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Controlled synthesis and photocatalytic performance of waxberry-like Ni11(HPO3)8(OH)6 microballs

Published online by Cambridge University Press:  02 May 2017

Yu Zhang ,
Zhijian Peng  and
Xiuli Fu
Yu Zhang
Affiliation:
School of Engineering and Technology, China University of Geosciences, Beijing 100083, People’s Republic of China; and State Key Laboratory of Information Photonics and Optical Communications, and School of Science, Beijing University of Posts and Telecommunications, Beijing 100876, People’s Republic of China
Zhijian Peng*
Affiliation:
School of Engineering and Technology, China University of Geosciences, Beijing 100083, People’s Republic of China
Xiuli Fu*
Affiliation:
State Key Laboratory of Information Photonics and Optical Communications, and School of Science, Beijing University of Posts and Telecommunications, Beijing 100876, People’s Republic of China
*
a) Address all correspondence to these authors. e-mail: pengzhijian@cugb.edu.cn
b) e-mail: xiulifu@bupt.edu.cn
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Abstract

Due to the increasingly severe environmental pollution problems, the development of semiconductor photocatalysts is being extensively carried out because they have exhibited high activities for the degradation of many organic and inorganic pollutants. In this study, waxberry-like Ni11(HPO3)8(OH)6 microball photocatalysts with a diameter of 10–20 μm have been successfully synthesized via a solvothermal route by using NiSO4 as a Ni-source and NaH2PO2 as a P-source in a mixture of ethylene glycol and water under the optimized conditions with a Ni:P molar ratio of 1:2 at 200 °C for 16 h. The as-prepared photocatalysts were characterized by powder X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray analysis, Brunauer–Emmett–Teller N2 adsorption, zeta potential, ultraviolet-visible (UV–vis) absorption, and photocatalysis tests. The decolourization of organic dyes, methylene blue and rhodamine B, under ultraviolet light over the as-prepared products reveals an excellent photocatalytic performance due to the good absorption for ultraviolet light.

Keywords

Ni11(HPO3)8(OH)6waxberry-like microballhydrothermal synthesisphotocatalysis
Type
Articles
Information
Journal of Materials Research , Volume 32 , Issue 14 , 28 July 2017 , pp. 2819 - 2828
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Copyright
Copyright © Materials Research Society 2017 

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Footnotes

Contributing Editor: Akira Nakajima

References

REFERENCES

Adair, J.H., Li, T., Kido, T., Havey, K., Moon, J., Mecholsky, J., Morrone, A., Talham, D.R., Ludwig, M.H., and Wang, L.: Recent developments in the preparation and properties of nanometer-size spherical and platelet-shaped particles and composite particles. Mater. Sci. Eng., R 23, 139 (1998).Google Scholar
Jun, Y.W., Choi, J.S., and Cheon, J.: Shape control of semiconductor and metal oxide nanocrystals through nonhydrolytic colloidal routes. Angew. Chem., Int. Ed. 45, 3414 (2006).Google Scholar
Wei, N., Cui, H.Z., Song, Q., Zhang, L.Q., Song, X.J., Wang, K., Zhang, Y.F., Li, J., Wen, J., and Tian, J.: Ag2O nanoparticle/TiO2 nanobelt heterostructures with remarkable photo-response and photocatalytic properties under UV, visible and near-infrared irradiation. Appl. Catal., B 198, 83 (2016).Google Scholar
Son, C.Y., Kwak, I.H., Lim, Y.R., and Park, J.: FeP and FeP2 nanowires for efficient electrocatalytic hydrogen evolution reaction. Chem. Commun. 387, 469 (2016).Google Scholar
Jiang, D.C., Sun, Z.J., Jia, H.X., Lu, D.P., and Du, P.W.: A cocatalyst-free CdS nanorod/ZnS nanoparticle composite for high-performance visible-light-driven hydrogen production from water. J. Mater. Chem. A 4, 675 (2016).Google Scholar
Yu, X.Y., Feng, Y., Guan, B.Y., Lou, X.W., and Paik, U.: Carbon coated porous nickel phosphides nanoplates for highly efficient oxygen evolution reaction. Energy Environ. Sci. 9, 1246 (2016).Google Scholar
Marcos, M.D., Amoros, P., and Lebail, A.: Synthesis and crystal-structure of a tubular hydroxyphosphite: Zn11(HPO3)8(OH)6 . J. Solid State Chem. 107, 250 (1993).Google Scholar
Marcos, M.D., Amoros, P., Beltranporter, A., Martinezmanez, R., and Attfield, J.P.: Novel crystalline microporous transition-metal phosphites M11(HPO3)8(OH)6 (M = Zn, Co, Ni): X-ray powder diffraction structure determination of the Co and Ni derivatives. Chem. Mater. 5, 121 (1993).Google Scholar
Silbernagel, R., Martin, C.H., and Clearfield, A.: Zirconium(IV) phosphonate-phosphates as efficient ion-exchange materials. Inorg. Chem. 55, 1651 (2016).Google Scholar
Liu, Y.Y., Wang, H.T., Lin, D.C., Liu, C., Hsu, P.C., Liu, W., Chen, W., and Cui, Y.: Electrochemical tuning of olivine-type lithium transition-metal phosphates as efficient water oxidation catalysts. Energy Environ. Sci. 8, 1719 (2015).Google Scholar
Zhong, G.M., Bai, J.Y., Duchesne, P.N., McDonald, M.J., Li, Q., Hou, X., Tang, J.A., Wang, Y., Zhao, W.G., and Gong, Z.L.: Copper phosphate as a cathode material for rechargeable Li batteries and its electrochemical reaction mechanism. Chem. Mater. 27, 5736 (2015).Google Scholar
Miao, H., Wan, H.X., Liu, M., Zhang, Y., Xu, X., Ju, W.W., Zhua, D.R., and Xu, Y.: Two novel organic–inorganic hybrid molybdenum(V) cobalt/nickel phosphate compounds based on isolated nanosized Mo/Co(Ni)/P cluster wheels. J. Mater. Chem. C 2, 6554 (2014).Google Scholar
Anigrahawati, P., Sahar, M.R., and Ghoshal, S.K.: Influence of Fe3O4 nanoparticles on structural, optical and magnetic properties of erbium doped zinc phosphate glass. Mater. Chem. Phys. 155, 155 (2015).Google Scholar
Zhong, D.K., Cornuz, M., Sivula, K., Graetzel, M., and Gamelin, D.R.: Photo-assisted electrodeposition of cobalt–phosphate (Co–Pi) catalyst on hematite photoanodes for solar water oxidation. Energy Environ. Sci. 4, 1759 (2011).Google Scholar
Wen, H., Cao, M.H., Sun, G.B., Xu, W.G., Wang, D., Zhang, X.Q., and Hu, C.W.: Hierarchical three-dimensional cobalt phosphate microarchitectures: Large-scale solvothermal synthesis, characterization, and magnetic and microwave absorption properties. J. Phys. Chem. C 112, 15948 (2008).Google Scholar
Zhang, L., Ni, Y.H., Liao, K.M., and Wei, X.W.: Large-scale synthesis of single crystalline NiHPO3·H2O nanoneedle bundles based on the dismutation of NaH2PO2 . Cryst. Growth Des. 8, 3636 (2008).Google Scholar
Pang, H., Yan, Z.Z., Wei, Y.Y., Li, X.X., Li, J., Zhang, L., Chen, J., Zhang, J.S., and Zheng, H.H.: The morphology evolution of nickel phosphite hexagonal polyhedrons and their primary electrochemical capacitor applications. Part. Part. Syst. Charact. 30, 287 (2013).Google Scholar
Gu, Z.J., Zhai, T.Y., Gao, B.F., Zhang, G.J., Ke, D.M., Ma, Y., and Yao, J.N.: Controlled hydrothermal synthesis of nickel phosphite nanocrystals with hierarchical superstructures. Cryst. Growth Des. 7, 825 (2007).CrossRefGoogle Scholar
Johansson, M.B., Niklasson, G.A., and Osterlund, L.: Structural and optical properties of visible active photocatalytic WO3 thin films prepared by reactive dc magnetron sputtering. J. Mater. Res. 27, 3130 (2012).Google Scholar
Yang, X.F., Tang, H., Xu, J.S., Antonietti, M., and Shalom, M.: Silver phosphate/graphitic carbon nitride as an efficient photocatalytic tandem system for oxygen evolution. ChemSusChem 8, 1350 (2015).Google Scholar
Ha, D.H., Han, B.H., Risch, M., Giordano, L., Yao, K.P.C., Karayaylali, P., and Shao-Horn, Y.: Activity and stability of cobalt phosphides for hydrogen evolution upon water splitting. Nano Energy 29, 37 (2016).Google Scholar
Muthuswamy, E., Savithra, G.H.L., and Brock, S.L.: Synthetic levers enabling independent control of phase, size, and morphology in nickel phosphide nanoparticles. ACS Nano 5, 2402 (2011).Google Scholar
Wang, J.W., Johnston-Peck, A.C., and Tracy, J.B.: Nickel phosphide nanoparticles with hollow, solid, and amorphous structures. Chem. Mater. 21, 4462 (2009).CrossRefGoogle Scholar
Moreau, L.M., Ha, D.H., Zhang, H.T., Hoyden, R., Muller, D.A., and Robinson, R.D.: Defining crystalline/amorphous phases of nanoparticles through X-ray absorption spectroscopy and X-ray diffraction: The case of nickel phosphide. Chem. Mater. 25, 2394 (2013).Google Scholar
Liu, S.L., Liu, X.Z., Xu, L.Q., Qian, Y.T., and Ma, X.C.: Controlled synthesis and characterization of nickel phosphide nanocrystal. J. Cryst. Growth 304, 430 (2007).Google Scholar
Zhang, Y., Jianmin, L., Nishiura, M., and Imamoto, T.: Spectral and structural properties of 2D network complex [Ni(4,4′-bipyridine)2(NCS)2] n . J. Mol. Struct. 519, 219 (2000).Google Scholar
Ren, Y.W., Lu, J.X., Cai, B.W., Shi, D.B., Jiang, H.F., Chen, J., Zheng, D., and Liu, B.: A novel asymmetric di-Ni(II) system as a highly efficient functional model for phosphodiesterase: Synthesis, structures, physicochemical properties and catalytic kinetics. Dalton Trans. 40, 1372 (2011).Google Scholar
Fukumoto, H., Yamane, K., Kase, Y., and Yamamoto, T.: π-Conjugated poly(aryleneethynylene)s consisting of salophen and Ni-salophen units in the π-conjugated main chain: Preparation and chemical properties. Macromolecules 43, 10366 (2010).Google Scholar
Yeh, T.F., Chan, F.F., Hsieh, C.T., and Teng, H.: Graphite oxide with different oxygenated levels for hydrogen and oxygen production from water under illumination: The band positions of graphite oxide. J. Phys. Chem. C 115, 22587 (2011).Google Scholar
Zhu, G.L., Yin, H., Yang, C.Y., Cui, H.L., Wang, Z., Xu, J.J., Lin, T.Q., and Huang, F.Q.: Black titania for superior photocatalytic hydrogen production and photoelectrochemical water splitting. ChemCatChem 7, 2614 (2015).Google Scholar
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