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The rheology of a suspension of nearly spherical particles subject to Brownian rotations

Published online by Cambridge University Press:  29 March 2006

L. G. Leal
Affiliation:
Chemical Engineering, California Institute of Technology
E. J. Hinch
Affiliation:
Department of Applied Mathematics and Theoretical Physics, University of Cambridge

Abstract

A set of constitutive equations, valid for arbitrary linear bulk flows, is derived for a dilute suspension of nearly spherical, rigid particles which are subject to rotary Brownian couples. These constitutive equations are subsequently applied to find the resulting stress patterns for a variety of time-dependent bulk flow fields. The rheological responses are found to exhibit many of the same qualitative features as have been observed in recent experimental investigations of polymeric solutions and other complex materials.

Type
Research Article
Copyright
© 1972 Cambridge University Press

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References

Astarita, G. & Nicodema, L. 1970 Chem. Engng J. 1, 57.
Batchelor, G. K. 1970 J. Fluid Mech. 41, 545.
Bird, R. B. & Harris, E. K. 1968 A.I.Ch.E. J. 14, 758.
Bird, R. B. & Harris, E. K. 1970 A.I.Ch.E. J. 16, 149.
Bird, R. B., Warner, H. R. & Evans, D. C. 1971 Adv. Polym. Sci. 8, 1.
Boeder, P. 1932 Z. Phys. 75, 258.
Booij, H. C. 1966 Rheologica Acta, 5, 215, 222.
Booij, H. C. 1968 Rheologica Acta, 7, 202.
Bretherton, F. P. 1962 J. Fluid Mech. 14, 284.
Burgers, J. M. 1938 In Second Report on Viscosity and Plasticity, Chapter 3. Kon. Ned. Akad. Wet. Verhand. (Eerste Sectie), 16, 113.
Coleman, B. D. & Markovitz, H. 1964 J. Appl. Phys. 35, 1.
Endo, H. & Nagasawa, M. 1970 J. Polym. Sci. 8, 371.
Ferry, J. D. 1970 Viscoelastic Properties of Polymers. Wiley.
Ferry, J. D., Holmes, L. A., Lamb, J. & Matheson, A. J. 1966 J. Phys. Chem. 70, 1685.
Frankel, N. A. & Acrivos, A. 1970 J. Fluid Mech. 44, 65.
Giesekus, H. 1962 Rheologica Acta, 2, 50.
Goddard, J. D. & Miller, C. 1966 Rheologica Acta, 5, 177.
Goddard, J. D. & Miller, C. 1967 J. Fluid Mech. 28, 657.
Hinch, E. J. & Leal, L. G. 1972 J. Fluid Mech. 52, 683.
Huppler, J. D., MacDonald, T. F., Ashare, E., Spriggs, T. W., Bird, R. B. & Holmes, L. A. 1967 Trans. Soc. Rheol. 11, 181.
Jeffery, G. B. 1922 Proc. Roy. Soc. A 102, 161.
Kirkwood, J. G. & Auer, P. L. 1951 J. Chem. Phys. 19, 281.
Kirkwood, J. G. & Flock, R. J. 1956 J. Chem. Phys. 24, 665.
Leal, L. G. & Hinch, E. J. 1971 J. Fluid Mech. 46, 685.
Leal, L. G. & Hinch, E. J. 1972 Rheologica Acta, to appear.
Maxwell, B. & Chartoff, R. P. 1965 Trans. Soc. Rheol. 9 (1), 41.
Metzner, A. B. & Metzner, A. P. 1970 Rheologica Acta, 9, 174.
Moore, R. S., McSkimin, H. J., Gieniewski, C. & Andreatch, P. 1969 J. Chem. Phys. 50, 5088.
Peterlin, A. 1938 Z. Phys. 111, 232.
Peterlin, A. & Stuart, H. A. 1939 Z. Phys. 112, 1, 129.
Sadron, Ch. 1953 Flow Properties of Disperse Systems (ed. J. J. Hermans), chap. 4. North-Holland Pub. Co.
Scheraga, H. A. 1955 J. Chem. Phys. 23, 1526.
Simmons, J. M. 1970 Rheologica Acta, 7, 184.
Stewart, W. E. & Sørensen, J. P. 1972 Trans. Soc. Rheol. 16 (1), 1.
Takserman-Krozer, R. & Ziabicki, A. 1963 J. Polym. Sci. A 1, 491, 507.
Vinogradov, G. V. & Belkin, I. M. 1965 J. Polym. Sci. 3, 917.
Wales, J. L. S. & den Otter, J. L. 1970 Rheologica Acta, 9, 115.