The Workman-Reynolds effect was investigated during the phase change of dilute (about 2 × 10-4 N) KCl solutions into single crystals of ice. The ice crystals were oriented with the c-axes either parallel or perpendicular to the growth direction. The solute distribution in the liquid phase. near the interface (within 10 mm), was obtained with a wire-type conductivity cell. For a crystal growth rate 8.8 μm/s the freezing potentials were + 10.0 V and + 6.0 V and the specific charge séparations were 1.3 ± 0 1 × 10-6 C/g of ice and 1 4 ± 0.1 × 10-6 C/g of ice for growth parallel and perpendicular. Respectively, to the c-axes of the ice crystals . The equilibrium solute distribution coefficient was found to be 4 × 10-3 for KCl solutions for both crystal orientations. An “apparent” (because of convection in the liquid phase) distribution coefficient ranged from 0.031- 0.074. The “apparent” diffusion coefficients ranged from 1.3–4.9 × 10-3 mm2/s and varied linearly with growth rate. The ionic distribution coefficients. K+ and K-, were approximately K+ - K- = - 2 × 10-5 and K+ + K - = 8 × 10-3 for the KCl solutions.