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Changes in surface area and composition during grinding of silicon in environments of various quality

Published online by Cambridge University Press:  03 March 2011

Klára Tkáčová ,
Nadežda Števulová ,
Zdeněk Bastl ,
Pavel Stopka  and
Magdaléna Bálintová
Klára Tkáčová
Affiliation:
Institute of Geotechnics, Slovak Academy of Sciences, Košice, Slavakia
Nadežda Števulová
Affiliation:
Institute of Geotechnics, Slovak Academy of Sciences, Košice, Slavakia
Zdeněk Bastl
Affiliation:
J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic
Pavel Stopka
Affiliation:
Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic
Magdaléna Bálintová
Affiliation:
Institute of Geotechnics, Slovak Academy of Sciences, Košice, Slovakia
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Abstract

Changes in particle size, surface properties, and composition brought about by planetary grinding of silicon in air and various permittivity liquids were investigated. Using a variety of spectroscopic techniques (ESR, IRS, and XPS), a mechanically induced surface oxidation was proved. While at grinding in air and organic liquids a part of the centers originating from dangling orbitals on SiIII are preserved, the properties of water-ground silicon are fully governed by the oxide surface shell. The most effective particle size reduction and surface protection can be reached by grinding in nonpolar liquids.

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Articles
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Journal of Materials Research , Volume 10 , Issue 11 , November 1995 , pp. 2728 - 2735
Copyright
Copyright © Materials Research Society 1995

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