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Breakthrough applications of high-entropy materials

Published online by Cambridge University Press:  20 August 2018

Jien-Wei Yeh  and
Su-Jien Lin
Jien-Wei Yeh*
Affiliation:
Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan, Republic of China
Su-Jien Lin
Affiliation:
Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan, Republic of China
*
a)Address all correspondence to this author. e-mail: jwyeh@mx.nthu.edu.tw
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Abstract

The concept of high-entropy alloys has been extended to ceramics, polymers, and composites. “High-entropy materials (HEMs)” are named to cover all these materials. Recently, HEMs has become a new emerging field through the collective efforts of many researchers. Basically, high mixing entropy can enhance the formation of solution-type phases for alloys, ceramics, and composites at high temperatures, and in general leads to simpler microstructure. Large degrees of freedom in composition design as well as process design have been found to provide a wide range of microstructure and properties for applications. There are many opportunities for HEMs to overcome the bottlenecks of conventional materials. In this article, several possible breakthrough applications are pointed out and emphasized for turbine blades, thermal spray bond coatings, high-temperature molds and dies, sintered carbides for cutting tools, hard coatings for cutting tools, hardfacings, and radiation-damage resistant materials. In addition, more possible breakthrough examples are briefly described.

Keywords

high-entropy alloyshigh-entropy ceramicshigh-entropy materialsbreakthrough applications
Type
Invited Article
Information
Journal of Materials Research , Volume 33 , Issue 19: Focus Issue: Fundamental Understanding and Applications of High-Entropy Alloys , 14 October 2018 , pp. 3129 - 3137
Copyright
Copyright © Materials Research Society 2018 

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References

REFERENCES

Murty, B.S., Yeh, J.W., and Ranganathan, S.: High Entropy Alloys (Butterworth-Heinemann, Boston, 2014).CrossRefGoogle Scholar
Gao, M.C., Yeh, J.W., Liaw, P.K., and Zhang, Y.: High-Entropy Alloys: Fundamentals and Applications (Springer International Publishing, Cham, 2016).CrossRefGoogle Scholar
Yeh, J.W., Chen, S.K., Lin, S.J., Gan, J.Y., Chin, T.S., Shun, T.T., Tsau, C.H., and Chang, S.Y.: Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes. Adv. Eng. Mater. 6, 299 (2004).CrossRefGoogle Scholar
Yeh, J.W.: Alloy design strategies and future trends in high-entropy alloys. JOM 65, 1759 (2013).CrossRefGoogle Scholar
Gludovatz, B., Hohenwarter, A., Catoor, D., Chang, E.H., George, E.P., and Ritchie, R.O.: A fracture-resistant high-entropy alloy for cryogenic applications. Science 345, 1153 (2014).CrossRefGoogle ScholarPubMed
Tsai, M.H. and Yeh, J.W.: High-entropy alloys: A critical review. Mater. Res. Lett. 2, 107 (2014).CrossRefGoogle Scholar
Cheng, C.Y., Yang, Y.C., Zhong, Y.Z., Chen, Y.Y., Hsu, T., and Yeh, J.W.: Physical metallurgy of concentrated solid solutions from low-entropy to high-entropy alloys. Curr. Opin. Solid State Mater. Sci. 21, 299 (2017).CrossRefGoogle Scholar
Miracle, D.B. and Senkov, O.N.: A critical review of high entropy alloys and related concepts. Acta Mater. 122, 448 (2017).CrossRefGoogle Scholar
Shi, Y., Yang, B., and Liaw, P.: Corrosion-resistant high-entropy alloys: A review. Metals 7, 43 (2017).CrossRefGoogle Scholar
Reed, R.C.: The Superalloys: Fundamentals and Applications (Cambridge University Press, Cambridge, 2006).CrossRefGoogle Scholar
Kennedy, R.L.: Allvac®718Plus™, Superalloy for the next forty years. In Superalloys 718, 625, 706 and Derivatives, Loria, E.A., ed. (TMS, Warrendale, Pennsylvania, 2005), pp. 1Google Scholar
Kawagishi, K., Yeh, A.C., Yokokawa, T., Kobayashi, T., Koizumi, Y., and Harada, H.: Development of an oxidation-resistant high-strength sixth-generation single-crystal superalloy TMS-238. In Superalloys 2012 (John Wiley & Sons, 2012), pp. 189.CrossRefGoogle Scholar
Tsai, K.Y., Tsai, M.H., and Yeh, J.W.: Sluggish diffusion in Co–Cr–Fe–Mn–Ni high-entropy alloys. Acta Mater. 61, 4887 (2013).CrossRefGoogle Scholar
Vaidya, M., Pradeep, K.G., Murty, B.S., Wilde, G., and Divinski, S.V.: Bulk tracer diffusion in CoCrFeNi and CoCrFeMnNi high entropy alloys. Acta Mater. 146, 211 (2018).CrossRefGoogle Scholar
Tsao, T.K., Yeh, A.C., Kuo, C.M., Kakehi, K., Murakami, H., Yeh, J.W., and Jian, S.R.: The high temperature tensile and creep behaviors of high entropy superalloy. Sci. Rep. 7, 12658 (2017).CrossRefGoogle ScholarPubMed
Padture, N.P., Gell, M., and Jordan, E.H.: Thermal barrier coatings for gas-turbine engine applications. Science 296, 280 (2002).CrossRefGoogle ScholarPubMed
Hsu, W.L., Murakami, H., Yeh, J.W., Yeh, A.C., and Shimoda, K.: A heat-resistant NiCo0.6Fe0.2Cr1.5SiAlTi0.2 overlay coating for high-temperature applications. J. Electrochem. Soc. 163, C752 (2016).CrossRefGoogle Scholar
Shen, W.J., Tsai, M.H., Tsai, K.Y., Juan, C.C., Tsai, C.W., Yeh, J.W., and Chang, Y.S.: Superior oxidation resistance of (Al0.34Cr0.22Nb0.11Si0.11Ti0.22)50N50 high-entropy nitride. J. Electrochem. Soc. 160, C531 (2013).CrossRefGoogle Scholar
Abram, T. and Ion, S.: Generation-IV nuclear power: A review of the state of the science. Energy Policy 36, 4323 (2008).CrossRefGoogle Scholar
Murty, K.L. and Charit, I.: Structural materials for Gen-IV nuclear reactors: Challenges and opportunities. J. Nucl. Mater. 383, 189 (2008).CrossRefGoogle Scholar
Zhang, Y., Zhao, S., Weber, W.J., Nordlund, K., Granberg, F., and Djurabekova, F.: Atomic-level heterogeneity and defect dynamics in concentrated solid-solution alloys. Curr. Opin. Solid State Mater. Sci. 21(5), 221 (2017).CrossRefGoogle Scholar
Jin, K., Lu, C., Wang, L.M., Qu, J., Weber, W.J., Zhang, Y., and Bei, H.: Effects of compositional complexity on the ion-irradiation induced swelling and hardening in Ni-containing equiatomic alloys. Scr. Mater. 119, 65 (2016).CrossRefGoogle Scholar
Kumar, N.A.P.K., Li, C., Leonard, K.J., Bei, H., and Zinkle, S.J.: Microstructural stability and mechanical behavior of FeNiMnCr high entropy alloy under ion irradiation. Acta Mater. 113, 230 (2016).CrossRefGoogle Scholar
Lu, Y., Dong, Y., Guo, S., Jiang, L., Kang, H., Wang, T., Wen, B., Wang, Z., Jie, J., Cao, Z., Ruan, H., and Li, T.: A promising new class of high-temperature alloys: Eutectic high-entropy alloys. Sci. Rep. 4, 6200 (2014).CrossRefGoogle ScholarPubMed
Bhattacharjee, T., Wani, I.S., Sheikh, S., Clark, I.T., Okawa, T., Guo, S., Bhattacharjee, P.P., and Tsuji, N.: Simultaneous strength-ductility enhancement of a nano-lamellar AlCoCrFeNi2.1 eutectic high entropy alloy by cryo-rolling and annealing. Sci. Rep. 8, 3276 (2018).CrossRefGoogle ScholarPubMed
Li, Z., Pradeep, K.G., Deng, Y., Raabe, D., and Tasan, C.C.: Metastable high-entropy dual-phase alloys overcome the strength-ductility trade-off. Nature 534, 227 (2016).CrossRefGoogle ScholarPubMed
Li, Z., Tasan, C.C., Pradeep, K.G., and Raabe, D.: A TRIP-assisted dual-phase high-entropy alloy: Grain size and phase fraction effects on deformation behavior. Acta Mater. 131, 323 (2017).CrossRefGoogle Scholar
Lin, R.C., Lee, T.K., Wu, D.H., and Lee, Y.C.: A study of thin film resistors prepared using Ni–Cr–Si–Al–Ta high entropy alloy. Adv. Mater. Sci. Eng. 2015, 1 (2015).Google Scholar
Bérardan, D., Franger, S., Meena, A.K., and Dragoe, N.: Room temperature lithium superionic conductivity in high entropy oxides. J. Mater. Chem. A 4, 9536 (2016).CrossRefGoogle Scholar