech. 121, 425.Google Scholar
Huh, C. & Mason, S. G. 1977 The steady moti on of a liquid meniscus in a capillary tube. J. Fluid Mech. 81, 401.Google Scholar
Huh, C. & Scriven, L. E. 1969 Shapes of axisymmetric fluid interfaces of unbounded extent. J. Colloid Interface Sci. 30, 323.Google Scholar
Jackson, R. 1977 Transport in Porous Catalysts. Elsevier.
Jansons, K. M. 1986 Moving contact lines at non-zero capillary number. J. Fluid Mech. 167, 393.Google Scholar
Koplik, J., Banavar, J. R. & Willemsen, J. F. 1988 Molecular dynamics of Poiseuille flow and moving contact lines. Phys. Rev. Lett.60, 1282.Google Scholar
Lowndes, J. 1980 The numerical simulation of the steady motion of the fluid meniscus in a capillary tube. J. Fluid Mech. 101, 631.Google Scholar
Ngan, C. G. & DussanV., E. B. 1989 On the dynamics of liquid spreading on solid surfaces. J. Fluid Mech. 209, 191.Google Scholar
Thompson, P. A. & Robbins, M. O. 1989 Simulations of contact-line motion: slip and dynamic contact angle. Phys. Rev. Lett. 63, 766.Google Scholar