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Corrosion-resistant fluoridated Ca–Mg–P composite coating on magnesium alloys prepared via hydrothermal assisted sol–gel process

Published online by Cambridge University Press:  06 August 2018

Yangyang Jiang ,
Lingjun Zhu ,
Shu Cai ,
Sibo Shen ,
Yue Li ,
Song Jiang ,
Yishu Lin ,
Shaoshuai Hua ,
Rui Ling  and
Guohua Xu
Yangyang Jiang
Affiliation:
Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, People’s Republic of China
Lingjun Zhu
Affiliation:
Department of Orthopedic Surgery, Changzheng Hospital, Second Military Medical University, Shanghai 200003, People’s Republic of China
Shu Cai*
Affiliation:
Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, People’s Republic of China
Sibo Shen*
Affiliation:
Center for Electron Microscopy, Institute for New Energy Materials & Low-Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, People’s Republic of China
Yue Li
Affiliation:
Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, People’s Republic of China
Song Jiang
Affiliation:
Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, People’s Republic of China
Yishu Lin
Affiliation:
Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, People’s Republic of China
Shaoshuai Hua*
Affiliation:
Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, People’s Republic of China
Rui Ling
Affiliation:
Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, People’s Republic of China
Guohua Xu*
Affiliation:
Department of Orthopedic Surgery, Changzheng Hospital, Second Military Medical University, Shanghai 200003, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: caishu@tju.edu.cn
b)e-mail: shensibo@tjut.edu.cn
c)e-mail: xuguohuamail@smmu.edu.cn
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Abstract

In this work, corrosion-resistant fluoridated Ca–Mg–P composite coatings were prepared on magnesium alloys via a hydrothermal assisted sol–gel process. All these coatings derived from Coating Sols with different F− concentrations are composed of fluoridated hydroxyapatite, magnesium hydroxide, and dittmarite. When F− concentration of Coating Sol is 0.03 M, the coating exhibited uniform and dense surface, and its thickness reached 32 μm, thus possessing a high charge transfer resistance of 312 ± 12.69 kΩ cm2 in simulated body fluid (SBF). Immersion test in SBF showed that this coating could quickly induce the formation of the mineralized layer, implying relatively high bioactivity. After 49 days of immersion, the original composite coating and newly formed mineralized layer reached 60 μm in thickness, providing effective long-term protection for magnesium alloys. These attractive results indicate that this fluoridated Ca–Mg–P composite coating is a promising protective coating on biodegradable magnesium and magnesium alloy implants for orthopaedic applications.

Keywords

coatingalloycorrosion
Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 22 , 28 November 2018 , pp. 3793 - 3800
Copyright
Copyright © Materials Research Society 2018 

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Footnotes

d)

These authors contributed equally to this work.

References

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